Themed collection Batteries showcase
Battery electrode slurry rheology and its impact on manufacturing
Slurry rheology is a critical metrology tool for understanding and optimising the manufacture of battery electrodes.
Energy Adv., 2025, Advance Article
https://doi.org/10.1039/D4YA00380B
Unlocking high-efficiency energy storage and conversion with biocompatible electrodes: the key role of interfacial interaction assembly and structural design
This perspective paper covers textile- and hydrogel-based biocompatible electrodes, and their applications for supercapacitors, biofuel cells, and actuators, focusing on the importance of interfacial interactions between electrode components.
Energy Adv., 2024,3, 2152-2174
https://doi.org/10.1039/D4YA00387J
Improving upon rechargeable battery technologies: on the role of high-entropy effects
An overview of high-entropy strategies for batteries is provided, emphasizing their unique structural/compositional attributes and positive effects on stability and performance, alongside a discussion of key challenges and future research directions.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D4EE03708A
Recent advances in p-type polymeric electrode materials towards high-voltage 4.0 V-class organic lithium-ion batteries
The p-type polymer electrodes have received an exponential growth of interest for organic lithium-ion batteries. This review summarizes their recent developments focusing on structure, performance, advantages, and challenges.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06028H
High-entropy materials for aqueous zinc metal batteries
This review explores the potential and effective application paths of HEMs in AZIBs, aiming to break the constraints in AZIBs and pave the way toward the development of high-performance AZIBs.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D4EE04442H
Recent advances in in situ/operando characterization of lithium–sulfur batteries
We review the recent literature on spectroscopic/electrochemical operando methods as they are increasingly being applied to understand lithium–sulfur batteries.
Energy Adv., 2024,3, 2479-2502
https://doi.org/10.1039/D4YA00416G
Green and sustainable metal–air batteries for powering flexible wearable electronics: current status and future prospects
Naturally occurring materials can serve as green alternatives to synthesize and fabricate green wearable metal–air batteries.
Sustainable Energy Fuels, 2024,8, 4687-4708
https://doi.org/10.1039/D4SE00555D
Graphene-based 2D materials for rechargeable batteries and hydrogen production and storage: a critical review
Graphene-based 2D materials for batteries and hydrogen production and storage applications.
Sustainable Energy Fuels, 2024,8, 4039-4070
https://doi.org/10.1039/D4SE00497C
Advanced bifunctional catalyst design for rechargeable zinc–air batteries
This review provides an overview of advanced bifunctional catalysts that promotes both oxygen reduction reaction and oxygen evolution reaction in rechargeable zinc–air batteries, and analyses in detail their principles and future development.
EES. Catal., 2024,2, 696-726
https://doi.org/10.1039/D4EY00014E
Toward the next generation of sustainable aluminum-ion batteries: a review
This review explores the current research progress on aluminum-ion batteries, focusing on cathode materials according to their mechanisms, as well as anodes and electrolytes, while discussing current challenges and modification strategies.
Green Chem., 2025,27, 352-378
https://doi.org/10.1039/D4GC04505J
Recent progresses in the synthesis and strategic designs of sustainable carbon-based fibrous electrodes for flexible batteries
A detailed review on carbon fiber (CF)-based flexible electrodes for application in rechargeable batteries is reported. Various preparation methods for flexible electrodes based on CFs are reviewed, along with their performance evaluations.
RSC Sustain., 2025, Advance Article
https://doi.org/10.1039/D4SU00394B
Biomass-derived metal-free heteroatom doped nanostructured carbon electrocatalysts for high-performance rechargeable lithium–air batteries
Renewable energy sources are crucial for addressing the energy crisis and global warming, but their intermittent nature necessitates storage.
Green Chem., 2024,26, 11427-11443
https://doi.org/10.1039/D4GC02551B
Yeast bio-batteries
We present a fully rechargeable, eco-friendly bio-battery powered by Saccharomyces cerevisiae on recyclable PET electrodes, with high cyclability and promising applications in sustainable energy solutions for low-power devices.
Sustainable Energy Fuels, 2024,8, 5165-5169
https://doi.org/10.1039/D4SE00903G
Structural and transport properties of battery electrolytes at sub-zero temperatures
Formulating and establishing design principles to improve low-temperature performance of battery electrolytes.
Energy Environ. Sci., 2024,17, 7691-7698
https://doi.org/10.1039/D4EE01437E
Electrolyte tuning with low concentrations of additive for dendrite suppression in lithium metal anodes
Lithium metal is considered as an ideal anode for high-energy density storage systems with dendrites being a major issue for lifetime and safety. A gadolinium additive is found to be suppressing dendrite growth resulting higher performance retention.
Sustainable Energy Fuels, 2024,8, 3574-3582
https://doi.org/10.1039/D4SE00548A
Recyclable HF-free Ti3C2Tx 3D-printed supercapacitors: their second life in sodium-ion batteries
Sodium lactate and conductive carbon are recycled to utilize them as electrolytes of supercapacitors and conductive additives of sodium-ion batteries, respectively.
J. Mater. Chem. A, 2025,13, 795-807
https://doi.org/10.1039/D4TA07436J
Diameter dependent performance of silicon nanowire anodes grown on 3D current collectors for lithium-ion batteries
Si nanowires (Si NWs) with diameters tuned from ∼35 to 100 nm were directly grown on large-area (30 cm2) stainless-steel mesh (SSM) substrates via a facile vapour–liquid–solid approach.
J. Mater. Chem. A, 2025,13, 696-703
https://doi.org/10.1039/D4TA07201D
Bimetallic-ion co-intercalation to stabilize vanadium–oxygen bonds towards high-performance aqueous zinc-ion storage
We designed a bimetallic-ion co-intercalation strategy to boost the performance of AZIBs using VOH, which significantly stabilizes the vanadium–oxygen bond.
J. Mater. Chem. A, 2025,13, 645-653
https://doi.org/10.1039/D4TA05938G
Non-woven pitch-based carbon fiber electrodes for low-cost redox flow battery
The low-cost and sustainable non-woven carbon fibers produced from petroleum pitch using a melt-blowing process are shown to be an ideal alternative to expensive polyacrylonitrile-based carbon felt electrode material for redox flow batteries.
Sustainable Energy Fuels, 2025,9, 198-207
https://doi.org/10.1039/D4SE01124D
Vat photopolymerization of tantalum-doped Li7La3Zr2O12 electrolytes: a new Frontier in solid-state battery design
Vat photopolymerization based 3D printing to fabricate Ta-doped LLZO electrolytes for solid state batteries, aiming to address limitations in traditional manufacturing methods.
J. Mater. Chem. A, 2025,13, 387-398
https://doi.org/10.1039/D4TA06160H
Pre-lithiation carbon anodes mitigating potassium loss for high-performance potassium-ion energy storage devices
A pre-lithiation carbon anode with a preformed SEI layer effectively mitigates potassium loss, thus enabling the fabrication of high-performance K+ energy storage devices without the need for unsafe and immature pre-potassium treatments.
J. Mater. Chem. A, 2024,12, 33958-33971
https://doi.org/10.1039/D4TA06451H
An ultrathin Li-doped perovskite SEI film with high Li ion flux for a fast charging lithium metal battery
A novel artificial SEI film (Li–CsPbCl3) based on lithium-doped cesium lead chloride perovskite enables fast charging lithium metal batteries by regulating the rapid transport and uniform deposition of lithium ions.
Energy Adv., 2024,3, 2999-3006
https://doi.org/10.1039/D4YA00507D
Manipulating defects simultaneously boosts the crystal stability and the electrochemical reversibility toward long-life aqueous zinc ion batteries
Combining sulfur-doping and heterojunction in vanadium oxide cathodes is first proposed herein toward long-life aqueous zinc ion batteries. The obtained S-VO2/V6O13-2 manifests a high capacity retention rate of 85.8% after 500 cycles at 0.5 A g−1.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA06186A
Regulating interfacial reactions through electrolyte chemistry enables an anion-rich interphase for wide-temperature zinc metal batteries
Zinc-ion batteries are challenged by zinc dendrites, notorious side reactions, and poor performance at low temperatures.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D4EE04803B
Lithiated polymer coating for interface stabilization in Li6PS5Cl-based solid-state batteries with high-nickel NCM
During cell cycling with NCM cathode and Li6PS5Cl catholyte, interfacial degradation leads to reduced active mass and particle cracking. We mitigate this by coating NCM with polyvinylpyrrolidone and sulfonated poly(phenylene sulfone).
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D4TA07265K
Asymmetric orbital hybridization at the MXene–VO2−x interface stabilizes oxygen vacancies for enhanced reversibility in aqueous zinc-ion batteries
The MXene–VO2−x cathode with asymmetric Ti–O–V orbital hybridization at the heterointerface for zinc-ion batteries is designed to stabilize the oxygen vacancies through charge transfer, thus efficiently boosting the electrochemical performance.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D4EE04466E
Reduced graphene oxide derived from the spent graphite anodes as a sulfur host in lithium–sulfur batteries
Recycled graphite anodes from spent LIBs as a conductive carbon host in LSBs.
Energy Adv., 2025, Advance Article
https://doi.org/10.1039/D4YA00480A
Removal of residual contaminants by minute-level washing facilitates the direct regeneration of spent cathodes from retired EV Li-ion batteries
Our study presents a minute-level water-based pretreatment that purifies degraded cathodes, enhancing lithium diffusivity and capacity retention in rejuvenated cathodes compared to contaminated ones.
Energy Environ. Sci., 2025, Advance Article
https://doi.org/10.1039/D4EE03021D
Enhancement of catalytic centres by RuO2 addition to CuFe2O4 cathode catalyst for rechargeable lithium–air batteries: influence of CO2 on Li–O2 battery performances
Herein, the oxygen reduction reaction and oxygen evolution reaction (ORR/OER) kinetics of the inverse-spinel CuFe2O4 catalyst was enhanced via the addition of a very low quantity of RuO2, which powers an LED when used in Li–air and Li–CO2 batteries.
Sustainable Energy Fuels, 2024,8, 5581-5594
https://doi.org/10.1039/D4SE01202J
Double layer capacitance as a sensitive metric to monitor the formation of solid electrolyte interphases in Li–ion batteries
Step-protocol to measure the SEI formation by double layer capacitances with detangled time and potential contributions.
Energy Adv., 2025, Advance Article
https://doi.org/10.1039/D4YA00524D
Interplay of intercalation dynamics and lithium plating in monolithic and architectured graphite anodes during fast charging
Fast charging of high-capacity anodes is challenging due to lithium plating reactions, which lead to poor cycling performance and safety concerns.
Energy Environ. Sci., 2024,17, 8702-8721
https://doi.org/10.1039/D4EE02211D
An energy-efficient tellurium electrode enabled by a Cs2TeI6 perovskite structure for durable aqueous Zn–Te batteries
CsI in 2 M ZnSO4 aqueous electrolyte facilitates the formation of Cs2TeI6 perovskite phase for Te electrode, effectively suppressing Te4+ hydrolysis and sustaining fast redox kinetics in multi-electron transfer Zn–Te aqueous batteries.
Energy Environ. Sci., 2024,17, 8633-8642
https://doi.org/10.1039/D4EE02916J
Recovery of graphite from industrial lithium-ion battery black mass
A streamlined workflow is established for the recovery of graphite from industrial lithium-ion battery black mass, which could be seamlessly integrated into the existing cathode materials recycling processes developed in the industry.
RSC Sustain., 2025, Advance Article
https://doi.org/10.1039/D4SU00427B
Electrolyte engineering for thermally stable Li–S batteries operating from –20 °C to 100 °C
An optimized electrolyte configuration is proposed for high performance Li–S batteries operating in extremely harsh temperature environments.
Energy Environ. Sci., 2024,17, 8151-8161
https://doi.org/10.1039/D4EE03191A
Cathode properties of a controlled crystallinity nano-Li1.2Cr0.4Mn0.4O2 cathode for lithium ion batteries
The milled-Li1.2Cr0.4Mn0.4O2 (milled-LCMO) cathode, a promising material for next-generation Li ion batteries, is prepared by dry ball-milling of layered rocksalt-type Li1.2Cr0.4Mn0.4O2 (layered-LCMO) obtained by solid-state synthesis.
RSC Mechanochem., 2025, Advance Article
https://doi.org/10.1039/D4MR00051J
Non-aqueous direct leaching using a reusable nickel-selective amic-acid extractant for efficient lithium-ion battery recycling
A nickel-selective amic-acid extractant D2EHAG efficiently leaches and separates metals from LiB cathode materials. Furthermore, D2EHAG can be reused for subsequent leaching, making it a promising candidate for a sustainable recycling process.
RSC Sustain., 2025, Advance Article
https://doi.org/10.1039/D4SU00414K
Multi-metal (Fe, Cu, and Zn) coordinated hollow porous dodecahedron nanocage catalyst for oxygen reduction in Zn–air batteries
The coupling of multiple low-cost metals and porous nanocarbon materials aimed at replacing precious metals to enhance electrocatalytic oxygen reduction is a critical challenge in some crucial research areas.
Energy Adv., 2024,3, 2648-2657
https://doi.org/10.1039/D4YA00295D
Long-life sodium–sulfur batteries enabled by super-sodiophilic seeds
Sodium–metal batteries (SMBs) are an appealing sustainable low-cost alternative to lithium–metal batteries due to their high theoretical capacity (1165 mA h g−1) and abundance of sodium.
Energy Environ. Sci., 2024,17, 7416-7423
https://doi.org/10.1039/D4EE02996H
Singlet oxygen is not the main source of electrolyte degradation in lithium–oxygen batteries
The lithium–oxygen field has focused on singlet oxygen’s role in cell degradation. This study shows no significant reaction between singlet oxygen and the electrolyte or carbon cathode, confirming it is not the major degradation source.
Energy Environ. Sci., 2024,17, 7355-7361
https://doi.org/10.1039/D4EE02176B
Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn–air battery
FeCoNiPdWP exhibit excellent oxygen evolution and reduction reaction performance via all elements playing distinctive roles and the switchable active sites in redox reactions, leading to robust zinc air batteries.
Energy Environ. Sci., 2024,17, 7193-7208
https://doi.org/10.1039/D4EE01912A
Dual-carbon coupling modulated bimetallic sulfides as high-efficiency bifunctional oxygen electrocatalysts in a rechargeable Zn–air battery
A hybrid of bimetallic sulfides modulated by 1D/2D carbon displays highly efficient bifunctional electrocatalytic performance for the ORR/OER in a rechargeable Zn–air battery.
Sustainable Energy Fuels, 2024,8, 3610-3616
https://doi.org/10.1039/D4SE00793J
A bi-functional air electrode developed from a dual-MOF strategy for high-performance zinc–air batteries
We designed a bi-functional (OER/ORR) air electrode using the a dual-MOF strategy for ZABs wherein a Fe-containing MOF (MIL-100) acts as a support to expose OER active sites and carbonized ZIF-67 acts as the ORR catalyst.
EES. Catal., 2024,2, 968-979
https://doi.org/10.1039/D4EY00008K
Enhanced electrochemical discharge of Li-ion batteries for safe recycling
The safe recycling of spent LIBs is challenging, as they often contain residual energy. Left untreated, this can trigger a thermal runaway and result in disaster during the recycling process. Electrochemical discharge method is an easy and inexpensive method to eliminate this hazard.
Sustainable Energy Fuels, 2024,8, 2777-2788
https://doi.org/10.1039/D4SE00125G
About this collection
How can we increase battery efficiency, reduce costs and improve sustainability? This collection investigates materials, chemistry and design to enhance energy storage capabilities.