Issue 50, 2012
From the journal:

Chemical Communications

Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state†‡

Vicente M. Blas-Ferrando,a   Javier Ortiz,a   Latifa Bouissane,a   Kei Ohkubo,b   Shunichi Fukuzumi,*bc   Fernando Fernández-Lázaroa  and  Ángela Sastre-Santos*a  

* Corresponding authors

a División de Química Orgánica Instituto de Bioingeniería, Universidad Miguel Hernández, Elche 03202, Spain
E-mail: asastre@umh.es

b Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan

c Department of Bioinspired Science, Ewha Womans University, Seoul, Korea

Abstract

A new ZnPc–PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.

Graphical abstract: Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC31087B
Article type
Communication
Submitted
14 Feb 2012
Accepted
02 May 2012
First published
04 May 2012

Chem. Commun., 2012,48, 6241-6243

Permissions

Request permissions

Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

V. M. Blas-Ferrando, J. Ortiz, L. Bouissane, K. Ohkubo, S. Fukuzumi, F. Fernández-Lázaro and Á. Sastre-Santos, Chem. Commun., 2012, 48, 6241 DOI: 10.1039/C2CC31087B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements