Themed collection Journal of Materials Chemistry A Recent Review Articles

Topological quantum materials in catalysis
Let's quantum: topological quantum materials offer high electron mobility, stable surface states, and resistance to contamination, making them ideal candidates for next-generation heterogeneous catalysts.
J. Mater. Chem. A, 2025,13, 6325-6341
https://doi.org/10.1039/D4TA08325C
How common is it to get an OER overpotential that is <250 mV?
This work raises concerns about the unintentional mistakes made by researchers developing OER electrocatalysts by overlooking the fundamentals.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00009B

On the use of bioprecursors for sustainable silicon-based anodes for Li-ion batteries
Plants and protists: promising sources for Si-based Li-ion battery anodes.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02555A
Advances and industrialization of LiFePO4 cathodes in electric vehicles: challenges, innovations, and future directions
Evolution, research focus, industrialization and recovery techniques of LiFePO4 cathodes are reviewed, highlighting their critical role in meeting energy demands, especially in EVs.
J. Mater. Chem. A, 2025,13, 17271-17283
https://doi.org/10.1039/D5TA00166H
Unveiling the significance of working electrode substrates in electrocatalytic water splitting for sustainable hydrogen energy production
This perspective highlights how electrode substrate choice critically affects electrocatalyst performance in water splitting, guiding researchers to design better catalysts by leveraging each substrate’s unique properties.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02980E
From lab to market: the future of zinc–air batteries powered by MOF/MXene hybrids
Zinc–air batteries (ZABs) stand at the forefront of energy storage technologies. However, challenges like slow kinetics and low rechargeability persist. MOF–MXene hybrids enhance performance, enabling sustainable ZAB technology.
J. Mater. Chem. A, 2025,13, 12855-12890
https://doi.org/10.1039/D5TA01344E
Recent advancements in metal–organic frameworks (MOFs) for flexible supercapacitors aimed at wearable technology
Flexible supercapacitors have made significant progress, as they can be integral to the wearable technology field due to their unique ability to allow seamless movement for the wearer.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01159K
Sulfur element achieves rapid and stable migration of Li+ in oxide cathode materials
Higher energy density can be obtained by increasing the charging cut-off voltage of Ni-rich materials to meet the range requirements of electric vehicles.
J. Mater. Chem. A, 2025,13, 9039-9048
https://doi.org/10.1039/D4TA09238D

Capacity-weighted figures-of-merit for battery transport metrics
Fast-charging materials are necessary for a battery-centric future. Ionic and electronic transport crucially determine performance where their capacity-weighted figures-of-merit account for performance across all states-of-charge.
J. Mater. Chem. A, 2025,13, 6314-6324
https://doi.org/10.1039/D4TA06041E
Recent advances in characterization of rechargeable battery materials via scanning probe microscopy
Scanning probe microscopy can be used to obtain topographical, mechanical, electrical, and electrochemical information on a wide range of materials in a variety of environments, including in situ and operando studies for rechargeable battery systems.
J. Mater. Chem. A, 2025,13, 5561-5581
https://doi.org/10.1039/D4TA05975A
Sorbent-based atmospheric water harvesting: engineering challenges from the process to molecular scale
Atmospheric water harvesting is an emerging technique that can potentially increase water access to water-constrained communities.
J. Mater. Chem. A, 2025,13, 4838-4850
https://doi.org/10.1039/D4TA06883A
Recent Advances in Anti-Fouling Oil-Water Separation Membranes: A Review Focusing on Active and Passive Anti-Fouling Strategies
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03722K

Progress in porous metal chalcogenides for electrocatalytic water splitting
This work reviews the progress in porous metal chalcogenides for electrocatalytic water splitting, highlighting their innovative design, the importance of the surface area, electrochemical performance, challenges, and future opportunities.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03489B
Progress and prospects of high-pressure CO2 electrocatalytic reduction
This review discusses the role of pressure intervention in regulating eCO2RR to produce C1 and C2+ products, the mutual influence and synergistic effects of pressure with other reaction microenvironments, CO and non-aqueous CO2 electroreduction.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03027G
3D-printed electromagnetic microwave absorption structures: a comprehensive review
The work focuses on the mechanisms of electromagnetic microwave (EMW) structures and the applications of various 3D printing technologies in the fabrication of EMW structures.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02073E
Interstitial cobalt nitrides (CoxN): holistic frontiers in energy storage and catalysis
This review explores the roles of CoxN in LIBs, SCs, RZABs, and electrocatalysis, focusing on fabrication strategies and structure–property–performance relationships to guide the design of efficient and durable electrochemical energy systems.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02335A
Cutting-edge advances for the positive electrode in aqueous K-ion batteries: exploring electrochemical properties, structural designs, and applicable perspectives
This paper summarizes positive electrode materials for aqueous K-ion batteries, analyzing their electrochemical performance and modification strategies, while providing perspectives on positive electrode materials.
J. Mater. Chem. A, 2025,13, 18146-18182
https://doi.org/10.1039/D5TA00894H

Triplet–triplet annihilation upconversion sensitized with nanocrystals for a new generation of photocatalytic systems
Nanocrystal (NC) sensitizers enable triplet–triplet annihilation photon upconversion (TTA-UC), converting NIR or visible light into higher-energy photons and offering promising potential for applications, especially in solar-driven reactions.
J. Mater. Chem. A, 2025,13, 18115-18145
https://doi.org/10.1039/D5TA01541C
Research progress onconductive hydrogels and their applications in flexible sensors: a review
Conductive hydrogels are a class of novel conductive materials characterized by a biomimetic structure, excellent conductivity, adjustable mechanical properties, and diverse functionalities and structures.
J. Mater. Chem. A, 2025,13, 18062-18080
https://doi.org/10.1039/D5TA01456E
Exploring spinel oxides from bimetallic to high-entropy with a focus on the structure and performance in the oxygen evolution reaction
A schematic representation of the transformation from bimetallic to high entropy spinel oxides for the oxygen evolution reaction.
J. Mater. Chem. A, 2025,13, 18040-18061
https://doi.org/10.1039/D5TA01363A
Electrochemical H/D isotope separation
Three main systems for electrochemical H/D separation, including water electrolysis, fuel cell, and electrochemical hydrogen pump systems.
J. Mater. Chem. A, 2025,13, 18081-18114
https://doi.org/10.1039/D5TA02337H
ZnIn2S4-based heterostructure photocatalysts for solar energy conversion: a comprehensive review
This review systematically summarizes the latest research progress in ZnIn2S4-based heterostructure photocatalysts for solar energy conversion.
J. Mater. Chem. A, 2025,13, 18253-18282
https://doi.org/10.1039/D5TA02501J
Molecular sieve confined catalysts for the catalytic combustion of VOCs: preparation, application and future development
Review of molecular sieve-confined catalysts for VOCs abatement, merits/limitations, mechanisms, and structure-activity relationships. Future catalyst design, mechanistic studies, and in situ characterization advancements explored.
J. Mater. Chem. A, 2025,13, 18209-18252
https://doi.org/10.1039/D5TA01092F
Cathode materials for proton batteries: recent advances and perspectives
This review systematically classifies and evaluates cathode materials for proton batteries, categorizing them into three distinct groups: inorganic materials, organic materials and emerging materials.
J. Mater. Chem. A, 2025,13, 18183-18208
https://doi.org/10.1039/D5TA02851E
Recent advances in electrocatalytic reduction of nitrate to ammonia: current challenges, resolving strategies, and future perspectives
This review clearly elucidates the lineage of the development of NO3−RR from the theoretical mechanism to practical reactions and deepens the understanding of NO3−RR, pointing out the direction for the advanced design of NO3−RR electrocatalysts.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02848E
In-Depth Understanding of Highly Crystalline Carbon Nitride for Near-Infrared Photocatalysis: From n→π* Transition to Midgap State Engineering
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03785A
Helmholtz plane engineering for stable zinc anodes: from interfacial dynamics to long-cycle battery design
By adjusting the composition of the inner Helmholtz plane and the outer Helmholtz plane, it is expected to improve the desolvation structure of zinc ions, inhibit the side reaction of zinc anode and enhance the long-cycle performance of the battery.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03553H
Spinel-structured photoelectrodes for photoelectrochemical energy and environmental applications: synergistic photothermal–magnetic effects
Spinel photovoltaic electrodes for PEC energy conversion and environmental treatment and their photothermal and magnetic effects synergistically promoting PEC systems.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02278A
A critical review on recent advancements in metal–organic frameworks for CO2 capture, storage and utilization
One of the biggest problems our world is currently facing is climate change caused by rising atmospheric CO2 levels.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02338F
Zirconium-Based MOFs for Light-Driven Reactions: A Critical Assessment of Recent Progress
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02797G
Lignocellulosic Biomass and its Main Structural Polymers as Sustainable Electrode Materials for (Bio)Sensing Applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02900G
Recent advances and future directions of CdIn2S4-based photocatalysts: properties, synthesis, and modifications for energy and environmental applications
CdIn2S4-based photocatalysts are promising in many energy and environmental applications such as hydrogen production, selective oxidation of organics, and some dual-functional systems.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02047F
Ion Flux Regulation in Aqueous Zinc-ion Batteries
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01379H
Recent status, key strategies and challenging perspectives of smart batteries for next-generation batteries
This review provides a comprehensive overview of the current development of smart batteries, which can be divided into three parts: smart materials, smart manufacturing and smart sensing.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01989C
Macrocycle-containing metal-organic frameworks in adsorption and related applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02670A
Solid–liquid phase change materials meet hydrogels: syntheses and multifunctional applications
Phase change hydrogels (PCHs), used in multiple engineering scenarios, have been developed to overcome leakage, structural instability, and low thermal conductivity of solid–liquid phase-change materials.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00346F
Recent progress in Ru electrocatalyst design for acidic oxygen evolution reaction
This review surveys recent advances in Ru-based electrocatalysts for the acidic OER, focusing on strategies to enhance activity and stability, mitigate Ru dissolution and performance degradation, and inform the design of robust PEMWE.
J. Mater. Chem. A, 2025,13, 17214-17241
https://doi.org/10.1039/D5TA01849H
Recent progress in metal–organic framework-based materials for electrocatalytic carbon dioxide reduction
The utilization of renewable electricity to turn CO2 into treasure through electrocatalytic CO2 reduction (eCO2RR), as well as the conversion of excess electricity into chemical energy storage, has become one of the research hotspots.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02285A

Probing solid-state battery aging: evaluating calendar vs. cycle aging protocols via time-resolved electrochemical impedance spectroscopy
The degradation behavior of In/InLi|Li6PS5Cl|NCM83:Li6PS5Cl battery cell was investigated using two different accelerated aging protocols to evaluate their ability to fast screen solid-state batteries.
J. Mater. Chem. A, 2025,13, 17261-17270
https://doi.org/10.1039/D5TA01083G
Machine learning-accelerated exploration on element doping-triggering material performance improvement for energy conversion and storage applications
The prediction performances of machine learning in the field of element-doped materials for energy conversion and storage applications are summarized.
J. Mater. Chem. A, 2025,13, 17197-17213
https://doi.org/10.1039/D5TA00922G
Recent advances in Cu-based intermetallics: structures, syntheses, and electrocatalytic applications
This review focuses on the latest developments in Cu-based intermetallics, covering their structures, synthesis methods, and electrocatalytic applications.
J. Mater. Chem. A, 2025,13, 17242-17260
https://doi.org/10.1039/D5TA02448J
Rational design and construction of aqueous multivalent metal ion battery systems
Energy storage chemistry of the cathode and anode of aqueous multivalent metal ion batteries and present their recent progress are reviewed and discussed. Progress in theoretical simulations of their energy storage modes is then reviewed.
J. Mater. Chem. A, 2025,13, 17159-17196
https://doi.org/10.1039/D5TA02196K

Mixed matrix membranes for hydrogen separation: a comprehensive review and performance analysis
This article discusses the current trend and performance evaluation of mixed matrix membranes for hydrogen separation.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00834D
A paradigm shifts in the arena of nano lubricants from ICEVs to EVs: present perspective and future directions
The transient shift from ICEVs to EVs reveals a paradigm shift in lubrication perspective. Net zero greenhouse emission, energy efficiency and eco-sustainability are the key drivers behind this shifting.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01123J
Strategies to mitigate Sr segregation of the LSCF oxygen electrode for solid oxide cells
Addressing the Sr segregation in LSCF oxygen electrode to enhance the long-term stability is essential for solid oxide cells (SOCs) operating in both fuel cell and electrolysis cell modes to realize large-scale energy storage.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01308A
Recent advances and prospects of flexible zinc ion batteries from material principles to device structure designs
Mechanisms of flexible zinc-ion battery components and device design principles were explored, guiding innovative structural designs based on mechanistic analysis.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01860A
Recent advances in material regulation and structure design for high-performance aqueous anode-free zinc batteries
This review explores strategies to enhance the performance of aqueous anode-free zinc batteries through electrolyte optimization, additives, and current collector design, aiming to unlock their full potential.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02463C
Manganese-based catalysts for the catalytic oxidation of chlorinated volatile organic compounds (CVOCs): critical properties, deactivation mechanisms, and design strategies
This review summarizes the characteristics, deactivation pathways, and design strategies of Mn-based catalysts for the catalytic oxidation of CVOCs. The objective is to provide insights for the development of highly efficient Mn-based catalysts.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02122G
Interfacial regulation of photoanodes for photoelectrochemical water splitting: the roles of the interlayer and overlayer
Here, a systematic understanding of the role and design principles of functional interlayers is presented for improving charge separation and transport efficiency and accelerating surface catalytic reactions of photoanodes.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01066G
Non-noble-metal catalysts for electrocatalytic ammonia oxidation
Ammonia emerges as a high-energy density, carbon-free medium for the storage, transport, and utilization of green electricity.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02105G
Advances in the preparation strategies and structural regulation for CeO2-containing electrocatalysts applied to the anodes of direct alcohol fuel cells: a comprehensive review
Direct alcohol fuel cells (DAFCs) are promising clean energy systems that directly transform the chemical energy of liquid alcohols into electricity.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01696G

Field-enhanced chemical vapor deposition: new perspectives for thin film growth
Chemical vapor deposition (CVD) is a versatile technique for producing thin films and coatings of functional materials with diverse mechanical, electrochemical, electrical, tribological, and optical properties.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01081K
Metal–organic frameworks: classifications, synthesis, structure–property–performance relationship, and techno-economic analysis of redox flow batteries
MOFs classification and application in redox flow batteries.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01469G
Advances in the influencing factors and reaction mechanisms of Pd-based supported catalysts for catalytic methane combustion
This article reviews various factors that influence the catalytic performance of palladium-based supported catalysts and their reaction mechanisms in the methane combustion reaction.
J. Mater. Chem. A, 2025,13, 16382-16413
https://doi.org/10.1039/D5TA00639B
Synthetic accessibility scoring and its application to the high-throughput design of energetic molecules
Synthetic accessibility assessment of energetic molecules is a bridge from conceptual design to practical synthesis. Ten mainstream scoring models are classified into two types: based on the molecular structure and based on synthetic routes.
J. Mater. Chem. A, 2025,13, 16330-16344
https://doi.org/10.1039/D5TA01042J

A review of machine learning applications in polymer composites: advancements, challenges, and future prospects
Machine learning can facilitate the development of next-generation high-performance polymer composites with superior mechanical strength, durability, and environmental sustainability.
J. Mater. Chem. A, 2025,13, 16290-16308
https://doi.org/10.1039/D5TA00982K
Water-stable MOFs and composites: a greener and sustainable approach for enhanced reactivity towards the electrochemical nitrate reduction reaction
The electrochemical nitrate reduction reaction (eNO3− RR) is a promising strategy to mitigate nitrate pollution, which has become a critical environmental concern due to its harmful effects on water resources and ecosystems.
J. Mater. Chem. A, 2025,13, 16309-16329
https://doi.org/10.1039/D4TA09189B
Iron-based polyanionic cathodes for sustainable sodium-ion batteries
Sodium-ion batteries (SIBs) have emerged as a compelling alternative to lithium-ion batteries, driven by the abundance of raw materials and lower costs.
J. Mater. Chem. A, 2025,13, 16274-16289
https://doi.org/10.1039/D5TA01112D
Synergizing photocatalysis with Aurivillius-phase Bi4Ti3O12: current insights and emerging trends
This contribution distills the advances in Aurivillius-phase Bi4Ti3O12 based photocatalysts by highlighting structure-properties correlations, principles and key strategies used to enhance photocatalytic functionality.
J. Mater. Chem. A, 2025,13, 16345-16381
https://doi.org/10.1039/D4TA07986H

Designing covalent organic frameworks for organic catalysis: bridging reticular and molecular chemistry
This work highlights how covalent organic frameworks can be structurally designed for efficient organic catalysis by combining molecular and reticular chemistry, through backbone tuning, ligands design, metal incorporation, and nanostructure hosting.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03140K
Exploring the influence of morphological variations in M/CeO2 catalysts for enhanced CO2 hydrogenation to C1 products
M/CeO2 catalysts (M = metal and metal oxide) have garnered significant attention due to their exceptional catalytic performance in thermal, photocatalytic, and electrocatalytic applications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01560J
Investigation into the stability of monometallic metal oxide electrocatalysts for hydrogen peroxide synthesis through the oxygen reduction reaction
Catalyst stability crucially impacts the practical value of the catalyst in industrial applications. This comprehensive review aims to lay the foundation for the rational design of high-performance transition metal oxide (TMO) catalysts.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02600H
Rational regulation strategies toward perovskite precursor inks and perovskite films from the lab to commercialization
This review explores the role of perovskite inks and their impact on the quality of scalable perovskite films. Factors such as fluid dynamics, solvent selection, and additive engineering during the meniscus-assisted coating process are summarized.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01221J
Progress on polymer-based materials and composites for humidity sensors applications: Materials aspects to sensor performances
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA00028A
Recent advances in Hybrid Supercapacitors: A review of High Performance Materials and Scalable Fabrication Techniques
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02887F
Versatile roles of functionalized fullerenes in perovskite solar cells
Fullerene materials have been extensively utilized in a variety of types of perovskite solar cells, primarily employed in versatile roles, performing multiple functions to increase efficiency and stability of devices significantly.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02187A
From energy to intelligence: MXenes transforming triboelectric nanogenerators
Incorporating the MXenes as electrodes, positive and negative tribolayers in triboelectric nanogenerators enhances the TENGs' performance.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02391B
Recent advances and challenges in degradation issues of direct ammonia solid oxide fuel cells: comprehensive review
Schematic diagram of degradation factors in direct ammonia solid oxide fuel cells.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA09267H
Recent advancements in carbon capture materials research: innovative optimization of materials synthesis and engineering applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01304F
Low mechanical-hysteresis soft materials: materials, design, and applications
Low mechanical hysteresis is the key to the dynamic response and stability of soft materials. This review aims to provide an overview of current research on low mechanical-hysteresis soft materials, with a focus on materials, design and applications.
J. Mater. Chem. A, 2025,13, 15427-15452
https://doi.org/10.1039/D5TA01343G
About this collection
This collection contains recent Review-type articles published by Journal of Materials Chemistry A, the home for high impact applications, properties and synthesis of exciting new materials for energy and sustainability.
New articles will be added to this collection as soon as possible after publication.