Themed collection Flowable energy storage
Zinc–iron (Zn–Fe) redox flow battery single to stack cells: a futuristic solution for high energy storage off-grid applications
Decoupling of energy and power; depth of discharge; flexible in design; high safety; recyclable.
Energy Adv., 2024,3, 2861-2876
https://doi.org/10.1039/D4YA00358F
Energy storage mechanism, advancement, challenges, and perspectives on vivid manganese redox couples
Manganese redox couples are a promising candidate for redox flow batteries due to their low cost, ecofriendliness, high standard reduction potential, and variable oxidation states.
Energy Adv., 2023,2, 948-964
https://doi.org/10.1039/D3YA00102D
Solid bromine complexing agents: long-term solution for corrosive conditions in redox-flow battery
Herein, we report on a SOLID bromine complexing agent for bromine catholyte of redox-flow batteries. Phase separation from the electrolyte enables safe, efficient and stable energy storage for more than 250 cycles.
Energy Adv., 2025, Advance Article
https://doi.org/10.1039/D4YA00367E
Influence of crossover on capacity fade of symmetric redox flow cells
Volumetrically unbalanced compositionally symmetric cell cycling with potentiostatic (CV) or galvanostatic-with-potential-hold (CCCV) protocols is a rigorous technique for evaluating the calendar lifetime of reactants for redox flow batteries.
Energy Adv., 2024,3, 2910-2921
https://doi.org/10.1039/D4YA00407H
Tautomerism and nucleophilic addition influence the performance of aqueous organic redox flow batteries of chelidamic acid and chelidonic acid
The influence of tautomerism and nucleophilic addition on chelidamic acid and chelidonic acid, compounds with similar molecular weights but different hetero atoms, was investigated in aqueous organic redox flow batteries.
Energy Adv., 2024,3, 2778-2789
https://doi.org/10.1039/D4YA00331D
Open circuit voltage of an all-vanadium redox flow battery as a function of the state of charge obtained from UV-Vis spectroscopy
A unique feature of redox flow batteries (RFBs) is that their open circuit voltage (OCV) depends strongly on the state of charge (SOC).
Energy Adv., 2024,3, 2597-2603
https://doi.org/10.1039/D4YA00360H
Electrochemical and spectroscopic characterisation of organic molecules with high positive redox potentials for energy storage in aqueous flow cells
We show that a number of ubiquitous organic molecules used as redox mediators and chemically sensing species can be used as positive couples in electrochemical energy storage.
Energy Adv., 2024,3, 2587-2596
https://doi.org/10.1039/D4YA00366G
Quantitative local state of charge mapping by operando electrochemical fluorescence microscopy in porous electrodes
Operando confocal microscopy coupled with electrochemistry yields spatially and temporally resolved state of charge maps within porous electrodes.
Energy Adv., 2024,3, 2468-2478
https://doi.org/10.1039/D4YA00362D
Analysis of the impact of remote oxygen plasma treatment on the surface chemistry and electrochemical properties of graphite felt electrodes for redox flow batteries
Remote oxygen plasma is compared to conventional thermal activation of electrodes for flow batteries and their impact on the mass transport and charge transfer properties of the resulting carbons.
Energy Adv., 2024,3, 2503-2511
https://doi.org/10.1039/D4YA00383G
Optimization framework for redox flow battery electrodes with improved microstructural characteristics
This research aims to advance the field of vanadium redox flow batteries (VRFBs) by introducing a pioneering approach to optimize the microstructural characteristics of carbon cloth electrodes.
Energy Adv., 2024,3, 2220-2237
https://doi.org/10.1039/D4YA00248B
Single-membrane pH-decoupling aqueous batteries using proton-coupled electrochemistry for pH recovery
Proton-coupled electrochemical reactions as proton pumps can facilitate in situ or ex situ pH recovery and capacity rebalancing within single-membrane pH-decoupling batteries.
Energy Adv., 2024,3, 1911-1918
https://doi.org/10.1039/D4YA00279B
Organized macro-scale membrane size reduction in vanadium redox flow batteries: part 2. Flow-field-informed membrane coverage distribution
Membranes are a critical component contributing to cost in flowing-electrolyte electrochemical systems. Flow-field-informed membrane reduction can be adopted to reduce performance compromise.
Energy Adv., 2024,3, 1307-1313
https://doi.org/10.1039/D4YA00118D
Bamboo charcoal as electrode material for vanadium redox flow batteries
We investigated bamboo electrodes for use in vanadium redox flow batteries. The electrodes showed promising electrochemical performance, wettability, and a channel structure suitable for vanadium electrolyte flow.
Energy Adv., 2024,3, 997-1008
https://doi.org/10.1039/D4YA00166D
An aqueous polysulfide redox flow battery with a semi-fluorinated cation exchange membrane
An economically viable thermally annealed cation exchange membrane for polysulfide-based redox flow batteries.
Energy Adv., 2024,3, 203-214
https://doi.org/10.1039/D3YA00509G
In-plane gradient design of flow fields enables enhanced convections for redox flow batteries
This work proposes an in-plane gradient flow field design which enhances the under-rib convections for redox flow batteries. Furthermore, generalized structured approaches have been proffered for future scientific research.
Energy Adv., 2023,2, 2006-2017
https://doi.org/10.1039/D3YA00365E
Beyond energy density: flow battery design driven by safety and location
Using satellite imagery we show that the installation footprint of grid-scale lithium-ion batteries is often comparable to much less energy-dense technologies such as aqueous battery systems.
Energy Adv., 2023,2, 1357-1365
https://doi.org/10.1039/D3YA00208J
About this collection
Flowable energy storage is a technology capable of addressing critical challenges in the energy landscape by offering scalable, durable and sustainable solutions.
This themed collection includes papers covering redox flow batteries (including lithium-sulfur, vanadium and aqueous organic systems), electrochemical flow capacitors, and component design for these systems.