Themed collection Advanced semiconductor nanocrystals

33 items
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Colloidal semiconductor quantum shells for solution-processed laser applications

Laser diodes based on solution-processed semiconductor quantum dots (QDs) present an economical and color-tunable alternative to traditional epitaxial lasers.

Graphical abstract: Colloidal semiconductor quantum shells for solution-processed laser applications
From the themed collection: Recent Review Articles
Open Access Communication

Molecularly-anchored single PbS quantum dots as resonant tunnelling transistors

Ten negative differential resistances (NDRs) were demonstrated in the output characteristics of molecularly-anchored single PbS quantum dot resonant tunneling transistors, which utilized heteroepitaxial spherical Au/Pt nanogap electrodes.

Graphical abstract: Molecularly-anchored single PbS quantum dots as resonant tunnelling transistors
From the themed collection: Advanced semiconductor nanocrystals
Communication

Tungsten oxide nanocrystals doped with interstitial methylammonium cations

The first colloidal synthesis of tungsten oxide nanocrystals doped with large organic cations is presented. The colloids show strong plasmonic properties in the near infrared.

Graphical abstract: Tungsten oxide nanocrystals doped with interstitial methylammonium cations
From the themed collection: Advanced semiconductor nanocrystals
Open Access Communication

Facile synthesis of Co3Te4–Fe3C for efficient overall water-splitting in an alkaline medium

This work introduces a novel design combining carbide (Fe3C) and chalcogenide (Co3Te4) materials for robust catalytic mechanisms in water electrolysis, ensuring high performance and durability for hydrogen production.

Graphical abstract: Facile synthesis of Co3Te4–Fe3C for efficient overall water-splitting in an alkaline medium
From the themed collection: Advanced semiconductor nanocrystals
Open Access Communication

Insights into the formation of CdSe nanoplatelets using a flow reactor

A novel synthesis to produce CdSe nanoplatelets in a flow reactor is introduced. Furthermore, the connection between CdSe magic-size clusters and the growth of these anisotropic nanoplatelets is investigated.

Graphical abstract: Insights into the formation of CdSe nanoplatelets using a flow reactor
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Colloidal organometallic synthesis of solution-processable barium titanate nanoparticles for nanoelectronic applications

Colloidal BaTiO3 nanoparticles were synthesized, ligand exchanged with oxalic acid to make an ink, and their properties explored for piezoelectrics.

Graphical abstract: Colloidal organometallic synthesis of solution-processable barium titanate nanoparticles for nanoelectronic applications
From the themed collection: Advanced semiconductor nanocrystals
Paper

Ultrafast electron transfer at the ZnIn2S4/MoS2 S-scheme interface for photocatalytic hydrogen evolution

An S-scheme ZnIn2S4/MoS2 heterostructure is designed. Transient absorption spectroscopy reveals the interfacial electron transfer from ZnIn2S4 to MoS2, which facilitates the photocatalytic hydrogen production rate for the heterostructure.

Graphical abstract: Ultrafast electron transfer at the ZnIn2S4/MoS2 S-scheme interface for photocatalytic hydrogen evolution
From the themed collection: Advanced semiconductor nanocrystals
Accepted Manuscript - Paper

Investigating visible range photoresponse of organic single-crystal of green fluorescent protein analogue

From the themed collection: Advanced semiconductor nanocrystals
Paper

Mixed metal halide perovskite CsPb1−xSnxBr3 quantum dots: insight into photophysics from photoblinking studies

Hot electrons from Sn populates Pb trap states in CsPb1−xSnxBr3 QDs, promoting exciton radiative recombination as shown by the suppression of GRAY levels in Photoblinking.

Graphical abstract: Mixed metal halide perovskite CsPb1−xSnxBr3 quantum dots: insight into photophysics from photoblinking studies
From the themed collection: Advanced semiconductor nanocrystals
Paper

Constructing fecal-derived electrocatalysts for CO2 upcycling: simultaneously tackling waste and carbon emissions

We developed a Cu-based electrocatalyst from pig manure-derived biochar for efficient CO2 reduction, achieving 87.14% faradaic efficiency and 44.80% multicarbon product selectivity.

Graphical abstract: Constructing fecal-derived electrocatalysts for CO2 upcycling: simultaneously tackling waste and carbon emissions
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Spectroelectrochemistry with hydrogen-doped indium oxide electrodes monitors electron and hole injection into PbS quantum dots

Determination of the absolute band edges and Fermi level positions by monitoring electrochemically induced IR absorption changes of EDT cross-linked PbS quantum dot films. IHO substrates provide optical transmittance and electrical conductivity.

Graphical abstract: Spectroelectrochemistry with hydrogen-doped indium oxide electrodes monitors electron and hole injection into PbS quantum dots
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Microwave-assisted synthesis of highly photoluminescent core/shell CuInZnSe/ZnS quantum dots as photovoltaic absorbers

A microwave-assisted synthesis of water-dispersible core/shell Cu–In–Zn–Se/ZnS QDs and their potential as absorbers for QDSSCs.

Graphical abstract: Microwave-assisted synthesis of highly photoluminescent core/shell CuInZnSe/ZnS quantum dots as photovoltaic absorbers
From the themed collection: Advanced semiconductor nanocrystals
Paper

Determination of the carrier temperature in weakly confined semiconductor nanocrystals using time-resolved optical spectroscopy

Using ultrafast PL is more suitable than TA for determining carrier temperatures of colloidal nanocrystals.

Graphical abstract: Determination of the carrier temperature in weakly confined semiconductor nanocrystals using time-resolved optical spectroscopy
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Zn0.5Cd0.5Se quantum dot-integrated MOF-derived C/N–CeO2 photocatalyst for enhanced H2O2 production and O2 evolution reactions

Zn0.5Cd0.5Se QD-integrated MOF-derived C/N–CeO2 photocatalyst for enhanced H2O2 production and O2 evolution reactions exhibited hierarchy and the desired multi-functionality of a MOF-derived C/N–CeO2 system. Part of the artwork reproduced with permission from Elsevier, 2021.

Graphical abstract: Zn0.5Cd0.5Se quantum dot-integrated MOF-derived C/N–CeO2 photocatalyst for enhanced H2O2 production and O2 evolution reactions
From the themed collection: Advanced semiconductor nanocrystals
Paper

Alternate InP synthesis with aminophosphines: solution–liquid–solid nanowire growth

Colloidal synthesis of InP nanowires is reported using aminophosphine and weakly-bound indium-ligand complexes, producing nanoribbons and nanowires. The aminophosphine is proposed to reduce indium for self-seeded solution–liquid–solid growth.

Graphical abstract: Alternate InP synthesis with aminophosphines: solution–liquid–solid nanowire growth
From the themed collection: Advanced semiconductor nanocrystals
Paper

Synergistic design of a graphene oxide-mediated polyaniline/α-Fe2O3 ternary heterostructure: advancing photocatalytic degradation and adsorption efficiency

This research involved synthesizing a novel Z-scheme PANI/GO/α-Fe2O3 ternary heterostructure and exploring its potential for degrading organic pollutants under visible light.

Graphical abstract: Synergistic design of a graphene oxide-mediated polyaniline/α-Fe2O3 ternary heterostructure: advancing photocatalytic degradation and adsorption efficiency
From the themed collection: Advanced semiconductor nanocrystals
Paper

Correlating photochemical H2 production and excited state lifetimes of heterostructured and doped ZnCdS nanoparticles

A variety of ZnCdS-based semiconductor nanoparticle heterostructures with extended exciton lifetimes were synthesized to enhance the efficacy of photocatalytic hydrogen production in water.

Graphical abstract: Correlating photochemical H2 production and excited state lifetimes of heterostructured and doped ZnCdS nanoparticles
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Layer-number-dependent photoswitchability in 2D MoS2-diarylethene hybrids

Optoelectronic properties of atomically-thin MoS2 flakes are modulated using photochromic diarylethene molecules. The layer-number-dependent charge transfer behaviors at the hybrid heterointerface are elucidated.

Graphical abstract: Layer-number-dependent photoswitchability in 2D MoS2-diarylethene hybrids
From the themed collection: Advanced semiconductor nanocrystals
Paper

Strong enhancement of effective refractive index in structured colloids (TiO2@Silica): Localization of light

A large enhancement of the effective refractive index experienced by Raman photons is demonstrated in a scattering medium comprising spatially-correlated photonic structures of core–shell TiO2@Silica scatterers plus silica NPs suspended in ethanol.

Graphical abstract: Strong enhancement of effective refractive index in structured colloids (TiO2@Silica): Localization of light
From the themed collection: Advanced semiconductor nanocrystals
Paper

Percolative phase transition in few-layered MoSe2 field-effect transistors using Co and Cr contacts

The metal-to-insulator phase transition in 2D materials has revealed interesting electronic behavior and the need for a deeper understanding of electronic transport processes while attracting interest in developing next-generation electronic devices.

Graphical abstract: Percolative phase transition in few-layered MoSe2 field-effect transistors using Co and Cr contacts
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Photogenerated charge carrier dynamics on Pt-loaded SrTiO3 nanoparticles studied via transient-absorption spectroscopy

Charge carrier recombination on a Pt cocatalyst was demonstrated using pico–nano and nano–micro second transient absorption spectroscopy.

Graphical abstract: Photogenerated charge carrier dynamics on Pt-loaded SrTiO3 nanoparticles studied via transient-absorption spectroscopy
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Triangular-shaped Cu–Zn–In–Se-based nanocrystals with narrow near infrared photoluminescence

Colloidal anisotropic Cu–Zn–In–Se-based nanocrystals synthesized in a one-pot seed-mediated approach exhibit an intensive narrow photoluminescence with maxima ranging from 1080 nm to 1220 nm and quantum yields reaching 40%.

Graphical abstract: Triangular-shaped Cu–Zn–In–Se-based nanocrystals with narrow near infrared photoluminescence
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Single-step, conformal, and efficient assembly of ligand-exchanged quantum dots for optoelectronic devices via an electric field

In this work the authors combined in-solution ligand exchange with an electrically driven film deposition technique to produce conformal PbSe quantum dot films on non-flat substrates in a single step without the need for post deposition processing.

Graphical abstract: Single-step, conformal, and efficient assembly of ligand-exchanged quantum dots for optoelectronic devices via an electric field
From the themed collection: Advanced semiconductor nanocrystals
Paper

Catalyst-assisted growth of CsPbBr3 perovskite nanowires

The formation of CsPbBr3 NW via the solution–solid–solid. At elevated temperatures, the ME catalyst undergoes a phase transition, facilitating the diffusion of reactants and the subsequent precipitation of solid CsPbBr3 nanowires.

Graphical abstract: Catalyst-assisted growth of CsPbBr3 perovskite nanowires
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Systematic probing of protein adsorption on protein-based nanoparticles in dependence of the particle surface charge

Fluorescence correlation spectroscopy reveals how surface charge affects protein adsorption on nanocages.

Graphical abstract: Systematic probing of protein adsorption on protein-based nanoparticles in dependence of the particle surface charge
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Ab initio calculations of vibrational fingerprints in the photoluminescence of graphene quantum dots

We used a computational method based on ab initio (constrained) density functional theory to obtain the photoluminescence spectrum of graphene quantum dots with up to 240 carbon atoms, including the effect of multiphonons.

Graphical abstract: Ab initio calculations of vibrational fingerprints in the photoluminescence of graphene quantum dots
From the themed collection: Advanced semiconductor nanocrystals
Open Access Paper

Blue CdSe/CdS core/crown nanoplatelet light-emitting diodes obtained via a design-of-experiments approach

The emissive material, consisting of blue-emitting CdSe colloidal nanoplatelets, and the organic charge injection layers were optimized using design of experiments, to produce a solution-processed blue light-emitting diode.

Graphical abstract: Blue CdSe/CdS core/crown nanoplatelet light-emitting diodes obtained via a design-of-experiments approach
From the themed collection: Advanced semiconductor nanocrystals
Paper

Boosting quantum efficiency and suppressing self-absorption in CdS quantum dots through interface engineering

Interface-engineered semiconductor quantum dots finally have it all – near-ideal photoluminescence efficiency and wide tunability without self-absorption.

Graphical abstract: Boosting quantum efficiency and suppressing self-absorption in CdS quantum dots through interface engineering
From the themed collection: Advanced semiconductor nanocrystals
Paper

Facile synthesis of defective ZnS–ZnO composite nanosheets for efficient piezocatalytic H2 production

Heterojunction-structured ZnO–ZnS composites with sulfur vacancies have been developed for efficient piezocatalytic H2 production.

Graphical abstract: Facile synthesis of defective ZnS–ZnO composite nanosheets for efficient piezocatalytic H2 production
From the themed collection: Advanced semiconductor nanocrystals
Paper

Shape-controlled, water-assisted synthesis of 2D luminescent CsPb2Br5 perovskite microcrystals for highly responsive UV detectors

Water-assisted, growth-controlled synthesis of CsPb2Br5 microcrystals for fast responsive UV-detectors.

Graphical abstract: Shape-controlled, water-assisted synthesis of 2D luminescent CsPb2Br5 perovskite microcrystals for highly responsive UV detectors
From the themed collection: Advanced semiconductor nanocrystals
Paper

Minimizing defect states through multidentate coordination and morphology regulation for enhancing the performance of inverted perovskite solar cells

The interaction between C[double bond, length as m-dash]O and Pb2+ regulated grain growth, enhanced crystallinity that effectively passivated non-radiative recombination centres and CF3 group stabilizes the perovskite structure by interacting with FA and Pb cationic defects.

Graphical abstract: Minimizing defect states through multidentate coordination and morphology regulation for enhancing the performance of inverted perovskite solar cells
From the themed collection: Advanced semiconductor nanocrystals
Paper

One-pot synthesis of heterostructured CsPbBr3/PdSe nanowires with excellent humidity stability

CsPbBr3@PdSe nanowires were prepared by a one-pot solution process and demonstrated excellent humidity stability. Approximately 95% of their PL intensity was retained after 30 days’ exposure to air.

Graphical abstract: One-pot synthesis of heterostructured CsPbBr3/PdSe nanowires with excellent humidity stability
From the themed collection: Advanced semiconductor nanocrystals
Paper

Selective photocatalytic C–C coupling of benzyl alcohol into hydrobenzoin using Pt-deposited CdS nanosheets passivated with cysteamine

We demonstrate selective photocatalytic synthesis of hydrobenzoin via the C–C coupling of benzyl alcohol using Pt/CdS nanosheets.

Graphical abstract: Selective photocatalytic C–C coupling of benzyl alcohol into hydrobenzoin using Pt-deposited CdS nanosheets passivated with cysteamine
From the themed collection: Advanced semiconductor nanocrystals
33 items

About this collection

Colloidal semiconductor nanocrystals are among the most captivating and influential nanomaterials due to their versatility and wide range of applications. Today, advanced nanocrystals are accessible, with high control over size, shape, and anisotropy, complex structures, exceptional purity, controlled doping, and more. These nanoscale materials exhibit unique optical and electronic properties because of their quantum confinement effects. They are used in light emitters, photodetectors, catalysis, energy harvesting, and components crucial for quantum computing endeavours. With continued research and innovation, these nanomaterials promise to revolutionize various technological fields and address pressing societal challenges. A better grasp of existing processes and uncovering unknown phenomena are crucial for practical applications.

This themed collection in Nanoscale and Nanoscale Advances guest edited by Professors Jannika Lauth (University of Tübingen, Germany), Indranath Chakraborty (IIT Kharagpur, India), Klaus Boldt (University of Rostock, Germany) and Angshuman Nag (IISER Pune, India) collates some of the latest research focusing on fundamental understanding and practical applications of semiconductor nanocrystals. 


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