Themed collection Celebrating the 100th Anniversary of Sun Yat-Sen University

This review delves into the application of phosphor-converted light-emitting diodes (pc-LEDs) in underwater optical communication and marine fishery, exploring the development strategies of phosphors tailored for the marine environment.

Successful construction of a bottom-up n–p homojunction within perovskite bulk films enables to enhance the photovoltaic performance of perovskite solar cells without relying on an electron transport layer.

The host–guest recognition system is incorporated into the core region of the 10–23 DNAzyme for precise regulation of its cleavage functionality in test tubes and living cells.

We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10⁻⁴ S cm⁻¹) and Li⁺ transference number (0.74), endowing solid LiFePO₄//Li batteries with excellent cyclability.

A photo-redox stereodivergent atom transfer radical addition of α-functionalized alkyl iodides to alkynes allows the selective and efficient synthesis of both E- and Z-iodoalkenes.

The synergetic effect between abrupt spin crossover and fluorescence is observed for the first time in an iron(III) complex.

This work introduces a rare example of CO₂R-to-CO coupled with 2e⁻WOR-to-H₂O₂, giving a total energy efficiency of 34%.

Mo₂C/MoS₂ heterostructure catalysts with hydrophilicity/aerophobicity are rapidly synthesized via carbothermal shock, demonstrating the accelerating alkaline HER kinetics.

The authors pioneer a photocatalytic system employing long-lived organic radicals for efficient organic pollutant degradation under ultralow light intensities, providing a foundation for practical photochemistry applications in pollution remediation.

The introduction of a halogen-bonded gate into a zeolite framework achieved molecular-sieving-like benzene separation from C₆ cyclic hydrocarbon mixtures.

The low-temperature photopatterning of soluble polyimide was realized by the photoinitiated thiol–ene reaction, providing a promising strategy for the development of high-performance, green and energy-saving PSPI materials.

The design of a carboxylate–pyridine–triazole integrated ligand, coupled with a strategy of “rivet” substitution and “hinge” linkage, facilitates the construction of the largest [Zn₅₄] cluster in a hierarchical supramolecular framework.

The coupling modes between azulene-based single molecule and electrode can be switched by the ion distribution in the electrochemical electric double layer.

A highly conserved G-quadruplex in STING promoter region has been verified and precisely targeted by CRISPR-mediated specificity, which can restrain STING expression and restore Aβ phagocytic capacity of microglia for treatment of Alzheimer's disease.

The doping of rare-earth element into NiFe-MOFs regulated the electronic property of active sites and optimized the adsorption energy of reaction intermediates, leading to superior performance for both alkaline freshwater and seawater splitting.

Metal–ligand cooperation (MLC) is an essential strategy in transition metal catalysis. Herein, we demonstrate a remote C–H bond cooperation strategy that enables the unprecedented homogeneous Ag(I)-catalyzed BH/HA reaction.

Efficient indolocarbazole based blue thermally activated delayed fluorescence emitters with aggregation-induced emission are presented, affording OLEDs with a high external quantum efficiency of 29.9%.

SynAsk is a chemistry-specific LLM platform, fine-tuned with domain data and integrated with in-house tools. It supports tasks like reaction prediction, retrosynthesis, and literature retrieval, advancing organic synthesis research.

N-heterocyclic vinyl (NHV) substituted diphosphaenones 3a,b [R–PP–C(O)–R, RNHV] have been isolated and crystallographically characterized. They not only exhibit a planar trans PP–CO configuration, but also show conjugated 1,4-addition.

An ultrathin polymer electrolyte with superior ionic conductivity and stable electrolyte/electrode interfaces enables a high-loading Li/NCM811 cell with a capacity retention of up to 71% after 400 cycles at a high cut-off voltage of 4.5 V.

A molecule-based ferroelectric [(CH₃)₃NCH₂CH₂Br][GaBr₄] (1), with a d₃₃ value of 331 pC N⁻¹, was synthesized. The power density of the 1@S-PDMS piezoelectric sensor, featuring optimized microstructures, is up to 490 μW cm⁻².

An unexpected finding of organic afterglow triggered by a paper (cellulose)-matrixed strategy was reported, which offers a novel host–guest afterglow system attributed to the Förster resonance energy transfer mechanism.

Eco-friendly chiral Mn complexes with Binapo ligands show red CPL (g_lum = 5.1 × 10⁻³) and efficient (EQE > 4% and g_EL = −8.5 × 10⁻³), outperforming many Pt and Ir-based devices, paving the way for sustainable materials.

The optical activity levels of metal centers govern the multi-mode emissions by manipulating the band alignments in hybrid metal halides.

Chain elongation and halogen substitution strategies are employed to synthesize low-melting-point bisphosphonium cation based metal halides, which can be used to fabricate highly stable glass scintillators.

We propose a nanocarbon-enabled hybridization strategy to construct pharmacologically cooperative nanodrugs for augmented cancer therapy based on pharmacophore hybridization in medicinal chemistry and the synthetic principles of nanocarbons.

A molecule-based ferroelectric, possessing the highest d₃₃ × g₃₃ values recorded to date, achieves a record power density of 120 μW cm⁻² in ferroelectric@PDMS PEGs, offering a viable method to enhance the electromechanical conversion coefficient.

A compact chemically driven [2]catenane rotary motor was designed for precise 360° unidirectional rotation utilizing a molecular pumping system. It operates in two phases: pumping induces a 180° rotation and discharging resets the motor.

A BODIPY-based silver cyclic trinuclear complex can be used as a photocatalyst for producing H₂O₂ either from pure water or from sea water with high photocatalytic activities in the absence of any additives.