Themed collection 2025 Inorganic Chemistry Frontiers Review-type Articles

Designing biomimetic catalytic systems for CO2 reduction to formate using NAD(P)H
This review article focuses on current achievements and identifies future research directions by designing biomimetic catalytic systems for CO2 reduction to formate using NAD(P)H.
Inorg. Chem. Front., 2025, Advance Article
https://doi.org/10.1039/D5QI00608B
Innovations in scintillator materials for X-ray detection
We review the latest developments in scintillator materials for X-ray detection thoroughly, including perovskites, nano-clusters, organic and rare-earth-doped compounds and specialized structures, and provide an in-depth insight for future prospects.
Inorg. Chem. Front., 2025, Advance Article
https://doi.org/10.1039/D5QI00671F
Dehydrogenation of Sodium Borohydride and Ammonia Borane over Cobalt-Based Catalysts: Advances and Prospects
Inorg. Chem. Front., 2025, Accepted Manuscript
https://doi.org/10.1039/D5QI00253B
Harnessing metal complexes to target tumour bioenergetics and metabolic vulnerabilities
This review comprehensively analyzes recent advances in metal complexes that not only impede the growth of cancer cells but also target altered metabolic pathways and induce immune response in resistant tumours.
Inorg. Chem. Front., 2025, Advance Article
https://doi.org/10.1039/D5QI00168D
Geometric and Electronic Perspectives on Dual-Atom Catalysts for Advanced Oxidation Processes
Inorg. Chem. Front., 2025, Accepted Manuscript
https://doi.org/10.1039/D5QI00478K
Toward highly durable aqueous zinc ion batteries: a review of MOFs/MOF-derived cathode materials
The authors summarize recent research progress on pristine MOFs and their derivatives for high-performance AZIBs and discuss the energy storage mechanisms.
Inorg. Chem. Front., 2025, Advance Article
https://doi.org/10.1039/D5QI00555H
Engineered molybdenum disulfide-based nanomaterials for capacitive deionization applications
This review summarized the methods for synthesizing MoS2-based nanomaterials and their application in capacitive deionization.
Inorg. Chem. Front., 2025, Advance Article
https://doi.org/10.1039/D4QI03147D

Comprehensive coordination chemistry of iminophosphonamides
This review summarizes the reported iminophosphonamide complexes of s-block, p-block, transition and f-block metals. Furthermore, the recent development in the field of chiral iminophosphonamide metal complexes is also discussed.
Inorg. Chem. Front., 2025, Advance Article
https://doi.org/10.1039/D5QI00275C
Structural diversity and photocurrent responses of multi-component chalcogenidometalates
This review offers an overview of recent advancements in novel multi-component chalcogenidometalates, emphasizing the intrinsic relationships between composition, structure, and photocurrent properties.
Inorg. Chem. Front., 2025,12, 3018-3040
https://doi.org/10.1039/D5QI00110B
MOF-based electrode materials for aqueous zinc-ion batteries: design strategy and future challenges
Summary of MOF-based aqueous zinc-ion battery electrode materials design strategies.
Inorg. Chem. Front., 2025,12, 2988-3017
https://doi.org/10.1039/D5QI00159E

Investigation of metallodrug/protein interaction by X-ray crystallography and complementary biophysical techniques
Selected studies carried out in the field of protein metalation, where the structural information achieved by X-ray crystallography has been complemented by other biophysical techniques, are described.
Inorg. Chem. Front., 2025, Advance Article
https://doi.org/10.1039/D4QI03277B
Design principles of metal phosphides for the oxygen evolution reaction in seawater: activity, selectivity and stability
Direct seawater electrolysis technology shows great potential, but chloride ions corrode the electrodes and cause competitive reactions, which limits its application.
Inorg. Chem. Front., 2025,12, 2554-2586
https://doi.org/10.1039/D4QI03108C

Design, analysis, and application of metal–organic framework derived carbons
MOF-derived carbons are a class of porous material that combine the stability of porous carbon with the functionality and versatility of MOFs. This review describes the systematic design, characterization, and application of these materials.
Inorg. Chem. Front., 2025,12, 2194-2209
https://doi.org/10.1039/D4QI03205E
Selenoborates: a latent structure resource for infrared functional crystal materials
This work reviews selenoborates, categorizing them by structure, synthesis methods, and highlighting their bandgaps, nonlinear optical properties, and potential as IR functional materials.
Inorg. Chem. Front., 2025,12, 2182-2193
https://doi.org/10.1039/D4QI02770A
Review on Ti3C2 MXene-based binary and ternary composites for photocatalytic applications
Ti3C2/TiO2 and C@TiO2 based composites for photocatalytic applications.
Inorg. Chem. Front., 2025,12, 2138-2181
https://doi.org/10.1039/D4QI02912G
Design strategies and applications of electrochemiluminescence from metal nanoclusters
We summarize the design strategies for improving the ECL of metal nanoclusters, including 1. aggregation-induced emission; 2. anodic pre-oxidation; 3. aggregation-induced self-loading; 4. Anionic substitution; 5. ion doping; 6. valence engineering.
Inorg. Chem. Front., 2025,12, 1798-1811
https://doi.org/10.1039/D4QI02461C
Bi2MO6 (M = Mo, W) Aurivillius oxides for efficient photocatalytic N2-to-NH3 conversion: a perspective review
This summary describes and elucidates an enhanced strategy for photocatalytic nitrogen fixation over Bi2MO6 (M = Mo, W)-based catalysts and points out the development prospects of photocatalytic nitrogen fixation.
Inorg. Chem. Front., 2025,12, 1773-1797
https://doi.org/10.1039/D4QI03182B
Optimization of electronic structure by defect engineering for electrocatalytic carbon dioxide reduction reaction
This paper reviews the progress of defective Cu-based materials for eCO2RR, highlights the design strategy for defect structure and emphasizes the mechanism of defect site on catalytic behaviors.
Inorg. Chem. Front., 2025,12, 1743-1772
https://doi.org/10.1039/D4QI02711F

Recent advances in computational modelling of mononuclear actinide single molecule magnets
In this review, we have highlighted computational studies on actinide-based mononuclear single-molecule magnets, focusing on compounds containing the elements U, Np, Pu, and Cf.
Inorg. Chem. Front., 2025,12, 1349-1370
https://doi.org/10.1039/D4QI02326A
In situ oxygen generation by a low-toxicity ruthenium electrocatalyst for multimodal radiotherapy sensitization
Tumor hypoxia limits the efficacy of radiotherapy. Therefore, we used a low-toxicity catalyst with high Z-atoms to improve the efficacy of radiotherapy by generating oxygen through in situ electrocatalysis of tumour.
Inorg. Chem. Front., 2025,12, 1857-1866
https://doi.org/10.1039/D4QI03065F
About this collection
Critical reviews, highlights and chemistry frontiers articles published in Inorganic Chemistry Frontiers during 2024 are collated as below for the benefit of readers.