Mesostructured material based on [Re6Te8(CN)6]4−cluster and Mn2+: a rational synthesis of hexagonal nonoxidic mesoscale material

Vo Vien; Min-Jung Suh; Seong Huh; Youngmee Kim; Sung-Jin Kim

doi:10.1039/B816000G

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Mesostructured material based on [Re₆Te₈(CN)₆]⁴⁻cluster and Mn²⁺: a rational synthesis of hexagonal nonoxidic mesoscale material†

Vo Vien,^a Min-Jung Suh,^a Seong Huh,^ab Youngmee Kim^a and Sung-Jin Kim*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Nano Science, Ewha Womans University, Seoul, Korea
E-mail: sjkim@ewha.ac.kr
Fax: +82 2 32773419
Tel: +82 2 3277 2350

^b Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin, Korea

Abstract

A new nonoxidic mesostructured material with highly ordered hexagonal symmetry, [C₁₆H₃₃N(CH₃)₃]₃Mn_0.5[Re₆Te₈(CN)₆], has been obtained through supramolecular assembly of [Re₆Te₈(CN)₆]⁴⁻clusters in the presence of a transition metal cation, Mn²⁺, with cetyltrimethylammonium bromide as a liquid crystal template under hydrothermal conditions.

This article is part of the themed collection: Celebrating the 75th Anniversary of the Korean Chemical Society (KCS)

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Supplementary files

Experimental details and EDX spectrum of theH-Re/Te/Mn PDF (366K)

Article information

DOI: https://doi.org/10.1039/B816000G
Article type: Communication
Submitted: 12 Sept. 2008
Accepted: 06 Nov. 2008
First published: 05 Dec. 2008

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Chem. Commun., 2009, 541-543

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Mesostructured material based on [Re₆Te₈(CN)₆]⁴⁻cluster and Mn²⁺: a rational synthesis of hexagonal nonoxidic mesoscale material

V. Vien, M. Suh, S. Huh, Y. Kim and S. Kim, Chem. Commun., 2009, 541 DOI: 10.1039/B816000G

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