Issue 41, 2021

Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

Abstract

Pd/Ni → Ge–F interactions supported by phosphine-chelation were found to trigger dual activation of Ge–F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge–C cross-coupling and enables Germa-Suzuki reactions to be achieved for the first time.

Graphical abstract: Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

Supplementary files

Article information

Article type
Communication
Submitted
15 Mar 2021
Accepted
20 Apr 2021
First published
20 Apr 2021

Chem. Commun., 2021,57, 5004-5007

Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

H. Kameo, A. Mushiake, T. Isasa, H. Matsuzaka and D. Bourissou, Chem. Commun., 2021, 57, 5004 DOI: 10.1039/D1CC01392K

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