Issue 22, 2012

CuO nano particles and [bmim]BF4: an application towards the synthesis of chiral β-seleno amino derivatives via ring opening reaction of aziridines with diorganyl diselenides

Abstract

A series of chiral β-seleno amino derivatives were synthesized via a ring opening reaction of different aziridines with diorganyl diselenides mediated by recyclable CuO nanopowder and an ionic liquid affording the corresponding products in good to excellent yields. The [bmim]BF4 ionic liquid acts as both promoter and reaction medium. Compared to the usual organic solvents the ionic liquid exhibited better performance with the advantage of its recyclability.

Graphical abstract: CuO nano particles and [bmim]BF4: an application towards the synthesis of chiral β-seleno amino derivatives via ring opening reaction of aziridines with diorganyl diselenides

Supplementary files

Article information

Article type
Paper
Submitted
18 Jul 2012
Accepted
18 Jul 2012
First published
13 Aug 2012

RSC Adv., 2012,2, 8478-8482

CuO nano particles and [bmim]BF4: an application towards the synthesis of chiral β-seleno amino derivatives via ring opening reaction of aziridines with diorganyl diselenides

S. M. Salman, S. Narayanaperumal, R. S. Schwab, C. R. Bender, O. E. D. Rodrigues and L. Dornelles, RSC Adv., 2012, 2, 8478 DOI: 10.1039/C2RA21488A

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