Issue 1, 2010
From the journal:

Chemical Communications

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis†‡

Jonathan Hopewell,a   Piotr Jankowski,a   Claire L. McMullin,a   A. Guy Orpena  and  Paul G. Pringle*a  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock’s Close, Bristol, UK
E-mail: paul.pringle@bristol.ac.uk
Fax: +44 (0)117 929 0509
Tel: +44 (0)117 928 8114

Abstract

An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine β-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.

Graphical abstract: Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

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Article information

DOI
https://doi.org/10.1039/B916359J
Article type
Communication
Submitted
11 Aug 2009
Accepted
08 Oct 2009
First published
02 Nov 2009

Chem. Commun., 2010,46, 100-102

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Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

J. Hopewell, P. Jankowski, C. L. McMullin, A. G. Orpen and P. G. Pringle, Chem. Commun., 2010, 46, 100 DOI: 10.1039/B916359J

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