Assembly of a unique octa-nuclear copper cluster-based metal–organic framework with highly selective CO2 adsorption over N2 and CH4

Jiahuan Luo; Jing Wang; Guanghua Li; Qisheng Huo; Yunling Liu

doi:10.1039/C3CC47462C

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Assembly of a unique octa-nuclear copper cluster-based metal–organic framework with highly selective CO₂ adsorption over N₂ and CH₄†

Jiahuan Luo,^a Jing Wang,^a Guanghua Li,^a Qisheng Huo^a and Yunling Liu*^a

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* Corresponding authors

^a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: yunling@jlu.edu.cn
Fax: +86-431-85168624
Tel: +86-431-85168614

Abstract

By using 4-(pyrimidin-5-yl) benzoic acid (4-PmBC) as a ligand, a porous metal–organic framework based on unique octa-nuclear copper clusters was constructed, which exhibited highly selective CO₂ uptake over N₂ and CH₄.

This article is part of the themed collection: CO2 Separation, Capture and Reuse

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Article information

DOI: https://doi.org/10.1039/C3CC47462C
Article type: Communication
Submitted: 30 Sep 2013
Accepted: 14 Oct 2013
First published: 15 Oct 2013

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Chem. Commun., 2013,49, 11433-11435

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Assembly of a unique octa-nuclear copper cluster-based metal–organic framework with highly selective CO₂ adsorption over N₂ and CH₄

J. Luo, J. Wang, G. Li, Q. Huo and Y. Liu, Chem. Commun., 2013, 49, 11433 DOI: 10.1039/C3CC47462C

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