Issue 76, 2014
From the journal:

Chemical Communications

Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons†

Richard A. Lewis,a   K. Cory MacLeod,a   Brandon Q. Mercadoa  and  Patrick L. Holland*a  

* Corresponding authors

a Department of Chemistry, Yale University, 225 Prospect St., New Haven, CT 06520, USA
E-mail: patrick.holland@yale.edu

Abstract

A low-coordinate iron(I) species can reversibly reduce pyridine, either by one electron to give a new C–C bond, or by two electrons to give a pyridine-derived bridge with an unprecedented μ-η1:η3 binding mode.

Graphical abstract: Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons

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Article information

DOI
https://doi.org/10.1039/C4CC05495D
Article type
Communication
Submitted
16 Jul 2014
Accepted
04 Aug 2014
First published
11 Aug 2014

Chem. Commun., 2014,50, 11114-11117

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Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons

R. A. Lewis, K. C. MacLeod, B. Q. Mercado and P. L. Holland, Chem. Commun., 2014, 50, 11114 DOI: 10.1039/C4CC05495D

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