Issue 18, 2012

Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

Abstract

Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.

Graphical abstract: Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

Supplementary files

Article information

Article type
Communication
Submitted
24 Jan 2012
Accepted
28 Feb 2012
First published
12 Mac 2012

Dalton Trans., 2012,41, 5458-5460

Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

A. F. Gross, E. Sherman and J. J. Vajo, Dalton Trans., 2012, 41, 5458 DOI: 10.1039/C2DT30174A

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