Issue 14, 2009
From the journal:

Chemical Communications

Aromatic trifluoromethylation catalytic in copper†

Masahiro Oishi,a   Hideaki Kondoa  and  Hideki Amii*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe, Japan
E-mail: amii@kobe-u.ac.jp
Fax: +81-78-803-5799
Tel: +81-78-803-5799

Abstract

Cu(I)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.

Graphical abstract: Aromatic trifluoromethylation catalytic in copper

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Article information

DOI
https://doi.org/10.1039/B823249K
Article type
Communication
Submitted
24 Dec. 2008
Accepted
30 Janv. 2009
First published
23 Febr. 2009

Chem. Commun., 2009, 1909-1911

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Aromatic trifluoromethylation catalytic in copper

M. Oishi, H. Kondo and H. Amii, Chem. Commun., 2009, 1909 DOI: 10.1039/B823249K

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