A weak acyl chelation-assisted distal C4–H allylation of indoles has been accomplished using vinylcyclopropanes as an allylating agent under redox-neutral ruthenium(II) catalysis. The regioselectivity, removable directing group, substrate scope and diastereoselectivity are the important practical features.
S. Basak, T. Paul and T. Punniyamurthy, Chem. Commun., 2023, 59, 11568 DOI: 10.1039/D3CC03614F
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