Themed collection Recent Review Articles


Is the single-ion conductor cubic Li7La3Zr2O12 a binary ionic electrolyte?
Garnet-type cubic Li7La3Zr2O12 (c-LLZO) is a single-ion conductor, but the electrochemically generated charged vacancies make it a binary ionic electrolyte, which explains the current- and thickness-dependent lithium dendrite initiation dynamics.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00069F
Rational design of uniform SiO2-based afterglow microparticles for photonic crystals
This article highlights recent advances in the rational design of uniform afterglow SiO2 microparticles, facilitated by pseudomorphic transformation-assisted doping, identifies key challenges, and explores opportunities in this field.
Mater. Horiz., 2025,12, 1381-1387
https://doi.org/10.1039/D4MH01541J

A comprehensive analysis from the basics to the application of V-cathodes in Zn–V static and flow batteries
This mini review summarizes the recent progress of Zn–V static battery and Zn–V redox flow battery. Mechanisms, classification and structures, problems and modification strategies are discussed for future developments of these batteries.
Nanoscale Horiz., 2025, Advance Article
https://doi.org/10.1039/D5NH00125K

Bioactive metal sulfide nanomaterials as photo-enhanced chemodynamic nanoreactors for tumor therapy
An overview of MeSNs for photo-enhanced chemodynamic theranostics of tumors is provided in this review, offering insights into their potential for next-generation cancer treatments.
Nanoscale Horiz., 2025, Advance Article
https://doi.org/10.1039/D5NH00122F

Becoming a Foodie in Virtual Environments: Simulating and Enhancing the Eating Experience with Wearable Electronics for the Next-Generation VR/AR
Mater. Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5MH00488H

Machine learning in biosignal analysis from wearable devices
This review outlines key machine learning algorithms for biosignal analysis and offers guidance on model selection. Applications in neural, cardiovascular, and biochemical signal monitoring for health tracking and disease prediction are discussed.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00451A
Research on light-responsive luminescence properties of carbon dots and their applications
This review classifies light-responsive carbon dots into photoluminescent and photochromic categories, examines their synthesis strategies and optical mechanisms, and discusses the applications of these materials in various fields.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00676G

Harnessing mesoporous g-C3N4-based photocatalytic materials for sustainable fuel production via solar energy conversion: a review
This TOC signifies the mp-g-CN photocatalyst enriched with a finely tuned functional porous surface and enhanced optoelectronic features, which suitably enables solar fuel production by using renewable stuffs to maintain the circular energy cycle.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00294J
Bioinspired rational design of nanozymes
This review presents a comprehensive overview of bioinspired rational design of nanozymes, guided by the catalytic mechanisms and structural characteristics of natural enzymes, and enhanced by emerging trend of machine learning assisted strategies.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00746A
Polymorphic phases in 2D In2Se3: fundamental properties, phase transition modulation methodologies and advanced applications
This review explores the latest progress of various polymorphic phases of 2D In2Se3, emphasizing their unique properties, characterization methods, phase modulation strategies, and practical applications.
Nanoscale Horiz., 2025,10, 1054-1076
https://doi.org/10.1039/D4NH00650J
Advancements in MOF-based resistive gas sensors: synthesis methods and applications for toxic gas detection
Gas sensors are essential tools for safeguarding public health and safety because they allow the detection of hazardous gases.
Nanoscale Horiz., 2025,10, 1025-1053
https://doi.org/10.1039/D4NH00662C

The emergence of metal-free molecular perovskites: challenges and opportunities
This review discusses the challenges associated with the emerging all-organic perovskite materials while outlining opportunities for their further development and applications in the future.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01877J
Self-powered Wearable Sensing Devices for Digital Health
Mater. Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5MH00443H
Recent advances in garnet-based electrolytes for solid-state lithium metal batteries: interfacial challenges and engineering strategies
In this review, we systematically analyze the interfacial challenges between garnet-type electrolytes/composite electrolytes and electrodes, mainly focusing on the interfacial failure mechanism of garnet-type based SSLMBs.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00583C
Machine Learning-Assisted X-ray Absorption Analysis of Bimetallic Catalysts
Mater. Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5MH00387C
Shape-morphing bioelectronic devices
Working principles, representative deformation modes, manufacturing methodologies, diverse applications, as well as challenges and opportunities of shape-morphing bioelectronic devices.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00453E
Control of molecular aggregation structures towards flexible organic photovoltaics
This review evaluates molecular aggregation structures across scales, elucidates mechanisms for enhancing tensile properties and summarizes methods to regulate structures, which provides critical insights for designing efficient and flexible OPVs.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00160A

Exploring the Intricacies of Protein-Nanoparticle Interaction and its Implications in Chronic Diseases: A Comprehensive Review
Nanoscale Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5NH00076A
Innovative biosensing smart masks: unveiling the future of respiratory monitoring
An innovative biosensing smart mask for the future of respiratory monitoring.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00279F
Enhanced biochemical sensing using metallic nanoclusters integrated with metal–organic frameworks (NCs@MOFs): a comprehensive review
Significant advancements have been made in biochemical sensing, particularly in the design, development, and utilization of metallic nanoclusters and metal–organic frameworks as separate functional materials.
Mater. Horiz., 2025,12, 3301-3319
https://doi.org/10.1039/D4MH01932F
Advances in small droplets manipulation on bio-inspired slippery surfaces: chances and challenges
This paper reviews droplet manipulation on bioinspired slippery surfaces. It also classifies methods into active and passive based on external stimuli like heat and light and emphasizes their significance for applications in multiple fields.
Mater. Horiz., 2025,12, 3267-3285
https://doi.org/10.1039/D4MH01666A
Recent advances in metal single-atom catalysts for ammonia electrosynthesis
This review provides insight into the development of advanced metal single-atom catalysts for ammonia electrosynthesis.
Mater. Horiz., 2025,12, 3286-3300
https://doi.org/10.1039/D5MH00042D

Wide-temperature solid polymer electrolytes: Li+ coordination structure, ionic transport and interphases
Solid polymer electrolytes have been considered one of the most promising candidates for solid-state batteries, while the Li coordination structure, interfaces and interphases and related cycling performance still remain challenge.
Mater. Horiz., 2025,12, 3201-3233
https://doi.org/10.1039/D4MH01869A
Recent advances in lead-free carbon supported perovskites based on Z-scheme and S-scheme heterojunctions for photocatalytic energy conversion
Photocatalysis has emerged as a crucial technology for utilizing solar energy to combat global warming and energy shortages.
Mater. Horiz., 2025,12, 3234-3266
https://doi.org/10.1039/D4MH01516A
Self-assembled monolayers for tin perovskite solar cells: challenges and opportunities
This review explores the potential of self-assembled monolayers (SAMs) as a solution to mitigate the voltage deficits in tin perovskite solar cells (TPSCs).
Mater. Horiz., 2025,12, 3188-3200
https://doi.org/10.1039/D4MH01603C
Bacterial Cellulose-Based Yarns Functional Materials: From Design to Applications
Mater. Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5MH00456J
Recent progress in the electrocatalytic applications of thiolate-protected metal nanoclusters
The latest developments in thiolate-protected metal nanoclusters in important electrocatalytic applications, such as hydrogen evolution, oxygen reduction and CO2 reduction reactions, are briefly reviewed in this work.
Nanoscale Horiz., 2025, Advance Article
https://doi.org/10.1039/D5NH00153F
Recent progress of gel-based materials in energy storage and conversion
Mater. Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5MH00368G
Recent advances in nanomaterial-based adsorbents for removal of pharmaceutical pollutants from wastewater
Adsorption is widely recognized as an effective and practical approach for mitigating the environmental hazards associated with pharmaceutical waste, owing to its operational simplicity, economic feasibility, and consistent performance.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00627A

Innovative engineering strategies and mechanistic insights for enhanced carbon-based electrocatalysts in sustainable H2O2 production
This review provides a comprehensive overview of the latest key advancements in materials engineering strategies for carbon-based electrocatalysts for H2O2 production.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00221D
Wearable Biosensors for Health Monitoring: Advances in Graphene-Based Technologies
Nanoscale Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5NH00141B
Thermogalvanic hydrogels for low-grade heat harvesting and health monitoring
With the advances and ongoing research efforts discussed in this review, a continuous breakthrough in high-performance thermogalvanic hydrogels for efficient low-grade heat harvesting and wearable electronics for health monitoring is foreseeable.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01931H

Recent advances in atomic layer deposition of superconducting thin films: a review
ALD of superconducting films for various high performance applications.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00323G
Advances in chiral luminescent liquid crystals (CLLCs): from molecular design to applications
Research on circularly polarized luminescent (CPL) materials has evolved into a hot research topic because of their potential application prospects in the optoelectronics and chiroptical fields.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01928H
Photoacoustic contrast agents: a review focusing on image-guided therapy
Photoacoustic (PA) imaging is a burgeoning imaging modality that has a broad range of applications in the early diagnosis of cancer, detection of various diseases, and relevant scientific research.
Nanoscale Horiz., 2025, Advance Article
https://doi.org/10.1039/D4NH00395K
Research advances in the diagnosis of infectious disease by aptasensor technology
Various aptasensors offer rapid, accurate and reliable detection tools for diagnosis of infectious disease pathogens.
Nanoscale Horiz., 2025, Advance Article
https://doi.org/10.1039/D5NH00098J
Radio frequency switching devices based on two-dimensional materials for high-speed communication applications
This review summarizes recent progress in two-dimensional material-based RF switches, focusing on performance optimization, fabrication methods, and challenges, and potential applications in future high-frequency communication systems.
Nanoscale Horiz., 2025, Advance Article
https://doi.org/10.1039/D5NH00105F

Poly(3-hexylthiophene) as a versatile semiconducting polymer for cutting-edge bioelectronics
Photo- and electro-active poly(3-hexylthiophene) (P3HT)-based materials serve as efficient and highly biocompatible phototransducers for cutting-edge bioelectronic applications.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00096C

Empowering artificial muscles with intelligence: recent advancements in materials, designs, and manufacturing
This review emphasizes memory-based intelligence, enabling artificial muscles to execute a range of pre-programmed movements and refresh stored actuation states in response to changing conditions, as well as sensory-based intelligence.
Mater. Horiz., 2025,12, 2764-2788
https://doi.org/10.1039/D5MH00236B
Multifunctional solar-driven interfacial evaporation system for simultaneous clean water production and high-value-added ion extraction
This review highlights the potential of solar-driven interfacial evaporation (SIE) technology to simultaneously produce clean water and extract valuable ions from water, addressing both water scarcity and resource recovery challenges.
Mater. Horiz., 2025,12, 2878-2898
https://doi.org/10.1039/D4MH01857E

From 3D to 4D printing of lignin towards green materials and sustainable manufacturing
This review summarized lignin/lignocellulose materials for various 3D printing techniques and their related applications, where lignin is used in an isolated state, as part of lignocellulose biomass or chemically modified to better bind with a matrix.
Mater. Horiz., 2025,12, 2789-2819
https://doi.org/10.1039/D4MH01680G
Applications, performance enhancement strategies and prospects of NixPy in electrocatalysis
The applications and performance enhancement strategies of NixPy with different crystal phases in the field of electrocatalysis are discussed.
Mater. Horiz., 2025,12, 2840-2877
https://doi.org/10.1039/D4MH01483A
Towards scalable memristive hardware for spiking neural networks
This review provides a systematic review and perspective of the challenges and opportunities in scaling memristive hardware for spiking neural networks (SNNs), focusing on device innovations, system integration, and algorithm-hardware co-design.
Mater. Horiz., 2025,12, 2820-2839
https://doi.org/10.1039/D4MH01676A
Recent development review of Ti3C2Tx MXene-based microsupercapacitors: a multi-dimensional analysis spanning from underlying mechanisms to integrated applications
This review presents the latest advancements in the mechanisms and fabrication techniques of Ti3C2Tx-based MSCs, emphasizes their applications across various components of MSCs, and provides a summary of integrated examples of MSC-powered systems.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00423C
Silicon anode modification strategies in solid-state lithium-ion batteries
This research proposes performance-boosting strategies for silicon anodes in solid-state batteries by leveraging nanostructuring, doping and compositing. Moreover, it surveys the field's perspective and charts future research directions.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00434A
Covalent organic framework membranes for lithium extraction: facilitated ion transport strategies to enhance selectivity
Mechanistic design of COF membranes enables high-selectivity ion transport for lithium extraction via diffusion and electrodialysis.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00457H
Wet Chemically Produced Nanomaterials for Soft Wearable Biosensors
Nanoscale Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5NH00048C
Recent advances in photocatalytic H2O2 production: modification strategies of 2D materials and in situ application of H2O2
This review summarizes recent advances in the modification strategies of 2D materials for photocatalytic H2O2 production and its in situ applications. Additionally, the existing challenges in this field and potential solutions are discussed.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00295H
Hydrazine-assisted water electrolysis system: performance enhancement and application expansion
Hydrazine-assisted water electrolysis exhibits various advantages compared with conventional water electrolysis and other hybrid water electrolysis systems in terms of reaction, electrocatalyst design and application expansion.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00118H
Side-chain engineering of conjugated molecules for n-type organic thermoelectrics
The performance of n-type thermoelectrics has increased significantly over the years, with side chain engineering playing a pivotal role in advancing this field.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00067J
Leveraging bound states in the continuum for advanced ultra-sensitive sensing technologies
Bound states in the continuum (BICs) are localized waves within radiating backgrounds, offering ultra-high quality factors. BICs have been applied in developing ultra-sensitive sensors. This review summarizes recent advances in this emerging field.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00413F
Exploring the wonders of polysaccharides in porous materials
Porous materials are a class of materials with abundant micro-nano pore structures, low density, light weight, and large specific surface area, and they have been widely used in various fields.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01670J
Advances in anion-intercalated layered double hydroxides for supercapacitors: study of chemical modifications and classifications
The electrochemical performance of LDH-based hybrid supercapacitors (SCs) with improved energy density (ED), enhanced stability, high porosity, and a large accessible surface area has attracted attention as a promising energy storage device.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01860E
Development and challenges of polarization-sensitive photodetectors based on 2D materials
Polarization-sensitive photodetectors based on two-dimensional (2D) materials have garnered significant research attention owing to their distinctive architectures and exceptional photophysical properties.
Nanoscale Horiz., 2025,10, 847-872
https://doi.org/10.1039/D4NH00624K

Next-generation CO2 electroreduction: the role of atomically precise nanoclusters and emerging catalytic strategies
Nanoscale Horiz., 2025, Accepted Manuscript
https://doi.org/10.1039/D5NH00138B

Polyelectrolyte complex-based materials for separations: progress, challenges and opportunities
Polyelectrolyte complex (PEC) based materials could provide a sustainable alternative to conventional materials, especially for separation applications.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01840K
Engineering magnetism in hybrid organic–inorganic metal halide perovskites
State-of-the-art review of magnetic hybrid organic–inorganic transition metal halide perovskites, focusing on chemical design, the origin and tunability of magnetism, and potential applications in magneto-optics, sensors, and spin filters.
Mater. Horiz., 2025,12, 2414-2435
https://doi.org/10.1039/D4MH01762E
Application of advanced quantum dots in perovskite solar cells: synthesis, characterization, mechanism, and performance enhancement
This review focuses on the synthesis of quantum dots, film deposition techniques, and their application across various functional layers in perovskite solar cells, elucidating the mechanisms by which quantum dots enhance photovoltaic performance.
Mater. Horiz., 2025,12, 2467-2502
https://doi.org/10.1039/D4MH01478B
Advanced wood–inorganic composites: preparation, properties and perspectives
A review on the modification methods, types of modifiers, and performance improvement of wood–inorganic composites.
Mater. Horiz., 2025,12, 2503-2523
https://doi.org/10.1039/D4MH01475H
Porous polymers: structure, fabrication and application
This review systematically examines the structural features, fabrication techniques, and applications of porous polymers, as well as their interrelationships, to serve as a guide for researchers.
Mater. Horiz., 2025,12, 2436-2466
https://doi.org/10.1039/D4MH01618A
Porphyrinic metal–organic frameworks as separation membranes: from synthesis to advanced applications
TCPP MOFs, characterized by diverse nanostructured morphologies, can be integrated into various membranes, performing advanced separation applications.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00266D

Photo-crosslinkable organic materials for flexible and stretchable electronics
Overview of photo-crosslinkable organic components—insulators, semiconductors, and conductors—and their integration into flexible and stretchable electronics such as physical sensors, OFETs, and OSCs via photo-crosslinking method.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01757A

Emerging fiber-based neural interfaces with conductive composites
This review presents conductive composites, fabrication processes, integration strategies, and therapeutic applications in the nervous system of fiber-based neural interfaces.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01854K

Magnetic Kagome materials: bridging fundamental properties and topological quantum applications
This review focuses on Kagome magnets, highlighting their lattice, rich electronic states and emergent quantum effects. It explores the synergy of topology, magnetism and correlations, and outlines future research directions in solid-state chemistry.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00120J

Dual organic structure-directing agents in zeolite synthesis: cooperation or competition?
Cooperation of OSDAs could lead to a certain topology, reduce the synthesis cost, fasten the synthesis, or alter the Al distribution/siting, while the competition of OSDAs may cause phase selectivity issues or intergrowth of different structures.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D5MH00235D
From synthesis to properties: expanding the horizons of machine learning in nanomaterials research
An overview of the application of machine learning in single nanomaterials and nanocomposites is provided. We highlight a closed-loop relationship between the synthesis and properties by machine learning models with optimization and prediction tasks.
Mater. Horiz., 2025, Advance Article
https://doi.org/10.1039/D4MH01909A
Neuromorphic devices for electronic skin applications
This paper illustrates future research directions for neuromorphic e-skin devices and their applications.
Mater. Horiz., 2025,12, 2045-2088
https://doi.org/10.1039/D4MH01848F
Unearthing the emerging properties at buried oxide heterointerfaces: the γ-Al2O3/SrTiO3 heterostructure
Epitaxially combining oxide layers can create new functionalities surpassing those of separate parent materials. This review highlights the unique structural, electronic, and magnetic properties of γ-Al2O3/SrTiO3, revealing the underlying mechanisms.
Mater. Horiz., 2025,12, 2119-2160
https://doi.org/10.1039/D4MH01192A

Layered double hydroxide modified bismuth vanadate as an efficient photoanode for enhancing photoelectrochemical water splitting
This review highlights the functions of layered double hydroxide-modified bismuth vanadate photoanodes in solar water splitting. Future outlook on the photoanode is also summarized.
Mater. Horiz., 2025,12, 2089-2118
https://doi.org/10.1039/D4MH01533A
Sensor-combined organ-on-a-chip for pharmaceutical and medical sciences: from design and materials to typical biomedical applications
Organ-on-a-chip (OoC) is a breakthrough technology in biomedicine.
Mater. Horiz., 2025,12, 2161-2178
https://doi.org/10.1039/D4MH01174K
About this collection
In addition to first reports of new concepts, Materials Horizons and Nanoscale Horizons publish topical review and minireview articles.
Reviews will be added to this webpage as soon as possible after publication.