Themed collection Journal of Materials Chemistry A Recent Review Articles

Topological quantum materials in catalysis
Let's quantum: topological quantum materials offer high electron mobility, stable surface states, and resistance to contamination, making them ideal candidates for next-generation heterogeneous catalysts.
J. Mater. Chem. A, 2025,13, 6325-6341
https://doi.org/10.1039/D4TA08325C
Unveiling the Significance of Working Electrode Substrate in Electrocatalytic Water Splitting for Hydrogen Energy
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02980E
Advances and industrialization of LiFePO4 cathodes in electric vehicles: challenges, innovations, and future directions
Evolution, research focus, industrialization and recovery techniques of LiFePO4 cathodes are reviewed, highlighting their critical role in meeting energy demands, especially in EVs.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00166H
From lab to market: the future of zinc–air batteries powered by MOF/MXene hybrids
Zinc–air batteries (ZABs) stand at the forefront of energy storage technologies. However, challenges like slow kinetics and low rechargeability persist. MOF–MXene hybrids enhance performance, enabling sustainable ZAB technology.
J. Mater. Chem. A, 2025,13, 12855-12890
https://doi.org/10.1039/D5TA01344E
Recent advancements in metal–organic frameworks (MOFs) for flexible supercapacitors aimed at wearable technology
Flexible supercapacitors have made significant progress, as they can be integral to the wearable technology field due to their unique ability to allow seamless movement for the wearer.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01159K
Sulfur element achieves rapid and stable migration of Li+ in oxide cathode materials
Higher energy density can be obtained by increasing the charging cut-off voltage of Ni-rich materials to meet the range requirements of electric vehicles.
J. Mater. Chem. A, 2025,13, 9039-9048
https://doi.org/10.1039/D4TA09238D
“The 250 mV Barrier”: A Thermodynamic Ceiling That Every OER/ORR Researcher Must Know!
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA00009B

Capacity-weighted figures-of-merit for battery transport metrics
Fast-charging materials are necessary for a battery-centric future. Ionic and electronic transport crucially determine performance where their capacity-weighted figures-of-merit account for performance across all states-of-charge.
J. Mater. Chem. A, 2025,13, 6314-6324
https://doi.org/10.1039/D4TA06041E
Recent advances in characterization of rechargeable battery materials via scanning probe microscopy
Scanning probe microscopy can be used to obtain topographical, mechanical, electrical, and electrochemical information on a wide range of materials in a variety of environments, including in situ and operando studies for rechargeable battery systems.
J. Mater. Chem. A, 2025,13, 5561-5581
https://doi.org/10.1039/D4TA05975A
Sorbent-based atmospheric water harvesting: engineering challenges from the process to molecular scale
Atmospheric water harvesting is an emerging technique that can potentially increase water access to water-constrained communities.
J. Mater. Chem. A, 2025,13, 4838-4850
https://doi.org/10.1039/D4TA06883A
Exploring spinel oxides from bimetallic to high-entropy with a focus on the structure and performance in the oxygen evolution reaction
A schematic representation of the transformation from bimetallic to high entropy spinel oxides for the oxygen evolution reaction.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01363A
Non-noble-metal catalysts for electrocatalytic ammonia oxidation
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02105G
Recent advances in Ni-based catalysts for hybrid CO2 electrolysis
The utilization of nickel-based catalysts in hybrid CO2 electrolysis systems enhances the efficiency of CO2 reduction by coupling low-energy alternative oxidation reactions, thereby offering an innovative route towards a sustainable carbon economy.
J. Mater. Chem. A, 2025,13, 14491-14509
https://doi.org/10.1039/D5TA01358E

ZnMn2O4 applications in batteries and supercapacitors: a comprehensive review
This review critically examines the relationship between ZMO synthesis techniques, the resulting structural and morphological features, and the subsequent impact on electrochemical performance in various energy storage systems (supercapacitors and batteries).
J. Mater. Chem. A, 2025,13, 14540-14579
https://doi.org/10.1039/D5TA00815H
Impact of catalyst engineering on the durability performance of self-supported catalysts in anion exchange membrane water electrolyzers: recent advances and perspectives
Optimizing these catalyst engineering strategies leads to substantial enhancements in durability performance, resulting in widespread implementation.
J. Mater. Chem. A, 2025,13, 14510-14539
https://doi.org/10.1039/D5TA00208G
Toward enhanced pyro-catalysis performance: mechanisms, strategies and challenges
Overview of the applications and performance improvement strategies of pyro-catalysis.
J. Mater. Chem. A, 2025,13, 14465-14490
https://doi.org/10.1039/D5TA00772K
Interfacial regulation of photoanodes for photoelectrochemical water splitting: the role of Interlayer and overlayer
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01066G

Probing solid-state battery aging: evaluating calendar vs. cycle aging protocols via time-resolved electrochemical impedance spectroscopy
The degradation behavior of In/InLi|Li6PS5Cl|NCM83:Li6PS5Cl battery cell was investigated using two different accelerated aging protocols to evaluate their ability to fast screen solid-state batteries.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01083G
Exploring the Influence of Morphological Variations in M/CeO2 Catalysts for Enhanced CO2 Hydrogenation to C1 Products
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01560J
Versatile Roles of Functionalized Fullerenes in Perovskite Solar Cells
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02187A
Electrochemical H/D isotope separation
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02337H
Advances in the Preparation Strategies and Structural Regulation for CeO2-containing Electrocatalysts Applied to the Anodes of Direct Alcohol Fuel Cells: A Comprehensive Review
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01696G
Investigation into the Stability of Monometallic Metal Oxides Electrocatalysts for Hydrogen Peroxide Synthesis Through Oxygen Reduction Reaction
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02600H
Recent advances in Cu-based intermetallics: structures, syntheses, and electrocatalytic applications
This review focuses on the latest developments in Cu-based intermetallics, covering their structures, synthesis methods, and electrocatalytic applications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02448J

Field-enhanced Chemical Vapor Deposition: New Perspectives for Thin Film Growth
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01081K
Recent progress in Ru electrocatalyst design for acidic oxygen evolution reaction
This review surveys recent advances in Ru-based electrocatalysts for the acidic OER, focusing on strategies to enhance activity and stability, mitigate Ru dissolution and performance degradation, and inform the design of robust PEMWE.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01849H
Rational regulation strategies toward perovskite precursor inks and perovskite films from the lab to commercialization
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01221J
Recent Progress of Metal-Organic Framework-based Materials for Electrocatalytic Carbon Dioxide Reduction
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02285A
From Energy to Intelligence: MXenes Transforming Triboelectric Nanogenerators
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02391B
Machine learning-accelerated exploration on element doping-triggering material performance improvement for energy conversion and storage applications
The prediction performances of machine learning in the field of element-doped materials for energy conversion and storage applications are summarized.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00922G
Rational design and construction of aqueous multivalent metal ion battery systems
Energy storage chemistry of the cathode and anode of aqueous multivalent metal ion batteries and present their recent progress are reviewed and discussed. Progress in theoretical simulations of their energy storage modes is then reviewed.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02196K
Recent advances in zwitterionic hydrogels: structure, applications and challenges
The current structure and diverse applications of zwitterionic hydrogels are summarized, and the properties of hydrogels can be effectively improved through structural optimization.
J. Mater. Chem. A, 2025,13, 13693-13705
https://doi.org/10.1039/D5TA01111F
Research progress of atomically dispersed iron, nitrogen co-coordinated carbon catalysts for oxygen reduction: a mini-review
The design principles, synthesis methods and characterization techniques of Fe–N–C for the ORR are systematically summarized.
J. Mater. Chem. A, 2025,13, 13675-13692
https://doi.org/10.1039/D5TA01480H
Recent progress in atomic-level manufacturing of two-dimensional transition metal dichalcogenides beyond exfoliation and restacking
Two-dimensional transition metal dichalcogenides (2DTMDCs) are promising in quantum computing, flexible electronics, spintronics, sustainable energy systems, and advanced healthcare.
J. Mater. Chem. A, 2025,13, 13585-13601
https://doi.org/10.1039/D5TA01124H
Meniscus-guided coating for organic photovoltaic cells
This review specifically focuses on the fluid flow dynamics and drying kinetics involved in the fabrication of organic photovoltaic cells via the meniscus-guided coating process.
J. Mater. Chem. A, 2025,13, 13657-13674
https://doi.org/10.1039/D5TA01491C
Recent progress of selectivity regulation and reaction mechanism of atomically dispersed metal catalysts for oxygen reduction electrocatalysis
This review summarizes the recent progress of atomically dispersed metal catalysts for oxygen reduction electrocatalysis, including advanced theories and descriptors, active site structure, and advanced characterization techniques.
J. Mater. Chem. A, 2025,13, 13602-13631
https://doi.org/10.1039/D5TA01183C
Advances in the application of ionic liquids in PEO-based lithium-ion solid-state electrolytes: from the perspective of fillers
The latest developments in PEO/ILs for lithium-ion solid-state polymer electrolytes are reviewed, covering the roles and interaction mechanisms of ILs and PEO and representative applications from the perspective of different fillers.
J. Mater. Chem. A, 2025,13, 13632-13656
https://doi.org/10.1039/D4TA09243K
ZnIn2S4-based heterostructure photocatalysts for solar energy conversion: A comprehensive review
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02501J
Molecular sieve confined catalysts for the catalytic combustion of VOCs: preparation, application and future development
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01092F
Cathode Materials for Proton Batteries: Recent Advances and Perspectives
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02851E
Advances in the influencing factors and reaction mechanisms of Pd-based supported catalysts for catalytic methane combustion
This article reviews various factors that influence the catalytic performance of palladium-based supported catalysts and their reaction mechanisms in the methane combustion reaction.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00639B
Recent advances and challenges in degradation issues on direct ammonia solid oxide fuel cells: Comprehensive Review
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D4TA09267H
Synergizing photocatalysis with Aurivillius-phase Bi4Ti3O12: current insights and emerging trends
This contribution distills the advances in Aurivillius-phase Bi4Ti3O12 based photocatalysts by highlighting structure-properties correlations, principles and key strategies used to enhance photocatalytic functionality.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA07986H
Solvate ionic liquids: past, present and future
Solvate ionic liquids (SILs) are modular and tuneable, enabling their utilisation in diverse applications spanning energy storage, electrodeposition, and advanced synthesis.
J. Mater. Chem. A, 2025,13, 12746-12784
https://doi.org/10.1039/D5TA01406A
Joule heating: a versatile and sustainable heating strategy with diverse applications in materials science and waste management
The principles, equipment, and recent advancements of Joule heating in materials synthesis and waste management were systematically reviewed. Applications were highlighted while challenges and future research directions were addressed.
J. Mater. Chem. A, 2025,13, 12828-12854
https://doi.org/10.1039/D4TA09092F
High-entropy compounds for photo(electro)catalysis: diverse materials and applications
High-entropy compounds harness multi-element synergy to deliver exceptional photo(electro)catalytic activity, stability and tunable functionality, while addressing mechanistic challenges and design strategies for energy/environmental applications.
J. Mater. Chem. A, 2025,13, 12808-12827
https://doi.org/10.1039/D4TA09220A

A review on photocatalytic methane conversion systems: from fundamental mechanisms to the emerging role of ferroelectric materials
This review provides a comprehensive tutorial about the promising potential of ferroelectric materials as unconventional photocatalysts for methane conversion applications.
J. Mater. Chem. A, 2025,13, 12712-12745
https://doi.org/10.1039/D4TA08554J

Benzodithiophene-based polymer donors for organic photovoltaics
This review summarizes the molecular design strategy for benzodithiophene-based donor–acceptor polymers and presents recent examples of their applications in high-efficiency solar cells.
J. Mater. Chem. A, 2025,13, 12785-12807
https://doi.org/10.1039/D4TA07020H
Metal-Organic Frameworks: Classifications, Synthesis, Structure-Property-Performance Relationship, and Techno-Economic Analysis of Redox Flow Batteries
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA01469G
Synthetic accessibility scoring and its application to the high-throughput design of energetic molecules
Synthetic accessibility assessment of energetic molecules is a bridge from conceptual design to practical synthesis. Ten mainstream scoring models are classified into two types: based on the molecular structure and based on synthetic routes.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01042J
Iron-based polyanionic cathodes for sustainable sodium-ion batteries
Sodium-ion batteries (SIBs) have emerged as a compelling alternative to lithium-ion batteries, driven by the abundance of raw materials and lower costs.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01112D
Recent Advances and Future Directions of Photocatalytic CdIn2S4-Based Photocatalysts: Properties, Synthesis, and Modifications for Energy and Environmental Applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02047F

A review of machine learning applications in polymer composites: advancements, challenges, and future prospects
Machine learning can facilitate the development of next-generation high-performance polymer composites with superior mechanical strength, durability, and environmental sustainability.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00982K
Water-stable MOFs and composites: a greener and sustainable approach for enhanced reactivity towards the electrochemical nitrate reduction reaction
The electrochemical nitrate reduction reaction (eNO3− RR) is a promising strategy to mitigate nitrate pollution, which has become a critical environmental concern due to its harmful effects on water resources and ecosystems.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA09189B
Advancements towards optimization of metal–organic framework-based polymer electrolyte membranes for aqueous redox flow batteries
Functionalizing the membrane framework with the introduction of MOFs, robust hybrid membranes separator devised in ARFBs that outperformed the pristine membrane separators in terms of electro-chemical efficiencies and capacity retention rates.
J. Mater. Chem. A, 2025,13, 11952-11988
https://doi.org/10.1039/D4TA08720H

UiO-66 (Zr) metal–organic framework for photocatalytic CO2 reduction: functional design strategies for sustainable carbon utilization
UiO-66 (Zr), well-acknowledged as an outstanding MOF nanomaterial, has emerged as a promising candidate for photocatalytic CO2 reduction—a green and sustainable process that utilizes renewable solar energy to convert CO2 into valuable products.
J. Mater. Chem. A, 2025,13, 11989-12008
https://doi.org/10.1039/D5TA00388A
Recent advances in surface modification for enhanced electrocatalytic CO2 reduction
We reviewed the recent advances in surface modification strategies of catalysts for improving CO2RR performance.
J. Mater. Chem. A, 2025,13, 12039-12056
https://doi.org/10.1039/D5TA00927H

Optimization strategies for flexible aqueous rechargeable sodium-ion batteries (ARSIBs)
This review aims to discuss and summarize the optimization strategies for the performance of flexible ARSIBs, their stability under extreme conditions, and the multifunctional applications in wearable integrated electronic systems.
J. Mater. Chem. A, 2025,13, 12009-12038
https://doi.org/10.1039/D5TA00276A
A review on 2D materials for surface acoustic wave gas sensors at room temperature
In surface acoustic wave (SAW)-based gas sensing applications, the sensitive material coated on the SAW sensor is critical for selectivity, limit of detection, and sensitivity, as it directly affects changes in sensing signals.
J. Mater. Chem. A, 2025,13, 11921-11951
https://doi.org/10.1039/D4TA07342H
Recent progress in minimizing the loss channel via triplet excitons in nonfullerene-based organic solar cells
Recent advances in minimizing the loss channel via triplet excitons in nonfullerene organic solar cells are summarized. Potential directions that might address the existing and emerging challenges are proposed to further boost the PCE.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00956A
Unlocking sunlight driven photocatalysis: synthesis, diversity, and applications of COF-based S-scheme heterojunctions
COFs with high stability and tunability face issues of self-stacking and restricted conductivity, whereas their S-scheme heterojunctions address these limitations. This review explores their synthesis, mechanism, applications, etc.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01232E
Low mechanical-hysteresis soft materials: materials, design, and applications
Low mechanical hysteresis is the key to the dynamic response and stability of soft materials. This review aims to provide an overview of current research on low mechanical-hysteresis soft materials, with a focus on materials, design and applications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA01343G
Recent progress in functional applications of polymer foams
This review summarizes the material matrix, preparation process and its latest functionalized applications of polymer foams with porous structures.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA09226K
Challenges and advances in redox flow batteries utilizing sustainable and cost-effective non-vanadium active materials
The key parameters for grid-scale energy storage systems (ESSs) are safety, longevity, and cost-effectiveness.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00113G

Strategically designed catalysts for ammonia synthesis under mild conditions: recent advances and challenges
Ammonia is envisioned to play a pivotal role in the changing energy landscape, with immense potential to promote carbon-neutrality and circularity in the energy economy.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA08232J
Emerging paired diatomic sites toward synergistic NH3 synthesis
We summarize the state-of-the-art dual atom catalysts (DACs) for the synergistic catalytic conversion of N2/NOx to NH3. Strategies for modifying DACs to enhance catalytic activity are also discussed.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00369E
Prelithiation of lithium-ion batteries towards commercialization: concepts, challenges, and application prospects
This review systematically summarizes the recent progress in prelithiation technology and discusses their commercial feasibility.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA00070J
Empowering high-performance triboelectric nanogenerators: advanced materials strategies
This review systematically discusses performance limiting factors and materials-related strategies for high-performance AC-TENGs and DC-TENGs.
J. Mater. Chem. A, 2025,13, 11264-11285
https://doi.org/10.1039/D4TA08819K
Application of MOF-808 and its derivatives in carbon capture and CO2 catalytic conversion
The present document delineates the optimization strategy of MOF-808 and its intrinsic mechanism of CO2 capture, separation and catalytic process.
J. Mater. Chem. A, 2025,13, 11185-11209
https://doi.org/10.1039/D5TA00011D

Challenges and mitigation strategies for general failure and degradation in polymer electrolyte membrane-based fuel cells and electrolysers
This review investigates the challenges and recommends various mitigation strategies for general cell failure and degradation mechanisms in polymer electrolyte membrane-based fuel cells and electrolysers.
J. Mater. Chem. A, 2025,13, 11236-11263
https://doi.org/10.1039/D4TA08823A
About this collection
This collection contains recent Review-type articles published by Journal of Materials Chemistry A, the home for high impact applications, properties and synthesis of exciting new materials for energy and sustainability.
New articles will be added to this collection as soon as possible after publication.