Issue 32, 2016

Halogen bonding between metal centers and halocarbons

Abstract

Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C–I⋯η1(Pt) halogen bonding and the bifurcated HI2C–I⋯η2(Pt–Cl) halogen bonding – the latter undergoes the thermally induced reversible HI2C–I⋯η2(Pt–Cl) ⇄ HI2C–I⋯η1(Pt) transformation – were observed and confirmed theoretically.

Graphical abstract: Halogen bonding between metal centers and halocarbons

Supplementary files

Article information

Article type
Communication
Submitted
03 פבר 2016
Accepted
16 מרץ 2016
First published
16 מרץ 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 5565-5568

Halogen bonding between metal centers and halocarbons

D. M. Ivanov, A. S. Novikov, I. V. Ananyev, Y. V. Kirina and V. Yu. Kukushkin, Chem. Commun., 2016, 52, 5565 DOI: 10.1039/C6CC01107A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements