Themed collection Honorary collection in memory of Professor Dr Helmut Ringsdorf

25 items
Review Article

Next-generation biopolymer gels: innovations in drug delivery and theranostics

Theranostic use of smart gels for precise treatment and drug delivery.

Graphical abstract: Next-generation biopolymer gels: innovations in drug delivery and theranostics
Communication

Perylene bisimide J-aggregates in a polymer matrix: controlling self-assembly and fluorescence properties

The self-assembly process of tetraphenoxy-substituted perylene bisimide dyes into J-aggregates via hydrogen bonds is investigated in three different polymer matrices resulting in solid-state materials with fluorescence quantum yields up to 28%.

Graphical abstract: Perylene bisimide J-aggregates in a polymer matrix: controlling self-assembly and fluorescence properties
Open Access Accepted Manuscript - Paper

Halogen-Bonded Ionic Liquid Crystals: Supramolecular Organization and Ionic Transport

Open Access Paper

Immunomodulatory and tumor-targeting palladium nanoparticles functionalized with resveratrol via green nanotechnology: synthesis, mechanisms, and in vivo therapeutic evaluation

Resveratrol functionalized palladium nanoparticles (Res-PdNPs) inhibit NF-κB, reprogram tumor-associated macrophages from the M2 to the M1 phenotype, and enhance in vivo anti-tumor activity.

Graphical abstract: Immunomodulatory and tumor-targeting palladium nanoparticles functionalized with resveratrol via green nanotechnology: synthesis, mechanisms, and in vivo therapeutic evaluation
Paper

Low clearing asymmetric BTBT mesogens with perfect ambipolar charge transport

A perfectly ambipolar balanced charge carrier mobility has been found for a cyano-substituted BTBT mesogen.

Graphical abstract: Low clearing asymmetric BTBT mesogens with perfect ambipolar charge transport
Accepted Manuscript - Paper

Plant-Derived Cellulose Nanocrystals as Pre-alignment Layer for Ferroelectric Mesogens in Display Applications

Open Access Accepted Manuscript - Paper

Multi-stimuli-responsive Degradable Boronic Ester-Crosslinked E-spun Nanofiber Wound Dressings

Paper

Phenoxazine-based ambipolar luminescent room-temperature liquid crystals capable of being used in bioimaging applications

A new class of phenoxazine-based luminescent liquid crystal molecules exhibiting room temperature liquid crystallinity, ambipolar charge carrier mobility which also can be used for bioimaging were synthesized.

Graphical abstract: Phenoxazine-based ambipolar luminescent room-temperature liquid crystals capable of being used in bioimaging applications
Open Access Paper

Polarity from the bottom up: a computational framework for predicting spontaneous polar order

The spontaneous long-range mutual orientation of their electric dipole moments that gives rise to polar liquid crystals is shown to result from subtle intermolecular interactions.

Graphical abstract: Polarity from the bottom up: a computational framework for predicting spontaneous polar order
Open Access Paper

Tuning the liquid crystal behavior of subphthalocyanines: effects of substitution, chirality, and hydrogen bonding

We demonstrate that the liquid crystal behavior of subphthalocyanine bowl-shaped aromatics is governed by their chirality and the number and nature of peripheral substituents.

Graphical abstract: Tuning the liquid crystal behavior of subphthalocyanines: effects of substitution, chirality, and hydrogen bonding
Paper

Chromogenic ecdysis of Au@Ag nanorods assembled in a hydrogel for selective detection of ammonia vapors in food

A chromogenic hydrogel sensor containing Au-Bead@Ag nanorods incorporated inside agarose gel for visual detection of ammonia released from spoiled food.

Graphical abstract: Chromogenic ecdysis of Au@Ag nanorods assembled in a hydrogel for selective detection of ammonia vapors in food
Open Access Paper

Systematic investigation on unsymmetrical mesogenic cyanobiphenyl dimers towards optical storage devices: synthesis, mesomorphic, photo switching and DFT studies

This research presents the synthesis and analysis of a novel series of mesogenic dimers comprising cyanobiphenyl and azonaphthyl units.

Graphical abstract: Systematic investigation on unsymmetrical mesogenic cyanobiphenyl dimers towards optical storage devices: synthesis, mesomorphic, photo switching and DFT studies
Open Access Paper

Heliconical smectic phases with transversal polar order

Helicity and polar order in bent-core liquid crystals. Fundamental insights into the synergistic roles of electrostatic energy, transient molecular helicity, and phase structure in controlling heliconical twist of achiral bent-core molecules.

Graphical abstract: Heliconical smectic phases with transversal polar order
Open Access Paper

The effect of templating on the mechanical properties of smectic liquid crystal elastomers

In this work, the effect of phase templating on the mechanical properties of smectic liquid crystal elastomers is examined. Samples polymerised in the nematic phase show markedly different properties to those polymerised in the smectic phase.

Graphical abstract: The effect of templating on the mechanical properties of smectic liquid crystal elastomers
Paper

Capturing the sol and gel states of thermoresponsive poly(2-oxazoline)/-(2-oxazine) hydrogels by ambient and subambient solid-state NMR

Two variants of pMeOx-b-pPheOzi-b-pMeOx with methyl or methoxy substituents were synthesized and used to test different NMR techniques for their characterization. Sample freezing provided new insights into the structure and different types of water.

Graphical abstract: Capturing the sol and gel states of thermoresponsive poly(2-oxazoline)/-(2-oxazine) hydrogels by ambient and subambient solid-state NMR
Paper

The balance between paraelectricity and ferroelectricity in non-chiral smectic homologs

Minimal structural modifications in non-chiral liquid crystals impact ferroelectricity, revealing key structure–property relationships. The findings highlight the potential for developing ferroelectric mixtures with broad application relevance.

Graphical abstract: The balance between paraelectricity and ferroelectricity in non-chiral smectic homologs
Open Access Paper

Self-assembly and ambipolar charge transport in columnar phases of polynuclear gold isocyano–triphenylene complexes

An uncommon approach to the synthesis of ambipolar semiconductors based on di- and tri-nuclear gold isocyano–triphenylene complexes of the formula [(AuX)n(CN–C6H4–O–(CH2)6)n–TriPh] (n = 2, 3; X = Cl, C[triple bond, length as m-dash]C–Ph) is described.

Graphical abstract: Self-assembly and ambipolar charge transport in columnar phases of polynuclear gold isocyano–triphenylene complexes
Open Access Paper

Glycosylated polyplex micelles from oppositely charged block copolymers

We present a novel glycosylated polyplex micelle system derived from charged glycosylated block copolymers. This approach offers a promising pathway toward the design of more intricate glycosylated nanoparticles.

Graphical abstract: Glycosylated polyplex micelles from oppositely charged block copolymers
Paper

Circularly polarized luminescence with large dissymmetry factors based on perovskite and cholesteric liquid crystal polymer network films

Based on perovskite and CLCN films, colour tuning, large |glum| values, and handedness inversion of circularly polarized luminescence were achieved.

Graphical abstract: Circularly polarized luminescence with large dissymmetry factors based on perovskite and cholesteric liquid crystal polymer network films
Paper

Cellulose-based bioactive material and turmeric-impregnated flexible and biocompatible scaffold for bone tissue engineering applications

Cellulose-based cotton fabric impregnated with a bioactive material and turmeric acts as a flexible, biocompatible, eco-friendly, and cost-effective material for bone regeneration applications.

Graphical abstract: Cellulose-based bioactive material and turmeric-impregnated flexible and biocompatible scaffold for bone tissue engineering applications
Paper

Development of a novel polyelectrolyte complex nanocomposite of modified chitosan and karaya gum for co-delivery of 5-fluorouracil and curcumin for cancer therapy

A pH-responsive polyelectrolyte complex of trimethylchitosan and carboxymethylkaraya gum containing silver nanoparticles has been developed as a matrix material for co-delivery of the drugs, 5-fluorouracil and curcumin.

Graphical abstract: Development of a novel polyelectrolyte complex nanocomposite of modified chitosan and karaya gum for co-delivery of 5-fluorouracil and curcumin for cancer therapy
Paper

Extremely durable supercapacitor enabled by disordered porous carbon with a capacity retention up to 60 000 cycles

Porous carbon materials have been prepared through a salt template method. The as-fabricated supercapacitors show an excellent cycling stability. These supercapacitors hold great potential for application in the field of energy storage.

Graphical abstract: Extremely durable supercapacitor enabled by disordered porous carbon with a capacity retention up to 60 000 cycles
Paper

Reversible photomechanical actuators with liquid crystal polymer graphene oxide nanocomposites

This study quantifies the photomechanical actuation in LC242 nanocomposites doped with azo dye and graphene oxide. Optimized doping and UV curing achieve a 35° photo-induced bend with rapid response, advancing applications in smart materials.

Graphical abstract: Reversible photomechanical actuators with liquid crystal polymer graphene oxide nanocomposites
Paper

Nitrogen doped carbon quantum dots: a multifaceted carbon nanomaterial that interferes in an amyloid-forming trajectory

LAdN-CQDs have been used to inhibit fibril formation, display biocompatibility, reduce reactive oxygen species, and safeguard against apoptosis, indicating promise in neuroprotection.

Graphical abstract: Nitrogen doped carbon quantum dots: a multifaceted carbon nanomaterial that interferes in an amyloid-forming trajectory
Open Access Paper

Modifying the liquid crystalline chessboard tiling – soft reticular self-assembly of side-chain fluorinated polyphiles

Combining side-chain fluorination with core-fluorination provides access to new liquid crystalline honeycombs due to nano-segregation and competing tilt modes, either within or out of the crystallographic plane.

Graphical abstract: Modifying the liquid crystalline chessboard tiling – soft reticular self-assembly of side-chain fluorinated polyphiles
25 items

About this collection

Professor Dr Helmut Ringsdorf (30 July 1929 to 20 March 2023) was a prominent German chemist who departed on 20 March 2023 at the age of 93. During his entire scientific career, Professor Ringsdorf made significant contributions to the scientific community in the scientific domains of supramolecular chemistry, polymer science, materials science, and biocompatible materials. Professor Dr Helmut Ringsdorf's contributions have had a lasting impact on both fundamental science and practical applications, making him a highly respected figure in the scientific community. In gratitude for his scientific services, we present this honorary collection.

This collection is guest edited by Dr Dharmendra Pratap Singh (Université du Littoral Côte d'Opale (ULCO), France), Professor Dr Matthias Lehmann (University of Würzburg, Germany), Professor A.S. Achalkumar (IIT Guwahati, India), Professor Sandeep Kumar (Nitte Meenakshi Institute of Technology, India).

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