Themed collection Energy & Environmental Science Recent HOT Articles, 2025

Designing next-generation all-weather and efficient atmospheric water harvesting powered by solar energy
We propose a next-generation solar-powered hybrid atmospheric water harvesting system for all-weather and efficient water production worldwide, which leverages the advantages of complementary AWH mechanisms with synergistic integration of heat pump.
Energy Environ. Sci., 2025,18, 7005-7022
https://doi.org/10.1039/D5EE01454A
Micro-sized CVD-derived Si–C anodes: challenges, strategies, and prospects for next-generation high-energy lithium-ion batteries
The development of high-capacity anodes is of paramount importance to address the rapidly increasing demand for high-energy-density lithium-ion batteries (LIBs).
Energy Environ. Sci., 2025,18, 4037-4052
https://doi.org/10.1039/D5EE01568E
Challenges in membrane electrode assemblies at elevated temperatures for proton exchange membrane fuel cells: a review
Elevated temperatures within membrane electrode assemblies (MEAs) have gained considerable attention, but current methodologies face significant challenges in ensuring the stable, long-term operation of MEAs at elevated temperatures.
Energy Environ. Sci., 2025,18, 6934-6982
https://doi.org/10.1039/D5EE01108F

Opportunities and challenges for emerging inorganic chalcogenide–silicon tandem solar cells
This review highlights the potential of emerging inorganic chalcogenide–silicon tandem solar cells, which address efficiency and stability limitations of single-junction devices and offer a less-toxic, more stable alternative for tandem applications.
Energy Environ. Sci., 2025,18, 6899-6933
https://doi.org/10.1039/D4EE04526B
The route for applied interfacial solar vapor generation: fundamental principles, device design, and practical application
A comprehensive framework for interfacial solar vapor generation (ISVG) is proposed, integrating fundamental scientific principles and regulation-centered strategies across solar absorption, mass transfer, anti-fouling and practical applications.
Energy Environ. Sci., 2025,18, 6366-6437
https://doi.org/10.1039/D5EE01542A
Stretching the future: strategies and emerging trends in stretchable organic photovoltaic materials
This review consolidates the latest advancements in stretchable organic photovoltaic (s-OPV) materials, providing a comprehensive overview of the field's progress.
Energy Environ. Sci., 2025,18, 6344-6365
https://doi.org/10.1039/D5EE01504A

Polymeric membranes in carbon capture, utilization, and storage: current trends and future directions in decarbonization of industrial flue gas and climate change mitigation
Material, process, and computational developments for polymeric membrane-assisted decarbonization.
Energy Environ. Sci., 2025,18, 5025-5092
https://doi.org/10.1039/D4EE05328A
Recent advances in perovskite air electrode materials for protonic solid oxide electrochemical cells
A review highlights recent advances in intermediate-temperature P-SOCs, focusing on perovskite air electrodes, their triple-conducting mechanisms, material design via AI and theory, and prospects for industrial applications.
Energy Environ. Sci., 2025,18, 4555-4595
https://doi.org/10.1039/D5EE00983A
Corrosion of metallic anodes in aqueous batteries
This review thoroughly discusses the corrosion behaviors of various metallic anodes in aqueous metal batteries. It also provides a comprehensive overview of corrosion prevention tactics and characterization methods.
Energy Environ. Sci., 2025,18, 2050-2094
https://doi.org/10.1039/D5EE00075K
Catalyst–electrolyte interface engineering propels progress in acidic CO2 electroreduction
The acidic CO2RR is an alternative to the alkaline/neutral CO2RR, mitigating carbonate formation and carbon crossover. This review covers its history, evaluation, advances and challenges, focusing on catalyst–electrolyte interface engineering.
Energy Environ. Sci., 2025,18, 2025-2049
https://doi.org/10.1039/D4EE05715E

A carbon cathode for lithium mediated electrochemical ammonia synthesis
To introduce the potential for tuneability of the cathode in lithium mediated ammonia synthesis, we report a carbon cathode which produces ammonia at a Faradaic efficiency of 37%.
Energy Environ. Sci., 2025,18, 5897-5901
https://doi.org/10.1039/D4EE05669H
Tailoring a multilayer fine-grained solid electrolyte interphase by pulse electrochemical activation maneuver for stable Si/C anodes
The fine-grained SEI layer was designed through the modulation of pulsed electrochemical activation to enhance the electrochemical performance of Si/C anodes.
Energy Environ. Sci., 2025,18, 7060-7070
https://doi.org/10.1039/D5EE02060C

Near-cryogenic direct air capture using adsorbents
Molecular simulations, experiments, and techno-economic analysis propose cost-efficient direct air capture at near-cryogenic temperatures via LNG regasification integration.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D5EE01473E

Carbon footprint of oil produced through enhanced oil recovery using carbon dioxide directly captured from air
Can oil production be carbon neutral? A general top-down analysis shows that DAC CO2-EOR may seem so if only the EOR phase is considered—but full reservoir life cycle accounting reveals that true carbon neutrality is physically unachievable.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D5EE01752A
Polarity coupling in biphasic electrolytes enables iodine/polyiodide co-extraction for portable Zn–iodine batteries following a liquid–liquid conversion route
A biphasic (BP) electrolyte system composed of two immiscible solutions of Zn(TFSI)2 in EA and ZnSO4/KI in water is designed to address the key issues existing in Zn–iodine batteries.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D5EE02593A
Dynamic disulfide bond networks enable self-healable and mechanically resilient intrinsically stretchable organic solar cells
A dynamic disulfide network introduced into donor/acceptor blends enables room-temperature self-healing and mechanical resilience in intrinsically stretchable organic solar cells, achieving performance recovery after high mechanical strain.
Energy Environ. Sci., 2025,18, 6597-6607
https://doi.org/10.1039/D5EE01082A
Immediate remaining capacity estimation of heterogeneous second-life lithium-ion batteries via deep generative transfer learning
This work proposes a novel deep generative transfer learning algorithm to estimate the relative remaining capacity of second-life batteries using minimal field data, enabling safe and sustainable reuse under data scarce and heterogeneous conditions.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D5EE02217G

Over one-micron-thick void-free perovskite layers enable highly efficient and fully printed solar cells
Guided by phase-field simulations, a pre-coated 2D perovskite layer enables the growth of void-free perovskite layers over one-micron-thick, achieving high-efficiency, fully printed solar cells.
Energy Environ. Sci., 2025,18, 5926-5939
https://doi.org/10.1039/D5EE01722J
Sustaining vacancy catalysis via conformal graphene overlays boosts practical Li–S batteries
A vacancy catalysis sustainer using directly grown graphene mitigates the detrimental coverage on active sites and promotes the preferential decomposition of anions, thereby achieving long-life Li–S batteries.
Energy Environ. Sci., 2025,18, 5940-5951
https://doi.org/10.1039/D5EE01134E
Ligand effects enhancing low-temperature oxygen reduction kinetics in neutral conditions
The local PO microenvironment activates the adjacent C atom to modulate the oxygen adsorption through the Yeager model, thereby enhancing the ORR kinetics even in hostile environments with low temperatures and proton concentrations.
Energy Environ. Sci., 2025,18, 5298-5308
https://doi.org/10.1039/D5EE01407G

Unlocking high-performance photocapacitors for edge computing in low-light environments
Integrating dye-sensitized solar cells with polyviologen-based supercapacitors enables efficient ambient light harvesting and storage, achieving 30% power conversion efficiency under indoor lighting conditions to power edge computing IoT networks.
Energy Environ. Sci., 2025,18, 4704-4716
https://doi.org/10.1039/D5EE01052G
The spontaneous cascade optimization strategy of the double enrichment improves anion-derived solid electrolyte interphases to enable stable lithium-metal batteries
The spontaneous cascade optimization strategy facilitates the maximization of TFSI− anion decomposition by enhancing both anion and charge enrichment.
Energy Environ. Sci., 2025,18, 4690-4703
https://doi.org/10.1039/D5EE01219H
Regulation of the cathode inner Helmholtz plane in dilute ether electrolytes using an electric-field-responsive solvent for high-voltage lithium metal batteries
Herein, we demonstrate that the battery intrinsic electric field drives the specific adsorption of a weakly solvated co-solvent, DTS, to replace conventional DME in the IHP, enabling the desirable CEI chemistry on the 4.6 V LiCoO2 cathode.
Energy Environ. Sci., 2025,18, 4677-4689
https://doi.org/10.1039/D4EE05818F
High-performance inverted perovskite solar cells and modules via aminothiazole passivation
A multifunctional additive 5ATCl is explored to passivate the undesirable defects of perovskites, which enables high-quality perovskite films and thus demonstrates impressive VOC × FF value for both rigid and flexible inverted perovskite solar cells.
Energy Environ. Sci., 2025,18, 4120-4129
https://doi.org/10.1039/D5EE01083G

Operando single-particle imaging reveals that asymmetric ion flux contributes to capacity degradation in aged Ni-rich layered cathodes
Using an operando optical scattering technique, we identify markedly asymmetric Li-ion flux in aged single crystalline NMC cathodes, primarily caused by an uneven growth of rocksalt phase across the particle surface.
Energy Environ. Sci., 2025,18, 4097-4107
https://doi.org/10.1039/D5EE00267B
Comprehensive crystallization retardation of inorganic perovskites for high performance inverted solar cells
Acrylonitrile–methyl acrylate is added to the perovskite precursor to retard the crystallization of inorganic perovskites, yielding a record efficiency of 21.7% for inverted inorganic PSCs, together with substantially improved operational stability.
Energy Environ. Sci., 2025,18, 4130-4141
https://doi.org/10.1039/D5EE00149H
Synchronous dimension-crystallization engineering enables highly efficient 2D/3D tin perovskite solar cells
Both the crystalization and 2D phases of 2D/3D tin perovskite films are regulated by introducing additives that affect the intermediate adduct and PEA adsorption, which effectively boost the PCE of tin perovskite solar cells up to 15.02%.
Energy Environ. Sci., 2025,18, 4108-4119
https://doi.org/10.1039/D4EE06142J

Industrially viable formate production with 50% lower CO2 emissions
The modulation of platinum valence states facilitates an industrially viable production of formate from methanol e-refinery, achieving a 50% reduction in CO2 emissions.
Energy Environ. Sci., 2025,18, 3680-3688
https://doi.org/10.1039/D5EE00452G
Buried and bulk synergistic engineering enables high-performance inverted 2D/3D perovskite solar cells
A buried and bulk synergistic strategy was developed to improve perovskite film quality. Optimizing the buried interface using FuMACl and bulk using (DFP)2PbI4 seeds led to a champion photovoltaic efficiency of 26.03% and a fill factor of 86.79%.
Energy Environ. Sci., 2025,18, 3740-3749
https://doi.org/10.1039/D5EE00156K

Modular perovskite-BiVO4 artificial leaves towards syngas synthesis on a m2 scale
Thermal evaporation enables the scalable production of 10 cm2 perovskite-BiVO4 artificial leaves for unassisted syngas synthesis. A 10 × 10 device array has been demonstrated outdoors in a 0.35 m2 reactor for the EIC Horizon Prize “Fuel from the Sun”.
Energy Environ. Sci., 2025,18, 3623-3632
https://doi.org/10.1039/D4EE05780E
Defective 1T-VS2 with fibonacci pattern unlocking high mass-loading and self-charging cathodes for aqueous zinc-ion batteries
Defective 1T-VS2 with fibonacci pattern designed with a multi-scale strategy for high mass-loading and self-charging cathodes in aqueous zinc-ion batteries.
Energy Environ. Sci., 2025,18, 3169-3176
https://doi.org/10.1039/D5EE00612K

Dual-plating aqueous Zn–iodine batteries enabled via halogen-complexation chemistry for large-scale energy storage
Very simple Ah-level aqueous batteries are realized by employing an X electrolyte which can fundamentally inhibit the polyiodide shuttle effect and zinc dendrite growth.
Energy Environ. Sci., 2025,18, 3160-3168
https://doi.org/10.1039/D5EE00027K

Nylon electrolyte chemistry in high-energy Li-metal batteries
Polyamide (PA, Nylon), a classical polymer featuring oxidation-resistant amide linkages, has been reengineered as high-voltage polymer electrolytes compatible with Li-metal batteries.
Energy Environ. Sci., 2025,18, 2826-2838
https://doi.org/10.1039/D4EE05739B
Iron clusters and single atom sites cooperatively promote bifunctional oxygen reaction activity in ultra-stable flexible zinc–air batteries
Iron clusters coupled with single atom sites have been developed as bifunctional oxygen reaction electrocatalysts for constructing ultra-stable, flexible zinc–air batteries operable in a temperature range from +40 °C to −40 °C.
Energy Environ. Sci., 2025,18, 2839-2851
https://doi.org/10.1039/D4EE05508J
A comprehensive investigation of Sr segregation effects on the high-temperature oxygen evolution reaction rate
This work provides a comprehensive understanding of the Sr segregation from the bulk Sr deficiencies and surface Sr segregates, and their impacts on oxygen vacancy formation, oxygen ion mobility, and the rate of electrode reactions.
Energy Environ. Sci., 2025,18, 2273-2284
https://doi.org/10.1039/D4EE05056H

Superthermal solar interfacial evaporation is not due to reduced latent heat of water
Reduced latent heat of water in solar evaporating materials cannot explain superthermal rates due to the full energy balance and vapor kinetic limitations. New mechanistic studies need to be pursued to understand superthermal solar evaporation.
Energy Environ. Sci., 2025,18, 1707-1721
https://doi.org/10.1039/D4EE05591H
Molten salt electrolytes with enhanced Li+-transport kinetics for fast-cycling of high-temperature lithium metal batteries
A solvent-free molten salt electrolyte with enhanced Li+-transport kinetics was reported for high-temperature lithium batteries. The cation–cation concerted effect and inorganic CEI/SEI interphases endow fast-cycling and long-cycling abilities.
Energy Environ. Sci., 2025,18, 1696-1706
https://doi.org/10.1039/D4EE04657A