Issue 70, 2014
From the journal:

Chemical Communications

Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum†‡

Igor L. Fedushkin,*ab   Vladimir G. Sokolov,ab   Alexander V. Piskunov,ab   Valentine M. Makarov,c   Eugeny V. Baranovab  and  Gleb A. Abakumovab  

* Corresponding authors

a G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, Nizhny Novgorod, Russian Federation
E-mail: igorfed@iomc.ras.ru
Fax: +7 831 4627497
Tel: +7 831 4629631

b N.I. Lobachevskii Nizhny Novgorod State University, Prospect Gagarina 23, Nizhny Novgorod, Russian Federation

c K. Minin Nizhny Novgorod State Pedagogical University, Ulyanova 1, Nizhny Novgorod, Russian Federation
E-mail: chemngpu@gmail.com
Fax: +7 831 4364446
Tel: +7 831 4390367

Abstract

A gallium(I) carbenoid derived from redox-active diimine 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) in complexes with molybdenum may serve either as a neutral [(dpp-bian)Ga:] or an anionic [(dpp-bian)Ga:]− two-electron donor depending on the electronic state of the transition metal.

Graphical abstract: Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

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Article information

DOI
https://doi.org/10.1039/C4CC04019H
Article type
Communication
Submitted
26 May 2014
Accepted
11 Jul 2014
First published
14 Jul 2014

Chem. Commun., 2014,50, 10108-10111

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Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

I. L. Fedushkin, V. G. Sokolov, A. V. Piskunov, V. M. Makarov, E. V. Baranov and G. A. Abakumov, Chem. Commun., 2014, 50, 10108 DOI: 10.1039/C4CC04019H

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