Comprehensive assessment of carbon-, biomaterial- and inorganic-based adsorbents for the removal of the most hazardous heavy metal ions from wastewater

Abstract

Owing to the high cost of recycling waste, underdeveloped countries discharge industrial, agricultural, and anthropogenic effluents without pretreatment. As a result, pollutant-loaded waste enters water bodies. Among the diverse toxic contaminants, heavy metal ions are the most detrimental because of their chronic toxicity, non-degradability, prevalence, and bioaccumulation. The growing shortage of water resources demands the removal of heavy metal ions from wastewater. Three SDGs of the sustainability agenda of the United Nations appeal for clean water to protect life beneath water and on land depending on the water sources. Therefore, efficient environmentally friendly approaches for wastewater treatment are urgently required. In this regard, several methods have been developed for the removal of heavy metal ions from wastewater, including adsorption as the most widely used method owing to its eco-friendly, cost-effective, and sustainable nature. The present review discusses the progress in the preparation and application of various adsorbents based on carbon, micro-organisms, agricultural waste and inorganic materials for the extraction of toxic metal ions such as Pb²⁺, Cr⁶⁺, As³⁺, As⁵⁺, Hg²⁺ and Cd²⁺. Herein, we provide information on the role of the homogeneity and heterogeneity of adsorbents, kinetics of the adsorption of an adsorbate on the surface of an adsorbent, insights into adsorption reaction pathways, the mechanism of the sorption process, and the uptake of solutes from solution. The present review will be useful for researchers working on environmental protection and clean environment.