Systematic headgroup engineering yields planarizable push–pull flipper probes that are ready for use in biology – stable, accessible, modifiable –, and affords non-trivial insights into chalcogen-bond mediated mechanophore degradation and fluorescence enhancement.
S. Soleimanpour, A. Colom, E. Derivery, M. Gonzalez-Gaitan, A. Roux, N. Sakai and S. Matile, Chem. Commun., 2016, 52, 14450 DOI: 10.1039/C6CC08771J
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