Issue 26, 2010
From the journal:

Chemical Communications

Heterometallic cobalt(ii)–titanium(iv) oxo cages; key building blocks for hybrid materials†

Salvador Eslava,*a   Frank Hengesbach,a   Mary McPartlina  and  Dominic S. Wrighta  

* Corresponding authors

a Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: se296@cam.ac.uk

Abstract

The two new heterometallic cobalt(II)/titanium oxo cages octanuclear [Ti7O5(OEt)19(CoCl)] (1) and pentanuclear [Ti4O(OEt)15(CoCl)] (2) have been obtained via condensation reactions of Ti(OEt)4 in the presence of CoCl2. This simple methodology gives access to key well-defined molecular building blocks for Co-doped hybrid materials.

Graphical abstract: Heterometallic cobalt(ii)–titanium(iv) oxo cages; key building blocks for hybrid materials

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Article information

DOI
https://doi.org/10.1039/C0CC00016G
Article type
Communication
Submitted
18 Feb 2010
Accepted
16 Apr 2010
First published
12 May 2010

Chem. Commun., 2010,46, 4701-4703

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Heterometallic cobalt(II)–titanium(IV) oxo cages; key building blocks for hybrid materials

S. Eslava, F. Hengesbach, M. McPartlin and D. S. Wright, Chem. Commun., 2010, 46, 4701 DOI: 10.1039/C0CC00016G

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