Themed collection Flowable energy storage

16 items
Open Access Review Article

Zinc–iron (Zn–Fe) redox flow battery single to stack cells: a futuristic solution for high energy storage off-grid applications

Decoupling of energy and power; depth of discharge; flexible in design; high safety; recyclable.

Graphical abstract: Zinc–iron (Zn–Fe) redox flow battery single to stack cells: a futuristic solution for high energy storage off-grid applications
Open Access Review Article

Energy storage mechanism, advancement, challenges, and perspectives on vivid manganese redox couples

Manganese redox couples are a promising candidate for redox flow batteries due to their low cost, ecofriendliness, high standard reduction potential, and variable oxidation states.

Graphical abstract: Energy storage mechanism, advancement, challenges, and perspectives on vivid manganese redox couples
From the themed collection: Energy Advances Recent Review Articles
Open Access Paper

Solid bromine complexing agents: long-term solution for corrosive conditions in redox-flow battery

Herein, we report on a SOLID bromine complexing agent for bromine catholyte of redox-flow batteries. Phase separation from the electrolyte enables safe, efficient and stable energy storage for more than 250 cycles.

Graphical abstract: Solid bromine complexing agents: long-term solution for corrosive conditions in redox-flow battery
Open Access Paper

Influence of crossover on capacity fade of symmetric redox flow cells

Volumetrically unbalanced compositionally symmetric cell cycling with potentiostatic (CV) or galvanostatic-with-potential-hold (CCCV) protocols is a rigorous technique for evaluating the calendar lifetime of reactants for redox flow batteries.

Graphical abstract: Influence of crossover on capacity fade of symmetric redox flow cells
Open Access Paper

Tautomerism and nucleophilic addition influence the performance of aqueous organic redox flow batteries of chelidamic acid and chelidonic acid

The influence of tautomerism and nucleophilic addition on chelidamic acid and chelidonic acid, compounds with similar molecular weights but different hetero atoms, was investigated in aqueous organic redox flow batteries.

Graphical abstract: Tautomerism and nucleophilic addition influence the performance of aqueous organic redox flow batteries of chelidamic acid and chelidonic acid
From the themed collection: Flowable energy storage
Open Access Paper

Open circuit voltage of an all-vanadium redox flow battery as a function of the state of charge obtained from UV-Vis spectroscopy

A unique feature of redox flow batteries (RFBs) is that their open circuit voltage (OCV) depends strongly on the state of charge (SOC).

Graphical abstract: Open circuit voltage of an all-vanadium redox flow battery as a function of the state of charge obtained from UV-Vis spectroscopy
Open Access Paper

Electrochemical and spectroscopic characterisation of organic molecules with high positive redox potentials for energy storage in aqueous flow cells

We show that a number of ubiquitous organic molecules used as redox mediators and chemically sensing species can be used as positive couples in electrochemical energy storage.

Graphical abstract: Electrochemical and spectroscopic characterisation of organic molecules with high positive redox potentials for energy storage in aqueous flow cells
Open Access Paper

Quantitative local state of charge mapping by operando electrochemical fluorescence microscopy in porous electrodes

Operando confocal microscopy coupled with electrochemistry yields spatially and temporally resolved state of charge maps within porous electrodes.

Graphical abstract: Quantitative local state of charge mapping by operando electrochemical fluorescence microscopy in porous electrodes
From the themed collection: Research advancing UN SDG 13: Climate Action
Open Access Paper

Analysis of the impact of remote oxygen plasma treatment on the surface chemistry and electrochemical properties of graphite felt electrodes for redox flow batteries

Remote oxygen plasma is compared to conventional thermal activation of electrodes for flow batteries and their impact on the mass transport and charge transfer properties of the resulting carbons.

Graphical abstract: Analysis of the impact of remote oxygen plasma treatment on the surface chemistry and electrochemical properties of graphite felt electrodes for redox flow batteries
From the themed collection: Flowable energy storage
Open Access Paper

Optimization framework for redox flow battery electrodes with improved microstructural characteristics

This research aims to advance the field of vanadium redox flow batteries (VRFBs) by introducing a pioneering approach to optimize the microstructural characteristics of carbon cloth electrodes.

Graphical abstract: Optimization framework for redox flow battery electrodes with improved microstructural characteristics
Open Access Paper

Single-membrane pH-decoupling aqueous batteries using proton-coupled electrochemistry for pH recovery

Proton-coupled electrochemical reactions as proton pumps can facilitate in situ or ex situ pH recovery and capacity rebalancing within single-membrane pH-decoupling batteries.

Graphical abstract: Single-membrane pH-decoupling aqueous batteries using proton-coupled electrochemistry for pH recovery
Open Access Paper

Organized macro-scale membrane size reduction in vanadium redox flow batteries: part 2. Flow-field-informed membrane coverage distribution

Membranes are a critical component contributing to cost in flowing-electrolyte electrochemical systems. Flow-field-informed membrane reduction can be adopted to reduce performance compromise.

Graphical abstract: Organized macro-scale membrane size reduction in vanadium redox flow batteries: part 2. Flow-field-informed membrane coverage distribution
Open Access Paper

Bamboo charcoal as electrode material for vanadium redox flow batteries

We investigated bamboo electrodes for use in vanadium redox flow batteries. The electrodes showed promising electrochemical performance, wettability, and a channel structure suitable for vanadium electrolyte flow.

Graphical abstract: Bamboo charcoal as electrode material for vanadium redox flow batteries
Open Access Paper

An aqueous polysulfide redox flow battery with a semi-fluorinated cation exchange membrane

An economically viable thermally annealed cation exchange membrane for polysulfide-based redox flow batteries.

Graphical abstract: An aqueous polysulfide redox flow battery with a semi-fluorinated cation exchange membrane
Open Access Paper

In-plane gradient design of flow fields enables enhanced convections for redox flow batteries

This work proposes an in-plane gradient flow field design which enhances the under-rib convections for redox flow batteries. Furthermore, generalized structured approaches have been proffered for future scientific research.

Graphical abstract: In-plane gradient design of flow fields enables enhanced convections for redox flow batteries
From the themed collection: Flowable energy storage
Open Access Paper

Beyond energy density: flow battery design driven by safety and location

Using satellite imagery we show that the installation footprint of grid-scale lithium-ion batteries is often comparable to much less energy-dense technologies such as aqueous battery systems.

Graphical abstract: Beyond energy density: flow battery design driven by safety and location
From the themed collection: Flowable energy storage
16 items

About this collection

Flowable energy storage is a technology capable of addressing critical challenges in the energy landscape by offering scalable, durable and sustainable solutions.

This themed collection includes papers covering redox flow batteries (including lithium-sulfur, vanadium and aqueous organic systems), electrochemical flow capacitors, and component design for these systems.

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