Ionic liquid-assisted sustainable preparation of photo-catalytically active nanomaterials and their composites with 2D materials

Abstract

The preparation of nanomaterials employing ionic liquids (ILs) and surface active ionic liquids (SAILs) in a relatively sustainable manner for different applications is reviewed. ILs offer structure directing and templating effects via inherent bi-continuous structures formed by the segregation of polar and non-polar domains. On the other hand, SAILs offer a structure-directing effect governed by their ability to lower the surface tension, self-assembling nature and interaction with precursors via ionic head groups. Binary mixtures of ILs with other relatively greener solvents or utilization of metal-based ILs (MILs), which act as precursors of metal ions, templates and stabilizing agents propose a new way to prepare a variety of nanomaterials. The introduction of SAILs that exfoliate 2D materials under low-energy bath sonication and also aid in photoreduction and stabilization of photocatalytically active nanomaterials at the surface of 2D materials poses a distinctive perspective in sustainable preparation and utilization of nanomaterials in different photocatalytic applications. The present feature article reviews the employment of distinctive properties of ILs in precise morphological control of nanomaterials, and their after-effects on their catalytic efficiencies.