Themed collection Green and Sustainable Batteries

Unlocking recent progress in niobium and vanadium carbide-based MXenes for sodium-ion batteries
This review examines the potential capability of Nb–C and VC MXenes as advanced anode materials for enhancing the performance of Na-ion batteries (SIBs). The crucial challenges and future prospects of these SIB electrodes have elaborated in detail.
J. Mater. Chem. A, 2025,13, 1590-1611
https://doi.org/10.1039/D4TA05669H
A holistic review on the direct recycling of lithium-ion batteries from electrolytes to electrodes
First critical review paper on LIBs direct recycling strategies, covering a broader scope with the positive electrode, negative electrode, and electrolyte, while discussing the substantial challenges to their effective implementation.
J. Mater. Chem. A, 2024,12, 31685-31716
https://doi.org/10.1039/D4TA04976D
Recent advances in bifunctional carbon-based single-atom electrocatalysts for rechargeable zinc–air batteries
The review delves into six modulation strategies of carbon-based single-atom catalysts, emphasizing the relationship between electronic structure and performance to aid in the development of bifunctional electrocatalysts for zinc–air batteries.
Green Chem., 2025,27, 293-324
https://doi.org/10.1039/D4GC04687K

Solving ZIB Challenges: The Dynamic Role of Water in Deep Eutectic Solvents electrolyte
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA00395D

Rational design for enhanced mechanical and kinetic properties of SnSb-based yolk–shell heterostructure as long cycle-life, high-rate Na-ion battery anode
A long cycle-life, high-rate SnSb@C-SiOC nanohybrid anode for SIBs is designed. The multi-functional shell boosts electrochemical kinetics, and the heterostructure effectively suppresses huge volume change and structural degradation of SnSb.
J. Mater. Chem. A, 2025,13, 5777-5788
https://doi.org/10.1039/D4TA08119F

Environmentally friendly regeneration of graphite from spent lithium-ion batteries for sustainable anode material reuse
Sustainable regeneration of graphite anodes through novel treatments boosts performance and supports circular economy in batteries.
J. Mater. Chem. A, 2025,13, 4984-4993
https://doi.org/10.1039/D4TA07618D

Rapid gram-scale microwave-assisted synthesis of organic anodes for sodium-ion batteries with environmental impact assessment
Gram-scale microwave synthesis and environmental impact assessment of sodium carboxylates for use as organic electrode materials in sodium-ion batteries.
Green Chem., 2025,27, 2035-2045
https://doi.org/10.1039/D4GC05530F

Exploring separation techniques for the direct recycling of high voltage spinel LNMO scrap electrodes
Workflow of the direct recycling of various LNMO electrode scraps through three distinct separation routes, with the resulting materials used directly for the preparation of new electrodes with no need for re-synthesis of the active material.
J. Mater. Chem. A, 2025,13, 2690-2706
https://doi.org/10.1039/D4TA07642G
Wet-spun Ni, N-codoped macroporous carbon fibers for efficient CO2 electroreduction and Zn–CO2 batteries
Ni, N-codoped macroporous carbon fibers have been developed as efficient electrocatalysts for CO2 reduction and Zn–CO2 batteries.
J. Mater. Chem. A, 2025,13, 2707-2715
https://doi.org/10.1039/D4TA06665K

High performing and sustainable hard carbons for Na-ion batteries through acid-catalysed hydrothermal carbonisation of vine shoots
Acid-assisted hydrothermal carbonisation of vine shoots, followed by annealing, yields tailored hard carbon anodes for Na-ion batteries. Diglyme-based electrolytes improved capacity, efficiency, and stability, showcasing sustainable energy solutions.
J. Mater. Chem. A, 2025,13, 2730-2741
https://doi.org/10.1039/D4TA07393B

A lactic acid dioxolane as a bio-based solvent for lithium-ion batteries: physicochemical and electrochemical investigations of lithium imide-based electrolytes
This work is the first report of a suitable formulation and application in lithium-ion battery full-cells of an electrolyte incorporating the novel bio-based solvent 5-methyl-1,3-dioxolane-4-one (LA-H,H) with imide-based salts.
Green Chem., 2025, Advance Article
https://doi.org/10.1039/D4GC05476H
Macromolecular electrolyte engineering for tuning Zn-ion solvation chemistry and boosting H+ storage toward stable aqueous zinc-organic batteries
We demonstrate a macromolecular electrolyte engineering strategy to break the Zn2+ solvation sheath using a porphyrin-based additive, which can facilitate the formation of the Zn-porphyrin complex and achieve superior electrochemical performance.
Green Chem., 2025,27, 660-669
https://doi.org/10.1039/D4GC05107F

Non-woven pitch-based carbon fiber electrodes for low-cost redox flow battery
The low-cost and sustainable non-woven carbon fibers produced from petroleum pitch using a melt-blowing process are shown to be an ideal alternative to expensive polyacrylonitrile-based carbon felt electrode material for redox flow batteries.
Sustainable Energy Fuels, 2025,9, 198-207
https://doi.org/10.1039/D4SE01124D

Electron transport kinetics for viologen-containing polypeptides with varying side group linker spacing
The role of the linker (the group connecting viologen moieties to peptide-based backbones) in electron transfer was studied. The backbone dictated the mechanism of electron transfer, whereas the linker length altered the rate of electron transfer.
J. Mater. Chem. A, 2024,12, 31871-31882
https://doi.org/10.1039/D4TA06766E
Carbonate deprotonation on an Ni-rich layered cathode: development of a new cis-oligomer as an organic coverage
This work highlights a cis-oligomer as an organic coverage. Results show that the oxygen atom on the NCM811 surface deprotonates the cis-oligomer rather than carbonates. Cis-oligomer adjustes the solvation of the carbonates for controllable CEI formation.
J. Mater. Chem. A, 2024,12, 28899-28910
https://doi.org/10.1039/D4TA05197A
A biphase coupled cathode enables all-organic rocking-chair lithium ion batteries based on crystalline AB-stacked covalent triazine-based frameworks
Crystalline AB-stacked CTFs were synthesized in the AlCl3–NaCl–KCl ternary eutectic salt system, and a CTF-based biphase coupled cathode (BPCC) has been proposed and proved to show significantly enhanced electrochemical performance.
Green Chem., 2024,26, 10593-10603
https://doi.org/10.1039/D4GC03426K

Tetrathiafulvalene-based covalent organic frameworks as high-voltage organic cathodes for lithium batteries
We report a series of 2D tetrathiafulvalene (TTF)-based COFs incorporating different organic linkers between the electroactive moieties that were investigated as p-type organic cathode materials for lithium-organic batteries.
J. Mater. Chem. A, 2024,12, 24156-24164
https://doi.org/10.1039/D4TA04576A
About this collection
This themed collection showcases cutting-edge research, advancements, and remaining challenges in realising the holy grail of batteries: sustainable batteries that balance performance, cost and environmental sustainability. The collection aims to uncover new research opportunities in this field by featuring multidisciplinary research on alternative battery chemistries, sustainable electrolytes, sustainability assessment (including assessing materials criticality and its environmental impact), battery recycling, electrodes manufacturing for improved performance, understanding and preventing degradation and improving life time, design for disassembly and technoeconomic assessment among other topics closely fitting to the sustainable battery topic.
Guest Edited by Magda Titirici (Imperial College London), Rebeca Marcilla (IMDEA Energy Institute), Cristina Pozo-Gonzalo (Institute of Carboquimica ICB-CSIC) and Theresa Schoetz (University of Illinois at Urbana-Champaign).
The journals supporting the collection are Green Chemistry, Journal of Material Chemistry A, Sustainable Energy & Fuels and RSC Sustainability