Themed collection In celebration of the Lunar New Year, 2025
Advancements and prospects of perovskite-based fuel electrodes in solid oxide cells for CO2 electrolysis to CO
Developments and prospects for solid oxide cells using a perovskite-based fuel electrode for CO2 electrolysis to CO.
Chem. Sci., 2024,15, 11166-11187
https://doi.org/10.1039/D4SC03306J
Flexible hydrogen-bonded organic frameworks (HOFs): opportunities and challenges
In this perspective, we have discussed the recent progress of flexible HOFs, with particular focus on various dynamic behaviors and their applications in different fields. Finally, the current challenges and opportunities in this field are discussed.
Chem. Sci., 2024,15, 9874-9892
https://doi.org/10.1039/D4SC02628D
Recent progress in ion-regulated organic room-temperature phosphorescence
In this perspective, the progress in ion-regulated organic RTP materials and described the roles of ions, including ion–π interactions, electrostatic interactions, and coordinate interactions, have been summarized.
Chem. Sci., 2024,15, 4222-4237
https://doi.org/10.1039/D3SC06931A
Hybrid and composite materials of organic crystals
Combining organic crystals and polymers results in a new class of all-organic, lightweight, flexible materials with unprecedented mechanical robustness, resilience, and diversity in combination with other functional materials.
Chem. Sci., 2024,15, 2684-2696
https://doi.org/10.1039/D3SC06469G
Time-resolved single-cell transcriptomic sequencing
Single-cell dynamics study enables to reveal cell heterogeneity in fundamental mechanisms governing cell behavior. This review provides an overview of the time-resolved single-cell transcriptomic sequencing methodologies and applications.
Chem. Sci., 2024,15, 19225-19246
https://doi.org/10.1039/D4SC05700G
When microplastics/plastics meet metal–organic frameworks: turning threats into opportunities
The study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.
Chem. Sci., 2024,15, 17781-17798
https://doi.org/10.1039/D4SC05205F
Flexible piezoelectric materials and strain sensors for wearable electronics and artificial intelligence applications
This review covers the recent advances in flexible piezoelectric materials, which show great potential for strain sensors in wearable electronics and artificial intelligence, focusing on microstructure engineering and fabrication techniques.
Chem. Sci., 2024,15, 16436-16466
https://doi.org/10.1039/D4SC05166A
Recent advances for enhanced photodynamic therapy: from new mechanisms to innovative strategies
Photodynamic therapy (PDT) has been developed as a potential cancer treatment approach owing to its non-invasiveness, spatiotemporal control and limited side effects.
Chem. Sci., 2024,15, 12234-12257
https://doi.org/10.1039/D3SC07006A
Insights into the cycling stability of manganese-based zinc-ion batteries: from energy storage mechanisms to capacity fluctuation and optimization strategies
This review summarizes the progress on the cycling stability of manganese-based zinc-ion batteries.
Chem. Sci., 2024,15, 7441-7473
https://doi.org/10.1039/D4SC00510D
Hard carbon for sodium-ion batteries: progress, strategies and future perspective
Recent progress of preparation approaches for HCs is systematically overviewed, with a special focus on the comparison between traditional fabrication methods and advanced strategies regarding their influence on performance.
Chem. Sci., 2024,15, 6244-6268
https://doi.org/10.1039/D4SC00734D
Structural engineering of atomic catalysts for electrocatalysis
This review systematically introduces how to regulate the electronic structure and geometric configuration of atomic catalysts to achieve high-efficiency electrocatalysis performances by analyzing detailed electrocatalytic applications and mechanisms.
Chem. Sci., 2024,15, 5082-5112
https://doi.org/10.1039/D4SC00569D
Molecular modulation strategies for two-dimensional transition metal dichalcogenide-based high-performance electrodes for metal-ion batteries
Through the purposeful modulation of specific parts or regions of TMD molecules, molecular modulation strategies aim to realize the effective modulation of TMDs' properties from an ‘internal’ perspective.
Chem. Sci., 2024,15, 2323-2350
https://doi.org/10.1039/D3SC05768B
Water-stable metal–organic frameworks (MOFs): rational construction and carbon dioxide capture
This review highlights the design and synthesis of water-stable MOFs, as well as their applications in carbon capture.
Chem. Sci., 2024,15, 1570-1610
https://doi.org/10.1039/D3SC06076D
Molecular cylinders with donor–acceptor structure and swinging motion
Two nanometer-sized, nitrogen-containing molecular cylinders were synthesized by connecting the cycloparaphenylene and fused aromatic moieties using cyclocondensation reaction.
Chem. Sci., 2024,15, 18832-18839
https://doi.org/10.1039/D4SC05849F
Amplification-free miRNA detection with CRISPR/Cas12a system based on fragment complementary activation strategy
We proposed the ‘Fragment Complementary Activation Strategy’ (FCAS) based on the CRISPR/Cas12a system and designed fragment activators consisting of ssDNA and miRNA targets, enabling the direct detection of miRNAs.
Chem. Sci., 2024,15, 18347-18354
https://doi.org/10.1039/D4SC05647G
Cobalt-catalyzed conformationally restricted alkylarylation enables divergent access to Csp3-rich N-heterocycles
Modular cobalt-catalyzed conformationally restricted alkylarylation enables the divergent synthesis of Csp3-rich N-hetero(spiro)cycles (>70 examples, >20 : 1 dr).
Chem. Sci., 2024,15, 16250-16258
https://doi.org/10.1039/D4SC04056B
Slightly Li-enriched chemistry enabling super stable LiNi0.5Mn0.5O2 cathodes under extreme conditions
Hetero-epitaxially grown Li2WO4 surface induced slightly Li-enriched chemistry was adopted to boost the stability of LiNi0.5Mn0.5O2 under extreme conditions.
Chem. Sci., 2024,15, 14415-14424
https://doi.org/10.1039/D4SC03805C
Palladium-catalyzed decarboxylative (4 + 3) cycloadditions of bicyclobutanes with 2-alkylidenetrimethylene carbonates for the synthesis of 2-oxabicyclo[4.1.1]octanes
A novel palladium-catalyzed strategy was employed to achieve higher-order (4 + 3) cycloadditions of bicyclobutanes with various 2-alkylidenetrimethylene carbonates to synthesize 2-oxabicyclo[4.1.1]octanes.
Chem. Sci., 2024,15, 13942-13948
https://doi.org/10.1039/D4SC02998D
Data-driven discovery of active phosphine ligand space for cross-coupling reactions
An active ligand space catalyst screening strategy based on a metal–phosphine ligand catalyst database (MPCD) helps to discover the cost-effective P-ligand for C–C cross-coupling reactions with inert aryl chloride.
Chem. Sci., 2024,15, 13359-13368
https://doi.org/10.1039/D4SC02327G
In situ polymerization of 1,3-dioxolane and formation of fluorine/boron-rich interfaces enabled by film-forming additives for long-life lithium metal batteries
This work proposes a film-forming Lewis acid additive to promote the in situ polymerization of 1,3-dioxane and the formation of a fluorine/boron rich interface, which enhance the cycling stability of lithium metal batteries.
Chem. Sci., 2024,15, 12108-12117
https://doi.org/10.1039/D4SC02010C
Nanoarchitectonics of ultrafine molybdenum carbide nanocrystals into three-dimensional nitrogen-doped carbon framework for capacitive deionization
Ultrafine MoC nanocrystals are confined within the MOF-derived NC matrix to generating NC/MoC. The NC/MoC based electrode achieves high CDI performance.
Chem. Sci., 2024,15, 11540-11549
https://doi.org/10.1039/D4SC00971A
An imidazole-based covalent-organic framework enabling a super-efficiency in sunlight-driven uranium extraction from seawater
The natural sunlight is for the first time used to acquire the key of nuclear energy, uranium, from natural seawater with an ultrahigh extraction efficiency of 6.9 mg g−1 day−1 upon a novel COF photocatalyst with ultralow exciton binding energy.
Chem. Sci., 2024,15, 10882-10891
https://doi.org/10.1039/D4SC02554G
How does ferrocene correlate with ferroptosis? Multiple approaches to explore ferrocene-appended GPX4 inhibitors as anticancer agents
Ferrocene correlates with ferroptosis: multiple approaches to explore ferrocene-appended GPX4 inhibitors as dual-function ferroptosis inducers, which consummate the potential of ferrocene in ferroptosis-targeted drug development.
Chem. Sci., 2024,15, 10477-10490
https://doi.org/10.1039/D4SC02002B
Tuning hydrogen bond network connectivity in the electric double layer with cations
Cations at interfaces can tune the structure and the connectivity of hydrogen bond networks in electric double layers.
Chem. Sci., 2024,15, 7111-7120
https://doi.org/10.1039/D3SC06904D
Pb2(SeO3)(SiF6): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification
The first selenite fluorosilicate, Pb2(SeO3)(SiF6), modified with perfluorinated groups, features a broad transparency range, large birefringence, high LIDT, and excellent environmental stability, marking it a potential birefringent material.
Chem. Sci., 2024,15, 7104-7110
https://doi.org/10.1039/D4SC01376J
In situ Nafion-nanofilm oriented (002) Zn electrodeposition for long-term zinc-ion batteries
Nafion introduced into an aqueous electrolyte activates a thermodynamically ultrastable Zn/electrolyte interface, which guides the directional Zn2+ electrodeposition along the (002) crystal surface for a dendrite-free Zn metal anode.
Chem. Sci., 2024,15, 4322-4330
https://doi.org/10.1039/D3SC06935D
Mesoporous Mo-doped PtBi intermetallic metallene superstructures to enable the complete electrooxidation of ethylene glycol
Novel freestanding M-PtBiMo IMSs were achieved via a simple and effective one-step wet chemical method. The M-PtBiMo IMSs as highly efficient anode electrocatalysts boosted the activity and stability toward the EGOR and actual DEGFCs.
Chem. Sci., 2024,15, 4349-4357
https://doi.org/10.1039/D4SC00323C
A covalent organic framework as a dual-active-center cathode for a high-performance aqueous zinc-ion battery
We designed a covalent organic framework (TA-PTO-COF) as a dual-active-center cathode. This work presents a promising organic cathode material for a high-performance aqueous zinc-ion battery.
Chem. Sci., 2024,15, 4341-4348
https://doi.org/10.1039/D3SC07013A
Multi-site isomerization of synergistically regulated stimuli-responsive AIE materials toward multi-level decryption
The utilization of multi-site modifications brings about the manipulation of excited-state processes and multi-stimuli responses of salicylaldehyde Schiff base isomers, which can be successfully applied in multi-level decryption.
Chem. Sci., 2024,15, 3920-3927
https://doi.org/10.1039/D3SC06191D
Molecular engineering of AIE-active boron clustoluminogens for enhanced boron neutron capture therapy
This study presents a new type of boron carrier for boron neutron capture therapy that integrates imaging, a lung cancer targeting drug and carborane, and showcases an impressive therapeutic efficacy against lung tumors both in vitro and in vivo.
Chem. Sci., 2024,15, 4019-4030
https://doi.org/10.1039/D3SC06222H
A flexible ligand and halogen engineering enable one phosphor-based full-color persistent luminescence in hybrid perovskitoids
A new series of perovskitoids were fabricated based on halogen engineering and a rigid and flexible ligand, and exhibit a multi-color afterglow covering nearly the whole visible region from cyan to red.
Chem. Sci., 2024,15, 3625-3632
https://doi.org/10.1039/D3SC06845E
De novo synthesis of inherently chiral heteracalix[4]aromatics from enantioselective macrocyclization enabled by chiral phosphoric acid-catalyzed intramolecular SNAr reaction
N3,O-calix[2]arene[2]triazines, whose inherent chirality arises from one different heteroatom linkage, were synthesized enantioselectively in ee up to 95% from macrocyclization via chiral monophosphoric acid-catalyzed intramolecular SNAr reaction.
Chem. Sci., 2024,15, 3610-3615
https://doi.org/10.1039/D3SC06436K
Dual role of nitroarenes as electrophiles and arylamine surrogates in Buchwald–Hartwig-type coupling for C–N bond construction
A reductive and denitrative amination of nitroarenes has been developed, allowing the highly selective synthesis of various di- and triarylamines. The protocol employed synthetically upstream nitroarenes as both the electrophiles and amine sources.
Chem. Sci., 2024,15, 3552-3561
https://doi.org/10.1039/D3SC06618E
Stereo effects for efficient synthesis of orange-red multiple resonance emitters centered on a pyridine ring
Despite theoretical difficulties, we herein for the first time demonstrate an effective concept for the synthesis of an orange-red multiple resonance (MR) emitter centered on a pyridine ring via stereo effects.
Chem. Sci., 2024,15, 3148-3154
https://doi.org/10.1039/D3SC06470K
Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis-[Zr6F34]10− clusters
The new zirconium fluoride, K3Ba2Zr6F31, is reported, featuring unprecedented acentric cis-[Zr6F34]10− clusters composed of ZrF8 units, which display a moderate second-harmonic generation response (0.5 × KH2PO4) and short UV cutoff edge (below 200 nm).
Chem. Sci., 2024,15, 2883-2888
https://doi.org/10.1039/D3SC06683E
Switchover from singlet oxygen to superoxide radical through a photoinduced two-step sequential energy transfer process
We present an efficient method for the transformation of type II photosensitizers (1O2) into type I photosensitizers (O2˙−) through the implementation of an artificial light-harvesting system involving a two-step sequential energy transfer process.
Chem. Sci., 2024,15, 1870-1878
https://doi.org/10.1039/D3SC05820D
About this collection
In celebration of Chinese New Year, we are delighted to present a special collection of recent articles by authors in China. This collection of popular articles highlights contributions from China from the last year in a range of fields including organic chemistry, energy conversion and storage, catalysis, chemical biology, physical chemistry, materials science, analytical science, and machine learning.
We would like to wish everyone a Happy Year of the Snake!