Issue 37, 2009
From the journal:

Chemical Communications

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds†‡

Carl W. Liskey,a   Carolyn S. Wei,a   Dale R. Pahlsa  and  John F. Hartwig*a  

* Corresponding authors

a Department of Chemistry, University of Illinois, 600 South Mathews Av, Urbana, USA
E-mail: Jhartwig@illinois.edu

Abstract

Iridium trisboryl complexes containing bisphosphine and bipyridine ligands and pinacolate and catecholate substituents on boron are reported. A large difference in reactivity towards the borylation of C–H bonds is observed for this series of trisboryl complexes, and this difference is attributed to the electron-donating properties of the pinacolate vs.catecholate groups, and the steric and electronic properties of bipyridinevs.bisphosphine ligands.

Graphical abstract: Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

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DOI
https://doi.org/10.1039/B913949D
Article type
Communication
Submitted
14 7 2009
Accepted
07 8 2009
First published
20 8 2009

Chem. Commun., 2009, 5603-5605

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Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

C. W. Liskey, C. S. Wei, D. R. Pahls and J. F. Hartwig, Chem. Commun., 2009, 5603 DOI: 10.1039/B913949D

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