Issue 19, 2017
From the journal:

Chemical Communications

Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups†

Bing-Hua Lei,ab   Zhihua Yang ORCID logo *a  and  Shilie Pan ORCID logo *a  

* Corresponding authors

a Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: zhyang@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn
Fax: +86-991-3838957
Tel: +86-991-3810816

b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The response electron distribution anisotropy (REDA) approximation was proposed to analyze the relationship between optical anisotropy and distribution of bonding electrons in compounds. Further, the optical anisotropy of tetrahedral chromophore compounds with common small birefringence can be enhanced and excellent nonlinear optical properties can be obtained by optimizing the distribution.

Graphical abstract: Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups

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Article information

DOI
https://doi.org/10.1039/C6CC09986F
Article type
Communication
Submitted
15 Dec 2016
Accepted
17 Jan 2017
First published
19 Jan 2017

Chem. Commun., 2017,53, 2818-2821

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Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups

B. Lei, Z. Yang and S. Pan, Chem. Commun., 2017, 53, 2818 DOI: 10.1039/C6CC09986F

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