Issue 4, 2012
From the journal:

Chemical Communications

Probing double layer structures of Au (111)–BMIPF6ionic liquid interfaces from potential-dependent AFM force curves†

Xiao Zhang,a   Yun-Xin Zhong,a   Jia-Wei Yan,*a   Yu-Zhuan Su,a   Meng Zhanga  and  Bing-Wei Mao*a  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
E-mail: bwmao@xmu.edu.cn, jwyan@xmu.edu.cn

Abstract

High quality AFM force curves are presented with detailed potential dependent layering behaviors of the ionic liquid molecules, from which charged interior and neutral exterior layers are distinguished. The electric double layer is confined within the interior layers of one to two molecular size within the potential range of up to 1 V negative of the PZC.

Graphical abstract: Probing double layer structures of Au (111)–BMIPF6 ionic liquid interfaces from potential-dependent AFM force curves

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Article information

DOI
https://doi.org/10.1039/C1CC15463J
Article type
Communication
Submitted
02 Sep 2011
Accepted
11 Nov 2011
First published
22 Nov 2011

Chem. Commun., 2012,48, 582-584

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Probing double layer structures of Au (111)–BMIPF6 ionic liquid interfaces from potential-dependent AFM force curves

X. Zhang, Y. Zhong, J. Yan, Y. Su, M. Zhang and B. Mao, Chem. Commun., 2012, 48, 582 DOI: 10.1039/C1CC15463J

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