Encapsulation of discrete (H2O)12 clusters in a 3D three-fold interpenetrating metal–organic framework host with (3,4)-connected topology

Xiuli Wang; Hongyan Lin; Bao Mu; Aixiang Tian; Guocheng Liu

doi:10.1039/C0DT00302F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Encapsulation of discrete (H₂O)₁₂clusters in a 3D three-fold interpenetrating metal–organic framework host with (3,4)-connected topology†

Xiuli Wang,*^a Hongyan Lin,^a Bao Mu,^a Aixiang Tian^a and Guocheng Liu^a

Author affiliations

* Corresponding authors

^a Faculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou, P. R. China
E-mail: wangxiuli@bhu.edu.cn
Fax: +86-416-3400158
Tel: +86-416-3400158

Abstract

A unique discrete cage-like (H₂O)₁₂ cluster guest containing six fused five-membered rings has been observed in a novel metal–organic framework host [Cu₃(L)₃(BTC)₂]_3n [L = N,N′-bis(4-pyridinecarboxamide)-1,4-benzene, BTC = 1,3,5-benzenetricarboxylate anion], which represents a (3,4)-connected topology with the new type of (6³)(6⁴·10²) presently known for three-fold interpenetrating systems.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C0DT00302F
Article type: Communication
Submitted: 13 Apr 2010
Accepted: 01 Jun 2010
First published: 14 Jun 2010

Download Citation

Dalton Trans., 2010,39, 6187-6189

Permissions

Request permissions

Encapsulation of discrete (H₂O)₁₂ clusters in a 3D three-fold interpenetrating metal–organic framework host with (3,4)-connected topology

X. Wang, H. Lin, B. Mu, A. Tian and G. Liu, Dalton Trans., 2010, 39, 6187 DOI: 10.1039/C0DT00302F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions