Issue 51, 2012
From the journal:

Chemical Communications

Rhodium-catalysed linear-selective alkyne hydroacylation†

Sarah-Jane Poingdestre,a   Jonathan D. Goodacre,b   Andrew S. Wellera  and  Michael C. Willis*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK
E-mail: michael.willis@chem.ox.ac.uk
Fax: 44 1865 285002
Tel: 44 1865 285126

b EpiNova DPU, Immuno-Inflammation TAU, GlaxoSmithKline, Medicines Research Centre, Gunnels Wood Road, Stevenage, UK

Abstract

The use of the electron-rich diphosphine ligand, dcpe, allows the efficient and highly linear selective hydroacylative coupling of aldehydes, including aryl examples, with a range of alkynes.

Graphical abstract: Rhodium-catalysed linear-selective alkyne hydroacylation

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Article information

DOI
https://doi.org/10.1039/C2CC32713A
Article type
Communication
Submitted
17 Apr 2012
Accepted
03 May 2012
First published
04 May 2012

Chem. Commun., 2012,48, 6354-6356

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Rhodium-catalysed linear-selective alkyne hydroacylation

S. Poingdestre, J. D. Goodacre, A. S. Weller and M. C. Willis, Chem. Commun., 2012, 48, 6354 DOI: 10.1039/C2CC32713A

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