Ethene hydroformylation with CO/H2O: nucleophilic attack by water on to a terminal CO of a Ru(II) acylcarbonyl complex

Giuseppe Fachinetti; Tiziana Funaioli; Fabio Marchetti

doi:10.1039/B502998H

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Ethene hydroformylation with CO/H₂O: nucleophilic attack by water on to a terminal CO of a Ru(ii) acylcarbonyl complex†

Giuseppe Fachinetti,*^a Tiziana Funaioli*^a and Fabio Marchetti^a

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* Corresponding authors

^a Dipartimento di Chimica e Chimica Industriale dell'Università di Pisa, Via Risorgimento, 35, Pisa, Italy
E-mail: tiziana@dcci.unipi.it
Fax: +39 0502219223
Tel: +39 0502219260

Abstract

The reaction with water of acyldicarbonyl–Ru(II) complexes relevant to ruthenium catalysed ethene hydrocarbonylation with CO/H₂O is shown to consist of a nucleophilic attack and to proceed via coordination of propionate and CO to the Ru(II) species.

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Article information

DOI: https://doi.org/10.1039/B502998H
Article type: Communication
Submitted: 03 Mar 2005
Accepted: 18 Apr 2005
First published: 06 May 2005

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Chem. Commun., 2005, 2912-2914

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Ethene hydroformylation with CO/H₂O: nucleophilic attack by water on to a terminal CO of a Ru(II) acylcarbonyl complex

G. Fachinetti, T. Funaioli and F. Marchetti, Chem. Commun., 2005, 2912 DOI: 10.1039/B502998H

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