Issue 6, 2015
From the journal:

Organic Chemistry Frontiers

A concise formal synthesis of platencin†

Jie Wang,a   Wang-Bin Sun,ab   Ying-Zi Li,a   Xuan Wang,a   Bing-Feng Sun,*a   Guo-Qiang Lina  and  Jian-Ping Zoub  

* Corresponding authors

a CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032, China
E-mail: bfsun@sioc.ac.cn

b Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, Suzhou, Jiangsu 215123, China

Abstract

A concise formal synthesis of platencin has been realized, featuring an organocatalytic approach to the [2.2.2] bicyclic core, a radical reductive elimination, a Au-catalyzed Meyer–Schuster rearrangement and a Rh-catalyzed chemo- and diastereoselective hydrosilylation.

Graphical abstract: A concise formal synthesis of platencin

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Article information

DOI
https://doi.org/10.1039/C5QO00065C
Article type
Research Article
Submitted
27 Feb 2015
Accepted
09 Apr 2015
First published
13 Apr 2015

Org. Chem. Front., 2015,2, 674-676

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A concise formal synthesis of platencin

J. Wang, W. Sun, Y. Li, X. Wang, B. Sun, G. Lin and J. Zou, Org. Chem. Front., 2015, 2, 674 DOI: 10.1039/C5QO00065C

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