Themed collection ChemComm 60th Anniversary Collection
Electrochemical deconstructive functionalization of arylcycloalkanes via fragmentation of anodically generated aromatic radical cations
This highlight summarises electrochemical approaches for the deconstructive functionalization of arylcycloalkanes via the fragmentation of anodically generated aromatic radical cations.
Chem. Commun., 2024,60, 11190-11201
https://doi.org/10.1039/D4CC03279A
Asymmetric electrophilic functionalization of amino-substituted heteroaromatic compounds: a convenient tool for the enantioselective synthesis of nitrogen heterocycles
The catalytic asymmetric electrophilic functionalization of the less reactive N-heteroaromatic compounds has been reported using the approach of the introduction of an exocyclic amino substituent.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03680H
Surface properties of carbon nitride materials used in photocatalytic systems for energy and environmental applications
We review what is known of the surface properties of carbon nitrides, increasingly popular photocatalysts, with a focus on hydrogen production and arsenic remediation.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03898C
Recent progress in asymmetric radical reactions enabled by chiral iron catalysts
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03047H
Macrocyclic receptors for anion recognition
Macrocyclic receptors play a pivotal role in molecular recognition and supramolecular chemistry. This review highlights recent advances in the design, synthesis, and applications of macrocyclic receptors specifically tailored for anion recognition.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04521A
Advancing the dynamic mechanical analysis of organic semiconductor materials
Dynamic mechanical analysis (DMA) is powerful for characterizing the mechanical properties of organic/polymeric semiconductors.
Chem. Commun., 2024,60, 10795-10804
https://doi.org/10.1039/D4CC03254C
Targeting sub-cellular organelles for boosting precision photodynamic therapy
In this review, recent advances and representative photosensitizers used in organelle targeted photodynamic therapy have been reviewed with a focus on organelle targeting strategies and organelle-mediated cell death signalling pathways.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC02702G
Stereochemistry of natural products from vibrational circular dichroism
VCD spectroscopy associated with DFT calculations is a powerful tool to unambiguously assign both the absolute configurations and conformations of chiral secondary metabolites directly in solution.
Chem. Commun., 2024,60, 10439-10450
https://doi.org/10.1039/D4CC02481H
Lithium metal based battery systems with ultra-high energy density beyond 500 W h kg−1
This highlight focuses on breakthroughs, future perspectives and applications of ultra-high-energy-density lithium-based battery systems beyond 500 W h kg−1, represented by systems such as Li–S/Se batteries, Li–gas batteries, Li–CFx batteries, etc.
Chem. Commun., 2024,60, 10245-10264
https://doi.org/10.1039/D4CC03177F
Photocatalytic decarboxylation of free carboxylic acids and their functionalization
This highlight article summarizes the complete development of photodecarboxylative functionalization of free carboxylic acids via a concerted single electron transfer (SET) or energy transfer (ET) pathways.
Chem. Commun., 2024,60, 9645-9658
https://doi.org/10.1039/D4CC03189J
Time-resolved serial femtosecond crystallography for investigating structural dynamics of chemical systems
This article highlights the expansion of time-resolved serial femtosecond crystallography (TR-SFX) to chemical systems by overcoming the challenges in SFX for small molecules.
Chem. Commun., 2024,60, 9472-9482
https://doi.org/10.1039/D4CC03185G
Functional implications of unusual NOS and SONOS covalent linkages found in proteins
Novel NOS linkages stabilize protein tertiary and quaternary structures and may be as prevalent as disulfide bonds. They regulate enzyme activity and have other important roles.
Chem. Commun., 2024,60, 9463-9471
https://doi.org/10.1039/D4CC03191A
Chiral 2D and quasi-2D hybrid organic inorganic perovskites: from fundamentals to applications
The field of chiral 2D and quasi-2D perovskite is reviewed highlighting the most important results to date and indicating future directions for advancement.
Chem. Commun., 2024,60, 9310-9327
https://doi.org/10.1039/D4CC03314K
Recent advances in dual photoredox/nickel catalyzed alkene carbofunctionalised reactions
Alkene carbofunctionalization reactions have great potential for synthesizing complex molecules and constructing complex structures in natural products and medicinal chemistry.
Chem. Commun., 2024,60, 8946-8977
https://doi.org/10.1039/D4CC02914C
Silk-based intelligent fibers and textiles: structures, properties, and applications
This review summarizes the hierarchical structure and multifaceted properties of natural silk fibers, and provides an in-depth analysis of their extensive applications in the realms of biomedicine and advanced smart fiber technology.
Chem. Commun., 2024,60, 7801-7823
https://doi.org/10.1039/D4CC02276A
Electrifying oxidation of ethylene and propylene
This highlight discusses the advantages of various oxidation methods for improved performance of the electrochemical oxidation of ethylene and propylene, and provides an overview of current challenges and problems requiring further efforts.
Chem. Commun., 2024,60, 6703-6716
https://doi.org/10.1039/D4CC02025A
Evolution of catalyst design for controlled synthesis of chiral single-walled carbon nanotubes
Three strategies to realize the chirality-controlled growth of SWCNTs are presented.
Chem. Commun., 2024,60, 6222-6238
https://doi.org/10.1039/D4CC01227E
Recent developments in photocatalytic production of hydrogen peroxide
This highlight article summarizes the recent developments and challenges in photocatalytic production of hydrogen peroxide and looks forward to the development direction of this field.
Chem. Commun., 2024,60, 5354-5368
https://doi.org/10.1039/D4CC01577K
Recent advances in electrosynthesis of H2O2via two-electron oxygen reduction reaction
This review provides an electrosynthesis strategy of H2O2via the 2e− ORR, covering aspects of reaction mechanisms, performance assessment, catalyst engineering, and setups for scaling up H2O2 production.
Chem. Commun., 2024,60, 5232-5244
https://doi.org/10.1039/D4CC01476F
CRISPR/Cas systems combined with DNA nanostructures for biomedical applications
DNA nanostructures are easy to design and construct, have good biocompatibility, and show great potential in biosensing and drug delivery when combined with CRISPR/Cas systems.
Chem. Commun., 2024,60, 3098-3117
https://doi.org/10.1039/D4CC00290C
Recent advances in metal carbene-induced semipinacol rearrangements
This review provides a complete overview of the advances in the semipinacol rearrangement-mediated 1,2-group migration onto metal carbene centers which were reported in the past decades.
Chem. Commun., 2024,60, 11253-11266
https://doi.org/10.1039/D4CC03252G
Organoboron catalysis for direct amide/peptide bond formation
This review explores studies on the development of direct dehydrative amide/peptide bond formation from carboxylic acids using organoboron catalysis.
Chem. Commun., 2024,60, 11202-11222
https://doi.org/10.1039/D4CC02994A
Progress on critical cell fabrication parameters and designs for advanced lithium–sulfur batteries
This feature article examines recent lithium–sulfur studies, with a focus on high-loading sulfur cathodes in lean-electrolyte and solid state-electrolyte cells, and highlights recent achievements, challenges, and strategies for future research.
Chem. Commun., 2024,60, 11017-11033
https://doi.org/10.1039/D4CC03085K
Luminescent lanthanide metallopeptides for biomolecule sensing and cellular imaging
Lanthanide ions display unique luminescent properties, such as long-lived excited states and relatively narrow emission bands, that make them particularly attractive for the development of bioprobes in combination with peptides.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03205E
Recent progress in electrochemical C–N coupling: metal catalyst strategies and applications
This paper's innovation lies in systematically summarizing and evaluating the latest metal catalyst design strategies and exploring their application in nitrogen sources.
Chem. Commun., 2024,60, 10822-10837
https://doi.org/10.1039/D4CC03256J
Europium(II/III) coordination chemistry toward applications
This article describes applications of Eu, including MRI, luminescence, catalysis, and separation science.
Chem. Commun., 2024,60, 10655-10671
https://doi.org/10.1039/D4CC03080J
Productive chemistry induced by mechanochemically generated macroradicals
Mechanochemical backbone fracture by homolysis of covalent bonds generates highly reactive macroradicals, providing potential strategy to form new load-bearing bonds enabling new synthetic applications and development of stress-responsive polymers.
Chem. Commun., 2024,60, 10629-10641
https://doi.org/10.1039/D4CC03206C
Spectrometric monitoring of CO2 electrolysis on a molecularly modified copper surface
Recent works on in situ monitoring of organically modified copper with vibrational spectroscopy have revealed a wide scale of effect modifiers can cause on CO2 electrolysis performance, which can also help design active organic/copper interface.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03973D
Mechanically interlocked host systems for ion-pair recognition
This review details utilising mechanically interlocked host molecules containing cation and anion binding motifs to achieve ion-pair recognition.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03916E
New insights into coordination-cage based catalysis
Recent work on catalysed reactions using coordination cage hosts, including new mechanistic insights and reactions types, is reviewed.
Chem. Commun., 2024,60, 10464-10475
https://doi.org/10.1039/D4CC03678F
Synthesis and catalytic application of nanostructured metal oxides and phosphates
This work summarizes catalyst design methodologies based on crystalline complex oxide nanostructures through the synthesis, catalytic application, and structure–activity relationship.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03233K
DNA-modulated dimerization and oligomerization of cell membrane receptors
Versatile DNA nanodevices that modulate membrane receptor aggregation and reprogram cell signaling with high precision and programmability.
Chem. Commun., 2024,60, 10265-10279
https://doi.org/10.1039/D4CC03077J
Strategies in photochemical alcohol oxidation on noble-metal free nanomaterials as heterogeneous catalysts
We highlight the challenges and recent progress in using semiconductors to harvest solar energy for carrying out alcohol oxidation.
Chem. Commun., 2024,60, 10295-10305
https://doi.org/10.1039/D4CC01204F
Transition metal oxide clusters: advanced electrocatalysts for a sustainable energy future
This article summarizes small-sized transition metal oxide (TMO) clusters for electrocatalysis. The synergistic actions between TMO and TM–Nx sites and mechanisms by DFT studies are comprehensively highlighted.
Chem. Commun., 2024,60, 9918-9929
https://doi.org/10.1039/D4CC02722A
Recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters
This feature article comprehensively summarizes the recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03788J
Supramolecular chemical biology: designed receptors and dynamic chemical systems
Supramolecular approaches to face chemical biology problems targeting different types of species are illustrated with selected representative examples, using conventional receptor design or dynamic covalent chemistry.
Chem. Commun., 2024,60, 9692-9703
https://doi.org/10.1039/D4CC03163F
Recent progress in transition metal complexes featuring silylene as ligands
This review highlights recent advances in transition metal complexes of silylene, showcasing their efficacy in hydroboration, hydrosilylation, hydrogenation, hydrogen isotope exchange, and small molecule activation chemistry.
Chem. Commun., 2024,60, 9483-9512
https://doi.org/10.1039/D4CC01930J
Unveiling the potential of triphenylphosphine salts in tuning organic room temperature phosphorescence
This article summarizes the potential of TPP salts in tuning RTP properties and their applications in multi-level information encryption, high-level anticounterfeiting tags, and X-ray scintillators.
Chem. Commun., 2024,60, 9328-9339
https://doi.org/10.1039/D4CC03156C
Cascading responses of stimuli-responsive materials
Cascading responses are a new concept for integrating stimulus-responsive materials to obtain output responses from the original input stimulus through successive conversions of the stimuli in a system.
Chem. Commun., 2024,60, 9163-9176
https://doi.org/10.1039/D4CC02827A
Spin characteristics in conjugated stable diradicals
The burgeoning interest in stable conjugated diradicals is attributed to their distinctive spin characteristics. In this review, we emphasize how to precisely control these spin characteristics to understand their role in the molecules and as functional radical materials.
Chem. Commun., 2024,60, 8997-9006
https://doi.org/10.1039/D4CC03067B
Zirconium-based metal–organic frameworks and their roles in electrocatalysis
This article discusses the roles of Zr-MOFs in electrocatalysis, and the challenges and opportunities in using Zr-MOFs in electrocatalytic applications.
Chem. Commun., 2024,60, 8360-8374
https://doi.org/10.1039/D4CC02793K
Advances and challenges in molecular engineering of 2D/3D perovskite heterostructures
Advances in the understanding and applications of perovskite 2D/3D heterostructures were overviewed with a focus on ligand design principles.
Chem. Commun., 2024,60, 7824-7842
https://doi.org/10.1039/D4CC02299H
Organocatalysis as an enabling tool for enantioselective ring-opening reactions of cyclopropanes
In this article we disclose our contributions to use of cyclopropanes as unconventional reagents for the development of enantioselective transformations under different organocatalytic activation manifolds for the synthesis of chiral building blocks.
Chem. Commun., 2024,60, 7288-7298
https://doi.org/10.1039/D4CC01933D
Uncovering tetrazoles as building blocks for constructing discrete and polymeric assemblies
This review introduces tetrazoles as the building blocks. The tetrazole ring offers four nitrogens, thereby assisting in multiple binding sites. The consequence is usually polymeric networks, but meticulous stratagem can form discrete cages as well.
Chem. Commun., 2024,60, 5573-5585
https://doi.org/10.1039/D4CC01616E
Transition metal-based electrocatalysts for alkaline overall water splitting: advancements, challenges, and perspectives
This review has examined the advancements and challenges in the development of transition metal-based electrocatalysts for the alkaline water splitting reaction in the last decade.
Chem. Commun., 2024,60, 5104-5135
https://doi.org/10.1039/D3CC06015B
Asymmetric phthalocyanine-based hole-transporting materials: evaluating the role of heterocyclic units and PMMA additive
ZnPcs with pyridine or imidazole units were synthesized as HTMs in PSCs. PMMA addition improved performance and stability, reaching 16.2% PCE for ZnPc-1.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03739A
Hydroxylation boosted low-overpotential CO2 reduction to ethylene for Cu/PTFE electrode
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03845B
NRAS DNA G-quadruplex-targeting molecules for sequence-selective enzyme inhibition
Sequence-selective G-quadruplex ligands are valuable for controlling gene expression.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03753G
Substituent-dependent [4+2] or [2+2] cycloadditions of phenylallenyl phosphine oxides with arynes
A substituent-dependent synthetic strategy to precisely convert easily accessible phenylallenyl phosphine oxides into phenanthren-9-yldiphenylphosphine oxides and benzo[b][1,4]oxaphosphinin-4-iums is reported.
Chem. Commun., 2024,60, 11343-11346
https://doi.org/10.1039/D4CC03507K
From Li2NiO3 to high-performance LiNiO2 cathodes for application in Li-ion and all-solid-state batteries
Thermal decomposition of overlithiated Li1+xNi1−xO2 yields high-quality LiNiO2 cathode materials that show potential for application in different kinds of batteries.
Chem. Commun., 2024,60, 11355-11358
https://doi.org/10.1039/D4CC03873H
Hypervalent zinc(I) complexes with an NNNN-macrocycle: C–H bond activation across the zinc(I)–zinc(I) bond
The heteroleptic complex [(Me4TACD)Zn–ZnCp*]+ (Me4TACD = N,N′,N′′,N′′′-1,4,7,10-tetramethylcyclododecane) reacts with activated C–H bonds to give the corresponding hydrocarbyl zinc(II) complex [(Me4TACD)ZnR]+ (R = CH2CN, CCPh).
Chem. Commun., 2024,60, 11359-11362
https://doi.org/10.1039/D4CC04266B
Polyoxometalate-incorporated NiFe-based oxyhydroxides for enhanced oxygen evolution reaction in alkaline media
NiFe–PMA/CNTs homogeneous/heterogeneous hybrid catalyst exhibits low overpotential and a high TOF for the oxygen evolution reaction.
Chem. Commun., 2024,60, 11287-11290
https://doi.org/10.1039/D4CC03874F
PdPt/SrTiO3:Al-catalysed redox-selective photoreduction of unsaturated carboxylic acids using minimal electron-donor and water
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03791J
Luminescent macroporous aerogels of two-dimensional nanocrystals of metal halide perovskites with adjustable semiconducting bandgaps
Semiconducting aerogels with tunable luminescence and photocurrent responses were fabricated by freeze-drying of colloidal cyclohexane dispersions of metal halide perovskites.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03511A
Topological control in paddlewheel metal–organic cages via ligand length variation
Extending the length of phenanthrene-based ligands directs the selective assembly of paddlewheel metal–organic cages into tetrahedral, square, or triangular topologies.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03769C
Fluorine-18 incorporation and radiometal coordination in macropa ligands for PET imaging and targeted alpha therapy
The development of theranostic agents for radiopharmaceuticals based on therapeutic alpha emitters marks an important clinical need.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04165H
Phosphination of Aryl/Alkyl Bromides via Mn-Mediated Reductive C-P Coupling
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC04750H
Photocatalytic CO2 Reduction to CO Catalysed by Lanthanide Complexes
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03175J
Hierarchical (Ni,Co)0.85Se sheets for efficient oxygen evolution reaction electrocatalysis: a combined approach of fabrication control and mechanistic understanding
Controlled fabrication of porous (Ni,Co)0.85Se sheets improves OER performance through optimized electronic properties and enhanced kinetics.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04285A
Tailoring helical ends of π-extended [6]heterohelicenes to control optical, and electrochemical features
The inherent helical chirality and improved π-stacking capabilities endow helicenes with fascinating photophysical characteristics when decorated with heteroatoms.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03707C
Dye self-organization in doped silica nanoparticles increases the electrochemiluminescence emission in magnetic bead-based assays
The charge of different Ru(II) Electro-Chemi-Luminescent complexes drives their self-organization inside doped silica nanoparticles, increasing the generated ECL signal in a magnetic microbeads-based immunoassay model.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03488K
Efficient multicolour and white circularly polarized luminescence from liquid crystalline polymer networks
Several liquid crystalline polymer network films with bright multicolour and white circularly polarized luminescence have been fabricated, which exhibit luminescence dissymmetry factors up to 0.85 and fluorescence quantum yields up to 90%.
Chem. Commun., 2024,60, 11096-11099
https://doi.org/10.1039/D4CC02966F
A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis
A highly crystalline and robust Zr-hydroxamate MOF was made from a pyrazine-derived ligand. Featuring abundant chelating sites which were readily metalated with a high Pd loading, the MOF became a versatile and recyclable Suzuki–Miyaura catalyst.
Chem. Commun., 2024,60, 11100-11103
https://doi.org/10.1039/D4CC03895A
Unusual defect properties of the one-dimensional photovoltaic semiconductor selenium
We demonstrate the intrinsic benign point defect properties of the one-dimensional photovoltaic semiconductor Se through a detailed theoretical investigation.
Chem. Commun., 2024,60, 11092-11095
https://doi.org/10.1039/D4CC03174A
Carbene and photocatalyst-catalyzed 3-acylation of indoles for facile access to indole-3-yl aryl ketones
A carbene and photocatalyst-catalyzed 3-acylation of indoles was disclosed, providing access to indole-3-yl aryl ketones, which play important roles in both organic synthesis and diverse types of functional molecules.
Chem. Commun., 2024,60, 11088-11091
https://doi.org/10.1039/D4CC03257H
Direct observation of arene⋯sulphur dioxide interaction: role of metal ions in electronic modulation for binding and activation
In a quest to understand bio-inspired interactions of SO2 with hosts, we have observed the lone pair⋯π interaction between the aromatic ring and O of SO2 (3.11 Å), in addition to the interaction between S of SO2 and metal-bound thiolate (2.63 Å).
Chem. Commun., 2024,60, 11104-11107
https://doi.org/10.1039/D4CC02329C
The synthesis of polydopamine nano- and microspheres in microdroplets
Polydopamine nano- and microspheres, with aminochrome as the principal building block, were rapidly and controllably synthesized in microdroplets.
Chem. Commun., 2024,60, 11068-11071
https://doi.org/10.1039/D4CC03017F
syn-1,2-Diaminobenzocyclobutenes from [2+2] cycloaddition of 2-imidazolones with arynes
Formal [2+2] cycloaddition between arynes and 2-imidazolones furnishes syn-1,2-diaminobenzocyclobutenes.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04023F
Film-electrochemical EPR spectroscopy to investigate electron transfer in membrane proteins in their native environment
Film-electrochemical electron paramagnetic resonance spectroscopy (FE-EPR) enables investigation of electron transfer in membrane proteins in their native membrane environment.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04013A
Orally bioavailable STING antagonist synthesized via multi-component Povarov–Doebner type reaction
Aberrant activation of the cGAS-STING signaling results in innate immune response induction.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03228D
About this collection
ChemComm is publishing its 60th volume in 2024. Over the past 60 years, ChemComm has been the RSC’s most cited journal, and one of the most trusted venues for rapid publication of short communications. In our anniversary year, we recognise the important contributions ChemComm has made, and continues to make, in advancing the chemical sciences.
This collection brings together the latest research from some of our most loyal and dedicated authors, who have taken this journey with us. From those marking the beginning of their independent academic career by publishing their first article with us, to the rising stars and established leaders publishing in our yearly ‘Emerging Investigators’ and ‘Pioneering Investigators’ collections, this collection champions the contributions of our worldwide author community.
We are proud many authors choose to support our journal by regularly publishing their best work with us. This collection also features papers from our ChemComm Emerging Investigator Lectureship winners, and our Outstanding Reviewer awardees, whose invaluable feedback has shaped our published content through the years.