B(C6F5)3-catalyzed methylation of amines using CO2 as a C1 building block

Zhenzhen Yang; Bo Yu; Hongye Zhang; Yanfei Zhao; Guipeng Ji; Zhishuang Ma; Xiang Gao; Zhimin Liu

doi:10.1039/C5GC01386K

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B(C₆F₅)₃-catalyzed methylation of amines using CO₂ as a C1 building block†

Zhenzhen Yang,^a Bo Yu,^a Hongye Zhang,^a Yanfei Zhao,^a Guipeng Ji,^a Zhishuang Ma,^a Xiang Gao^a and Zhimin Liu*^a

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: liuzm@iccas.ac.cn

Abstract

B(C₆F₅)₃ was proven to be an efficient metal-free catalyst for the methylation of amines using CO₂ as a C1 building block in the presence of hydrosilanes under easy-handling conditions. A broad range of N-alkylanilines, dialkylamines and primary anilines all proceeded well under the catalytic conditions.

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Article information

DOI: https://doi.org/10.1039/C5GC01386K
Article type: Communication
Submitted: 21 Jun 2015
Accepted: 14 Jul 2015
First published: 14 Jul 2015

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Green Chem., 2015,17, 4189-4193

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B(C₆F₅)₃-catalyzed methylation of amines using CO₂ as a C1 building block

Z. Yang, B. Yu, H. Zhang, Y. Zhao, G. Ji, Z. Ma, X. Gao and Z. Liu, Green Chem., 2015, 17, 4189 DOI: 10.1039/C5GC01386K

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