Cucurbitimines – imine cages with concave walls

Christine Bourguignon; Dorothee Schindler; Gangxiang Zhou; Frank Rominger; Michael Mastalerz

doi:10.1039/D1QO00478F

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Cucurbitimines – imine cages with concave walls†

Christine Bourguignon,

^a Dorothee Schindler,‡^a Gangxiang Zhou,^a Frank Rominger^a and Michael Mastalerz

*^a

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* Corresponding authors

^a Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
E-mail: michael.mastalerz@oci.uni-heidelberg.de

Abstract

The variety of shape-persistent organic cages by imine bond formation has tremendously enlarged in recent years by using different building blocks (aldehydes and amines) in the condensation reactions. Here, we describe the use of a kinked tetraldehyde to generate pumpkin-shaped cages with concave walls, similar to cucurbiturils.

This article is part of the themed collections: Recent Open Access Articles in Frontiers Journals and Macrocycle-based Supramolecular Elements

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DOI: https://doi.org/10.1039/D1QO00478F
Article type: Research Article
Submitted: 30 mrt 2021
Accepted: 29 apr 2021
First published: 17 mei 2021
This article is Open Access

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Org. Chem. Front., 2021,8, 3668-3674

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Cucurbitimines – imine cages with concave walls

C. Bourguignon, D. Schindler, G. Zhou, F. Rominger and M. Mastalerz, Org. Chem. Front., 2021, 8, 3668 DOI: 10.1039/D1QO00478F

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Organic Chemistry Frontiers

Cucurbitimines – imine cages with concave walls†

Abstract

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Cucurbitimines – imine cages with concave walls

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