Themed collection Most Highly Cited in RSC Energy 2024

Updated perspective on solar steam generation application
This perspective highlights the challenges and opportunities in interfacial evaporation, heat and water management, materials synthesis, and device development for solar steam generation.
Energy Environ. Sci., 2024,17, 2088-2099
https://doi.org/10.1039/D3EE04073A

Selective catalytic reduction of NOx with NH3 over copper-based catalysts: recent advances and future prospects
This review presents the important progress of Cu-based catalysts for the NH3-SCR reaction. Special attention is given to elucidating the design of high-performance catalysts, as well as anti-inactivation measures in industrial applications.
EES Catal., 2024,2, 231-252
https://doi.org/10.1039/D3EY00210A

Recent advances in layered double hydroxide (LDH)-based materials: fabrication, modification strategies, characterization, promising environmental catalytic applications, and prospective aspects
Layered double hydroxides (LDHs) are clay networks with brucite (Mg(OH2)) layers that are coupled with anions between the produced layers.
Energy Adv., 2024,3, 2136-2151
https://doi.org/10.1039/D4YA00272E
Flatland materials for photochemical and electrochemical nitrogen fixation applications: from lab-door experiments to large-scale applicability
Flatland materials were meticulously surveyed to explore their functionality in photochemical and electrochemical nitrogen reduction reaction applications. New insights are presented for pilot-scale NRR operations via 2D materials.
Sustainable Energy Fuels, 2024,8, 3476-3495
https://doi.org/10.1039/D4SE00565A
Tailoring desolvation strategies for aqueous zinc-ion batteries
This review provides a comprehensive overview detailing the advancements in desolvation strategies pertaining to aqueous zinc-ion batteries (AZIBs) performances, addressing the applications and working mechanisms of desolvation strategies in AZIBs.
Energy Environ. Sci., 2024,17, 4819-4846
https://doi.org/10.1039/D4EE00313F

A review on the recent advances in the design and structure–activity relationship of TiO2-based photocatalysts for solar hydrogen production
The recent progress in visible light driven photocatalysis by describing the integration of TiO2 with variety of materials, and how it helps in tailoring electronic, structural and optical properties towards improved solar H2 production activity.
Energy Adv., 2024,3, 1472-1504
https://doi.org/10.1039/D4YA00249K

Rechargeable iron-ion (Fe-ion) batteries: recent progress, challenges, and perspectives
With the ever-increasing demand for efficient and sustainable energy solutions, rechargeable Fe-ion batteries have emerged as a viable alternative to conventional rechargeable batteries.
Energy Adv., 2024,3, 927-944
https://doi.org/10.1039/D4YA00101J

Cu-based catalysts for electrocatalytic nitrate reduction to ammonia: fundamentals and recent advances
This review provides an overview of Cu-based catalysts for electrocatalytic nitrate reduction to ammonia. It encompasses materials, reaction mechanisms, analysis methods and insights into the practical applications and economic prospects.
EES Catal., 2024,2, 727-752
https://doi.org/10.1039/D4EY00002A

Future costs of hydrogen: a quantitative review
A quantitative review of 89 hydrogen production cost forecasts, providing future prospects and multifaceted analyses.
Sustainable Energy Fuels, 2024,8, 1806-1822
https://doi.org/10.1039/D4SE00137K
Design and development of nanostructured photocatalysts for large-scale solar green hydrogen generation
Thin films mediated photocatalytic hydrogen production is the recent intriguing challenge to overcome the global energy demand. By development of fine nanomaterials and preparation of thin films hydrogen production can be increased to large scale.
Sustainable Energy Fuels, 2024,8, 1872-1917
https://doi.org/10.1039/D4SE00056K
Current advances and future outlook of heterogeneous catalytic transesterification towards biodiesel production from waste cooking oil
The demonstration of disposal and utilisation of waste cooking oil as potential feedstock towards biodiesel synthesis by catalytic heterogeneous transesterification.
Sustainable Energy Fuels, 2024,8, 1105-1152
https://doi.org/10.1039/D3SE01564E

Crystalline carbon nitrides for photocatalysis
This review comprehensively summarizes the recent advances on crystalline carbon nitrides, including their preparation, optimization strategies, photocatalytic applications, as well as challenges and prospects.
EES Catal., 2024,2, 411-447
https://doi.org/10.1039/D3EY00302G
Advanced design strategies for Fe-based metal–organic framework-derived electrocatalysts toward high-performance Zn–air batteries
This article summarizes the regulation strategies of Fe-based MOFs-derived electrocatalysts for ZABs, and provides a prospect for their future development.
Energy Environ. Sci., 2024,17, 1725-1755
https://doi.org/10.1039/D3EE04410F
Improvement of cycle life for layered oxide cathodes in sodium-ion batteries
In this review, research progress on layered oxide cathodes for SIBs in recent years is summarized, with emphasis on the problems of poor cycle life caused by irreversible phase transition, Jahn–Teller effect and interface deterioration, and several strategies are proposed to alleviate these issues.
Energy Environ. Sci., 2024,17, 1756-1780
https://doi.org/10.1039/D3EE02934D

Graphene-derived composites: a new Frontier in thermoelectric energy conversion
Diagram depicting the internal structure of various p-type and n-type legs in thermoelectric power generators.
Energy Adv., 2024,3, 389-412
https://doi.org/10.1039/D3YA00526G

MXene–carbon based hybrid materials for supercapacitor applications
Designing hybrid materials with superior electrochemical properties has attracted tremendous interest in recent years for energy-storage applications owing to a high demand for energy sources and the depletion of fossil fuel resources.
Energy Adv., 2024,3, 341-365
https://doi.org/10.1039/D3YA00502J

Recent progress in understanding the catalyst layer in anion exchange membrane electrolyzers – durability, utilization, and integration
This review discusses recent insights in catalyst layer design strategies for anion exchange membrane water electrolyzers, including electrode design, catalyst/ionomer integration, operational variables, in situ diagnostics, and cell durability.
EES Catal., 2024,2, 109-137
https://doi.org/10.1039/D3EY00193H

Single atom catalysts for water electrolysis: from catalyst-coated substrate to catalyst-coated membrane
This review summarizes the integration of single atom catalysts and catalyst-coated membrane architecture, exhibiting high utilization of SACs, facile ion transport, low interfacial resistance, and excellent scalability.
EES Catal., 2024,2, 49-70
https://doi.org/10.1039/D3EY00165B

Gas-phase errors in computational electrocatalysis: a review
In this review we show how DFT gas-phase errors affect computational models of electrocatalytic reactions.
EES Catal., 2024,2, 157-179
https://doi.org/10.1039/D3EY00126A

Structural engineering of catalysts for ammonia electrosynthesis from nitrate: recent advances and challenges
Electrocatalytic nitrate reduction to ammonia offers a sustainable approach for nitrogenous waste upcycling. This review outlines recent advances in the design of electrocatalysts through cross-scale structural engineering.
EES Catal., 2024,2, 202-219
https://doi.org/10.1039/D3EY00184A

Recent advances in tunable metal–support interactions for enhancing the photocatalytic nitrogen reduction reaction
Photocatalytic nitrogen reduction using inexhaustible solar energy has been considered as a promising strategy for NH3 synthesis. The design of heterogeneous photocatalysts with tunable MSIs is of great significance.
EES Catal., 2024,2, 180-201
https://doi.org/10.1039/D3EY00191A
Unlocking the local structure of hard carbon to grasp sodium-ion diffusion behavior for advanced sodium-ion batteries
The proposal of dispersion region can complete the HC model, explain the anomalous diffusion in the low-voltage region, guide the microstructure design of high-performance HC materials, and provide new insights into the storage mechanism of SIBs.
Energy Environ. Sci., 2024,17, 1387-1396
https://doi.org/10.1039/D3EE03347C

Modified Cu–Zn–Al mixed oxide dual function materials enable reactive carbon capture to methanol
A novel RCC process using modified CZA DFMs to produce renewable MeOH is presented. K/CZA provides exceptionally high productivity of MeOH compared to previously reported attempts of RCC to MeOH.
EES Catal., 2024,2, 253-261
https://doi.org/10.1039/D3EY00254C
Chemically tuned cellulose nanocrystals/single wall carbon nanosheet based electrodes for hybrid supercapacitors
Adopting a green and environmentally friendly strategy requires the development of supercapacitor electrodes using sustainable, renewable, and environmentally beneficial materials.
Sustainable Energy Fuels, 2024,8, 3595-3609
https://doi.org/10.1039/D4SE00286E
Design of Bi-functional mixed oxide electrodes for selective oxidative C–C cleavage of glycerol to formate and synchronized green hydrogen production
NiCoMn oxide nanoneedles with a cactus-like morphology are shown as bifunctional electrocatalysts that selectively oxidize glycerol to HCOOH and concurrently produce H2.
Sustainable Energy Fuels, 2024,8, 2954-2968
https://doi.org/10.1039/D4SE00434E

Exploring zinc oxide morphologies for aqueous solar cells by a photoelectrochemical, computational, and multivariate approach
Unveiling structure-performance relationship for different ZnO-based electrodes used for aqueous dye-sensitized solar cell.
Energy Adv., 2024,3, 1062-1072
https://doi.org/10.1039/D4YA00010B

Ag/Pd bimetallic nanoparticle-loaded Zr-MOF: an efficacious visible-light-responsive photocatalyst for H2O2 and H2 production
A noble bimetallic nanoparticle-modified UiO-66-NH2 MOF (Ag/Pd@UiO-66-NH2) composite photocatalyst for efficient hydrogen peroxide and hydrogen production.
Energy Adv., 2024,3, 1073-1086
https://doi.org/10.1039/D3YA00597F

Promoting water-splitting reaction on TiO2/gCN with Pd/SrO cocatalysts: H2 evolution in the absence of a sacrificial reagent
This study investigates Pd–SrO@TiO2/gCN photocatalysts for eco-friendly H2 generation through water splitting.
Energy Adv., 2024,3, 983-996
https://doi.org/10.1039/D4YA00045E
Importance of geometric effects in scaling up energy-efficient plasma-based nitrogen fixation
With the focus on feasibility evaluation of scaling-up plasma-based nitrogen fixation by combined experiments and thermodynamic modelling, we aim to tackle the challenge of design and development of an energy-efficient and scaled-up plasma reactor.
Sustainable Energy Fuels, 2024,8, 2191-2209
https://doi.org/10.1039/D3SE01615C

Bimetallic and plasmonic Ag and Cu integrated TiO2 thin films for enhanced solar hydrogen production in direct sunlight
Plasmonic metal nanoparticle integrated mesoporous TiO2 nanocomposites (Ag/TiO2, Cu/TiO2 and Ag–Cu/TiO2), prepared by a simple chemical reduction method, have been demonstrated to show superior activity in thin-film form for solar H2 generation.
Energy Adv., 2024,3, 829-840
https://doi.org/10.1039/D4YA00056K
Light-induced quinone conformation of polymer donors toward 19.9% efficiency organic solar cells
UV-light illumination converts the aromatic conformation of polymer donors into a rigid quinone structure, resulting in compact fibrillar aggregation of the active layer to achieve a maximum efficiency of 19.9% of single-junction organic solar cells.
Energy Environ. Sci., 2024,17, 2492-2499
https://doi.org/10.1039/D4EE00605D

A comparative techno-economic assessment of blue, green, and hybrid ammonia production in the United States
Low-carbon ammonia competitive with conventional process with policy support. Novel hybrid processes and biomethane integration can offer additional benefits.
Sustainable Energy Fuels, 2024,8, 1495-1508
https://doi.org/10.1039/D3SE01421E
Binary Ni–Cu nanocomposite-modified MXene-adorned 3D-nickel foam for effective overall water splitting and supercapacitor applications
Herein, a multifunctional binary nickel–copper-modified MXene on nickel foam was synthesized and employed as an electrode material for hydrogen evolution reaction (HER), oxygen evolution reaction (OER), overall water splitting and supercapacitors.
Sustainable Energy Fuels, 2024,8, 1509-1525
https://doi.org/10.1039/D4SE00058G
A high-entropy layered P2-type cathode with high stability for sodium-ion batteries
The configuration entropy is increased by substitution of beryllium and magnesium for nickel. And sodium-ion diffusion rate and cycling performance at high rates were improved with the co-doping strategy.
Sustainable Energy Fuels, 2024,8, 1304-1313
https://doi.org/10.1039/D3SE01597A
Modulating the electronic structure of Ni(OH)2 by coupling with low-content Pt for boosting the urea oxidation reaction enables significantly promoted energy-saving hydrogen production
A urea-assisted water splitting electrolyzer based on Pt nanoparticle-anchored Ni(OH)2@Ni-CNF catalyst and Pt@Ni-CNF catalyst is constructed for effectively reducing the energy consumption of H2 production.
Energy Environ. Sci., 2024,17, 1984-1996
https://doi.org/10.1039/D3EE03398H
1,5-Diiodocycloctane: a cyclane solvent additive that can extend the exciton diffusion length in thick film organic solar cells
The addition of cyclane 1,5-diiodocycloctane (DICO) provides critical roles in extending exciton diffusion length within active layer, consequently contributing to the improvement in the power conversion. efficiency in thick film organic solar cells.
Energy Environ. Sci., 2024,17, 1916-1930
https://doi.org/10.1039/D3EE04281B

Cooperative tungsten centers in polymeric carbon nitride for efficient overall photosynthesis of hydrogen peroxide
Meticulously designed neighboring WOR and ORR active sites significantly enhance the overall photocatalytic synthesis of hydrogen peroxide.
Energy Environ. Sci., 2024,17, 1520-1530
https://doi.org/10.1039/D3EE03032F
Double self-reinforced coordination modulation constructing stable Ni4+ for water oxidation
Nitrate ligands and Co atoms not only promote the formation of Ni4+ by accelerating deprotonation and attracting electrons, but also adsorb the electron-withdrawing bridge hydroxyl to stabilize Ni4+.
Energy Environ. Sci., 2024,17, 1468-1481
https://doi.org/10.1039/D3EE02627B

Manganese dissolution in alkaline medium with and without concurrent oxygen evolution in LiMn2O4
Manganese oxides such as LiMn2O4 exhibit two distinct Mn dissolution processes; one independent of oxygen evolution and the other associated with it. Less Mn4+ before the onset of the OER lowers the Mn dissolution rate.
Energy Adv., 2024,3, 504-514
https://doi.org/10.1039/D3YA00434A

Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity
Loading Pt exclusively on the surface of USY constructs a consecutive hydrocracking process of polyolefin wastes.
EES Catal., 2024,2, 300-310
https://doi.org/10.1039/D3EY00180F
About this collection
This collection highlights the top 10 most highly cited articles published in 2024 in each of the Royal Society of Chemistry’s energy journals; Energy & Environmental Science, EES Catalysis, Sustainable Energy & Fuels and Energy Advances. Featuring groundbreaking research at the forefront of sustainable energy science, these influential works span diverse topics from advanced energy conversion and storage technologies to innovative catalytic systems and clean fuel production.