Issue 14, 2019

Strongly luminescent 5d/4f heterometal–organic macrocycles with open metal sites: post-assembly modification and sensing

Abstract

A series of strongly luminescent 5d/4f heterometal–organic macrocycles formulated as Ln2(Pt–L)2 have been constructed from a preformed cis-blocked alkynylplatinum metalloligand (Pt–L) and lanthanide (Ln = LaIII, EuIII, LuIII) ions. Open metal sites on the lanthanide centres of the heterometal–organic macrocycles facilitate not only the post-assembly modification leading to great enhancement of the luminescence, but also the displacement sensing toward toxic thiophosphonates.

Graphical abstract: Strongly luminescent 5d/4f heterometal–organic macrocycles with open metal sites: post-assembly modification and sensing

Supplementary files

Article information

Article type
Communication
Submitted
16 feb 2019
Accepted
04 mrt 2019
First published
04 mrt 2019

Dalton Trans., 2019,48, 4479-4483

Strongly luminescent 5d/4f heterometal–organic macrocycles with open metal sites: post-assembly modification and sensing

Q. Zhu, L. Zhou and Q. Sun, Dalton Trans., 2019, 48, 4479 DOI: 10.1039/C9DT00710E

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