Recovering sensitivity lost through convection in pure shift NMR†
Elsa
Caytan, 
ab
Howard M.
Foster,
a
Laura
Castañar,
ac
Ralph W.
Adams,
a
Mathias
Nilsson
a
and
Gareth A.
Morris
*a
ab
Howard M.
Foster,
a
Laura
Castañar,
ac
Ralph W.
Adams,
a
Mathias
Nilsson
a
and
Gareth A.
Morris
*a
Abstract
Practical pure shift NMR experiments, especially on instruments equipped with cryoprobes, can sometimes give very disappointing results. Here we show for the first time that this is a consequence of signal loss due to sample convection, and demonstrate a simple adjustment to common pure shift NMR experiments that restores the lost signal.
- This article is part of the themed collections: Celebrating the 200th Anniversary of the University of Manchester and Celebrating the scientific accomplishments of RSC Fellows
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