Ultrasensitive sensing performances of amphiphilic block copolymer induced gyrus-like In2O3 thick films to low-concentration acetone

Abstract

In the present work, an inducible assembly of di-block polymer compounds approach was employed for the synthesis of mesoscopic gyrus-like In₂O₃ by using lab-made high-molecular-weight amphiphilic di-block copolymer poly(ethylene oxide)-b-polystyrene (PEO-b-PS) as a revulsive, with indium chloride as an indium source and THF/ethanol as the solvent. The obtained mesoscopic gyrus-like In₂O₃ indium oxide materials exhibit a large surface area and a highly crystalline In₂O₃ nanostructure framework, and the gyrus distance is about 40 nm, which can facilitate the diffusion and transport of acetone vapor molecules. By using this material as a chemoresistance sensor, the obtained gyrus-like indium oxides were used as sensing materials, showing an excellent performance to acetone at a low operating temperature (150 °C) due to their high porosity and unique crystalline framework. The limit of detection of the thick-film sensor based on indium oxides is appropriate for diabetes exhaled breath acetone concentration detection. Moreover, the thick-film sensor shows a very fast response–recovery dynamics upon contacting acetone vapor due to its abundant open folds mesoscopic structure, and also to the large surface area of the nanocrystalline gyrus-like In₂O₃.