Themed collection Journal of Materials Chemistry A Recent Review Articles

Topological quantum materials in catalysis
Let's quantum: topological quantum materials offer high electron mobility, stable surface states, and resistance to contamination, making them ideal candidates for next-generation heterogeneous catalysts.
J. Mater. Chem. A, 2025,13, 6325-6341
https://doi.org/10.1039/D4TA08325C
Repurposing PVA-based slime to address electrolyte challenges in portable electrochemical devices
PVA-based slime is an unexplored, cost-effective, and spill-proof alternative to conventional electrolytes. Its inherent ionic conductivity makes it a promising electrolyte for portable electrochemical surface-monitoring probes.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03449C
Ordered energy conversion systems inspired from the biological world
In addressing the urgent challenges facing the energy industry, this perspective emphasizes the importance of offering efficient, clean and low-carbon ordered energy conversion systems by integrating biology and engineering.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03826J
Stabilizing Ultrafine Intermetallics on Carbon Supports: From Structural Design to Catalytic Applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04405G

On the use of bioprecursors for sustainable silicon-based anodes for Li-ion batteries
Plants and protists: promising sources for Si-based Li-ion battery anodes.
J. Mater. Chem. A, 2025,13, 21421-21435
https://doi.org/10.1039/D5TA02555A
How common is it to get an OER overpotential that is <250 mV?
This work raises concerns about the unintentional mistakes made by researchers developing OER electrocatalysts by overlooking the fundamentals.
J. Mater. Chem. A, 2025,13, 21436-21452
https://doi.org/10.1039/D5TA00009B
Unveiling the significance of working electrode substrates in electrocatalytic water splitting for sustainable hydrogen energy production
This perspective highlights how electrode substrate choice critically affects electrocatalyst performance in water splitting, guiding researchers to design better catalysts by leveraging each substrate’s unique properties.
J. Mater. Chem. A, 2025,13, 19252-19281
https://doi.org/10.1039/D5TA02980E
Recent advancements in metal–organic frameworks (MOFs) for flexible supercapacitors aimed at wearable technology
Flexible supercapacitors have made significant progress, as they can be integral to the wearable technology field due to their unique ability to allow seamless movement for the wearer.
J. Mater. Chem. A, 2025,13, 19236-19251
https://doi.org/10.1039/D5TA01159K
Advances and industrialization of LiFePO4 cathodes in electric vehicles: challenges, innovations, and future directions
Evolution, research focus, industrialization and recovery techniques of LiFePO4 cathodes are reviewed, highlighting their critical role in meeting energy demands, especially in EVs.
J. Mater. Chem. A, 2025,13, 17271-17283
https://doi.org/10.1039/D5TA00166H
From lab to market: the future of zinc–air batteries powered by MOF/MXene hybrids
Zinc–air batteries (ZABs) stand at the forefront of energy storage technologies. However, challenges like slow kinetics and low rechargeability persist. MOF–MXene hybrids enhance performance, enabling sustainable ZAB technology.
J. Mater. Chem. A, 2025,13, 12855-12890
https://doi.org/10.1039/D5TA01344E
Sulfur element achieves rapid and stable migration of Li+ in oxide cathode materials
Higher energy density can be obtained by increasing the charging cut-off voltage of Ni-rich materials to meet the range requirements of electric vehicles.
J. Mater. Chem. A, 2025,13, 9039-9048
https://doi.org/10.1039/D4TA09238D

Capacity-weighted figures-of-merit for battery transport metrics
Fast-charging materials are necessary for a battery-centric future. Ionic and electronic transport crucially determine performance where their capacity-weighted figures-of-merit account for performance across all states-of-charge.
J. Mater. Chem. A, 2025,13, 6314-6324
https://doi.org/10.1039/D4TA06041E
Recent advances in characterization of rechargeable battery materials via scanning probe microscopy
Scanning probe microscopy can be used to obtain topographical, mechanical, electrical, and electrochemical information on a wide range of materials in a variety of environments, including in situ and operando studies for rechargeable battery systems.
J. Mater. Chem. A, 2025,13, 5561-5581
https://doi.org/10.1039/D4TA05975A
Sorbent-based atmospheric water harvesting: engineering challenges from the process to molecular scale
Atmospheric water harvesting is an emerging technique that can potentially increase water access to water-constrained communities.
J. Mater. Chem. A, 2025,13, 4838-4850
https://doi.org/10.1039/D4TA06883A
Recent advances in interface engineering of Iron triad metal phosphides electrocatalysts towards enhanced hydrogen evolution reaction performance
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04085J
Thermally Insulating Radiative Coolers: Fundamentals, Manufacturing, and Applications in Energy-Efficient Buildings
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03930D
Hydrate-based H2 storage with porous materials as heterogeneous promoters: state of the art and challenges
A multiscale strategy for porous material-assisted H2 hydrate storage, bridging materials properties and engineering operations.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04503G
Covalent organic framework-derived functional interphase for improving Zn chemistry in aqueous zinc-ion batteries
This review systematically summarizes the cutting-edge development of covalent organic framework-derived functional interphases for improving Zn chemistry in aqueous zinc-ion batteries.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04055H
Triple-junction all-perovskite solar cells: a review
This paper reviews the working principles and key parameters of TJPSCs and presents recent research progress, focuses on how component optimization, interface engineering, and charge transport layer improvements influence efficiency.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03389F
Engineering crystalline property of polymer solid electrolytes for boosted electrochemical performances: a critical review
Summary of crystalline property engineering of SPEs.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04066C
Recent progress in high-entropy intermetallics for advanced catalysis
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04394H
Recent advances in biohybrid membranes for water treatment: preparation strategies, nano-hybridization, bioinspired functionalization, applications, and sustainability analysis
We present a comprehensive review on the synthesis, nano-hybridization, bioinspiration functionalization, water treatment, and sustainability of biohybrid membranes.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04214C
MXene-based zinc-ion batteries: synthesis, applications, and strategies for performance optimization
Aqueous zinc-ion batteries (ZIBs) have garnered significant research attention due to their distinct advantages, such as low cost, safety, and environmental compatibility.
J. Mater. Chem. A, 2025,13, 23227-23247
https://doi.org/10.1039/D5TA02048D
Recent advances in anti-fouling oil–water separation membranes: a review focusing on active and passive anti-fouling strategies
Illustration of active and passive anti-fouling strategies in oil–water separation membranes.
J. Mater. Chem. A, 2025,13, 23418-23438
https://doi.org/10.1039/D5TA03722K
An in-depth understanding of highly crystalline carbon nitride for near-infrared photocatalysis: from n → π* transition to midgap state engineering
This minireview systematically summarizes the research progress and mechanistic breakthroughs of highly crystalline carbon nitride in the field of near-infrared photocatalysis from n → π* electron transition to midgap state engineering.
J. Mater. Chem. A, 2025,13, 23312-23322
https://doi.org/10.1039/D5TA03785A
Zirconium-based MOFs for light-driven reactions: a critical assessment of recent progress
This review summarizes progress on Zr-MOFs in light-driven CO2 reduction, hydrogen evolution, and pollutant degradation. It highlights their stability, tunable porosity, and strategies to boost photocatalytic performance for sustainable and environmental applications.
J. Mater. Chem. A, 2025,13, 23377-23417
https://doi.org/10.1039/D5TA02797G
Macrocycle-containing metal–organic frameworks in adsorption and related applications
A periodic summary is given for the current development stage of the adsorbents constructed using macrocycle-containing metal–organic frameworks.
J. Mater. Chem. A, 2025,13, 23354-23376
https://doi.org/10.1039/D5TA02670A
Progress on polymer-based materials and composites for humidity sensor applications: from materials aspects to sensor performances
Polymers and their composites are efficient sensing materials for humidity sensor applications because of their favorable properties such as water ad/absorption, flexibility, and hygroscopicity.
J. Mater. Chem. A, 2025,13, 23248-23311
https://doi.org/10.1039/D5TA00028A
Recent advancements in carbon capture materials research: innovative optimization of materials synthesis and engineering applications
The escalating urgency of global climate change has propelled the advancement of efficient carbon capture technologies.
J. Mater. Chem. A, 2025,13, 23323-23353
https://doi.org/10.1039/D5TA01304F
From energy to intelligence: MXenes transforming triboelectric nanogenerators
Incorporating the MXenes as electrodes, positive and negative tribolayers in triboelectric nanogenerators enhances the TENGs' performance.
J. Mater. Chem. A, 2025,13, 23170-23226
https://doi.org/10.1039/D5TA02391B
Advances in topological quantum materials for energy conversion
Topological surface states enhances charge transport in solar cell, water splitting and photoelectrochemical cells. They can have a great impact on reducing charge recombination, dye degradation, corrosion and heat losses leading to enhanced PCE.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02897C
Recent advances in MBenes for Li/Na-ion batteries: from synthesis to application
This review examines MBenes for their structural versatility and electrochemical performance in Li/Na-ion batteries, while addressing synthesis challenges and outlining future research directions for next-generation energy storage.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04141D
Towards longevity in solid oxide electrolysis cells: multi-scale modeling and machine learning for degradation diagnosis and mitigation
The degradation of SOECs is influenced by coupling across multiple scales. It is necessary to consider establishing a full-chain research framework that integrates multiscale numerical simulations with artificial intelligence methods.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03711E
Recent advances in NASICON-type materials for high-performance capacitive deionization: Design strategies and mechanistic insights
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04112K
Polymers for perovskite solar cells: advances and perspectives
This review summarizes recent advancements of polymers in perovskite solar cells (PSCs), revealing their mechanisms and guiding future developments.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02970H
Advances in CO catalytic oxidation on typical metal oxide catalysts: performance, mechanism, and optimization
Review of CO oxidation over CuOx, MnOx, CeOx, CoOx: surface, lattice, vacancies, valence; L–H, MvK, E–R mechanisms; low-T, poisoning, stability issues; defect, facet, synergy, interface tuning; flue gas & air purify.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03067F
Integrated photothermal and photocatalytic degradation of micro-/nanoplastics: a mini-review with mechanistic insights and future perspectives
Sources of MNPs and various treatment approaches.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03680A
Unlocking the Potential of Strontium Iridate for Oxygen Evolution Reaction: From Fundamental Insights to Advanced Electrocatalyst Design
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04873G

High throughput computational and experimental methods for accelerated electrochemical materials discovery
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA00331H
Ion flux regulation in aqueous zinc-ion batteries
Establishing uniform ion flux profiles collectively mitigates cathode dissolution, suppresses zinc dendrite proliferation and stabilizes interfacial charge transfer, which are critical milestones toward practical development of zinc ion batteries.
J. Mater. Chem. A, 2025,13, 22324-22364
https://doi.org/10.1039/D5TA01379H

Progress in porous metal chalcogenides for electrocatalytic water splitting
This work reviews the progress in porous metal chalcogenides for electrocatalytic water splitting, highlighting their innovative design, the importance of the surface area, electrochemical performance, challenges, and future opportunities.
J. Mater. Chem. A, 2025,13, 22271-22294
https://doi.org/10.1039/D5TA03489B
Progress and prospects of high-pressure CO2 electrocatalytic reduction
This review discusses the role of pressure intervention in regulating eCO2RR to produce C1 and C2+ products, the mutual influence and synergistic effects of pressure with other reaction microenvironments, CO and non-aqueous CO2 electroreduction.
J. Mater. Chem. A, 2025,13, 22295-22323
https://doi.org/10.1039/D5TA03027G
3D-printed electromagnetic microwave absorption structures: a comprehensive review
The work focuses on the mechanisms of electromagnetic microwave (EMW) structures and the applications of various 3D printing technologies in the fabrication of EMW structures.
J. Mater. Chem. A, 2025,13, 22240-22270
https://doi.org/10.1039/D5TA02073E
Interstitial cobalt nitrides (CoxN): holistic frontiers in energy storage and catalysis
This review explores the roles of CoxN in LIBs, SCs, RZABs, and electrocatalysis, focusing on fabrication strategies and structure–property–performance relationships to guide the design of efficient and durable electrochemical energy systems.
J. Mater. Chem. A, 2025,13, 22200-22239
https://doi.org/10.1039/D5TA02335A

Fundamental concepts of 3,4-alkoxythiophene-based polymeric systems, from synthesis to applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03149D
Recent Developments in Addressing Challenges for Polymeric-Based Solid-State Lithium-Sulfur Batteries
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03664J
Advances in metal–organic framework-based materials for sustainable energy solutions
This review summarizes recent advances in using MOFs and their derivatives for energy storage, focusing on MOF-derived carbon heterostructures and metal compound modifications to enhance performance through material and structural optimization.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03212A
High-entropy materials for electrocatalytic oxygen reduction reaction
This review highlights the structural diversity and entropy-driven design of high-entropy materials for oxygen reduction, revealing key structure–activity relationships and guiding future electrocatalyst development.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03392F
Bioinspired self-sensing materials: from comprehensive advances to outlook on self-monitoring water-lubricated bearings
This review introduces the phenomena and mechanisms of stimulus perception in nature, summarizes the research progress on bioinspired self-sensing materials in engineering, and explores their potential applications in water-lubricated bearings.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02603B
Interfacial chemistry of CuBi2O4 in aqueous media: engineering strategies for energy and environmental applications
We conducted a systematic analysis of CuBi2O4's surface and interface interactions, investigated a series of novel solutions for CuBi2O4-related challenges, and summarized some of its key applications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04609B
2D covalent organic frameworks: organic electrode materials for aqueous batteries
A review about 2D covalent organic frameworks as organic electrode materials for aqueous batteries.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03752B
Recent status, key strategies and challenging perspectives of smart batteries for next-generation batteries
This review provides a comprehensive overview of the current development of smart batteries, which can be divided into three parts: smart materials, smart manufacturing and smart sensing.
J. Mater. Chem. A, 2025,13, 21116-21171
https://doi.org/10.1039/D5TA01989C
Helmholtz plane engineering for stable zinc anodes: from interfacial dynamics to long-cycle battery design
By adjusting the composition of the inner Helmholtz plane and the outer Helmholtz plane, it is expected to improve the desolvation structure of zinc ions, inhibit the side reaction of zinc anode and enhance the long-cycle performance of the battery.
J. Mater. Chem. A, 2025,13, 21172-21180
https://doi.org/10.1039/D5TA03553H
Solid–liquid phase change materials meet hydrogels: syntheses and multifunctional applications
Phase change hydrogels (PCHs), used in multiple engineering scenarios, have been developed to overcome leakage, structural instability, and low thermal conductivity of solid–liquid phase-change materials.
J. Mater. Chem. A, 2025,13, 21245-21267
https://doi.org/10.1039/D5TA00346F
Recent advances in electrocatalytic reduction of nitrate to ammonia: current challenges, resolving strategies, and future perspectives
This review clearly elucidates the lineage of the development of NO3−RR from the theoretical mechanism to practical reactions and deepens the understanding of NO3−RR, pointing out the direction for the advanced design of NO3−RR electrocatalysts.
J. Mater. Chem. A, 2025,13, 21181-21232
https://doi.org/10.1039/D5TA02848E
Spinel-structured photoelectrodes for photoelectrochemical energy and environmental applications: synergistic photothermal–magnetic effects
Spinel photovoltaic electrodes for PEC energy conversion and environmental treatment and their photothermal and magnetic effects synergistically promoting PEC systems.
J. Mater. Chem. A, 2025,13, 21389-21420
https://doi.org/10.1039/D5TA02278A
Recent advances in material regulation and structure design for high-performance aqueous anode-free zinc batteries
This review explores strategies to enhance the performance of aqueous anode-free zinc batteries through electrolyte optimization, additives, and current collector design, aiming to unlock their full potential.
J. Mater. Chem. A, 2025,13, 21233-21244
https://doi.org/10.1039/D5TA02463C
A critical review on recent advancements in metal–organic frameworks for CO2 capture, storage and utilization
One of the biggest problems our world is currently facing is climate change caused by rising atmospheric CO2 levels.
J. Mater. Chem. A, 2025,13, 21352-21388
https://doi.org/10.1039/D5TA02338F
Recent progress in metal–organic framework-based materials for electrocatalytic carbon dioxide reduction
The utilization of renewable electricity to turn CO2 into treasure through electrocatalytic CO2 reduction (eCO2RR), as well as the conversion of excess electricity into chemical energy storage, has become one of the research hotspots.
J. Mater. Chem. A, 2025,13, 21268-21291
https://doi.org/10.1039/D5TA02285A
Recent advances and future directions of CdIn2S4-based photocatalysts: properties, synthesis, and modifications for energy and environmental applications
CdIn2S4-based photocatalysts are promising in many energy and environmental applications such as hydrogen production, selective oxidation of organics, and some dual-functional systems.
J. Mater. Chem. A, 2025,13, 21292-21351
https://doi.org/10.1039/D5TA02047F
A comprehensive review of form-stable phase change materials in cold chain logistics: encapsulation strategies, thermal conductivity enhancement, and applications
Integration diagram of FSPCMs, including preparation methods, thermal conductivity enhancement, and application in cold chain logistics.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01227A
Proton co-intercalation enabled high-performance aqueous multivalent metal-ion batteries
Aqueous rechargeable batteries have emerged as promising candidates for large-scale energy storage due to their inherent safety, low cost, and environmental friendliness.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03599F
A paradigm shifts in the arena of nano lubricants from ICEVs to EVs: present perspective and future directions
The transient shift from ICEVs to EVs reveals a paradigm shift in lubrication perspective. Net zero greenhouse emission, energy efficiency and eco-sustainability are the key drivers behind this shifting.
J. Mater. Chem. A, 2025,13, 20319-20354
https://doi.org/10.1039/D5TA01123J
Strategies to mitigate Sr segregation of the LSCF oxygen electrode for solid oxide cells
Addressing the Sr segregation in LSCF oxygen electrode to enhance the long-term stability is essential for solid oxide cells (SOCs) operating in both fuel cell and electrolysis cell modes to realize large-scale energy storage.
J. Mater. Chem. A, 2025,13, 20268-20288
https://doi.org/10.1039/D5TA01308A
Manganese-based catalysts for the catalytic oxidation of chlorinated volatile organic compounds (CVOCs): critical properties, deactivation mechanisms, and design strategies
This review summarizes the characteristics, deactivation pathways, and design strategies of Mn-based catalysts for the catalytic oxidation of CVOCs. The objective is to provide insights for the development of highly efficient Mn-based catalysts.
J. Mater. Chem. A, 2025,13, 20234-20267
https://doi.org/10.1039/D5TA02122G
Recent advances and prospects of flexible zinc ion batteries from material principles to device structure designs
Mechanisms of flexible zinc-ion battery components and device design principles were explored, guiding innovative structural designs based on mechanistic analysis.
J. Mater. Chem. A, 2025,13, 20289-20318
https://doi.org/10.1039/D5TA01860A
Recent advances in hybrid supercapacitors: a review of high performance materials and scalable fabrication techniques
A comprehensive review highlighting recent advancements in high-performance materials and scalable fabrication techniques for next-generation hybrid supercapacitors.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02887F
Non-noble-metal catalysts for electrocatalytic ammonia oxidation
Ammonia emerges as a high-energy density, carbon-free medium for the storage, transport, and utilization of green electricity.
J. Mater. Chem. A, 2025,13, 20176-20199
https://doi.org/10.1039/D5TA02105G
Interfacial regulation of photoanodes for photoelectrochemical water splitting: the roles of the interlayer and overlayer
Here, a systematic understanding of the role and design principles of functional interlayers is presented for improving charge separation and transport efficiency and accelerating surface catalytic reactions of photoanodes.
J. Mater. Chem. A, 2025,13, 20200-20233
https://doi.org/10.1039/D5TA01066G
Advances in the preparation strategies and structural regulation for CeO2-containing electrocatalysts applied to the anodes of direct alcohol fuel cells: a comprehensive review
Direct alcohol fuel cells (DAFCs) are promising clean energy systems that directly transform the chemical energy of liquid alcohols into electricity.
J. Mater. Chem. A, 2025,13, 20143-20175
https://doi.org/10.1039/D5TA01696G
About this collection
This collection contains recent Review-type articles published by Journal of Materials Chemistry A, the home for high impact applications, properties and synthesis of exciting new materials for energy and sustainability.
New articles will be added to this collection as soon as possible after publication.